The DOI matches its Crossref record; 5 of the 5 references it cites were found in a registry or an index.
Poly(thioether) Vitrimers via Transalkylation of Trialkylsulfonium Salts
Open accessAbstract
Abstract Vitrimers are permanently cross-linked organic polymers that can be reshaped, molded, and recycled without loss of network integrity. Herein, we report poly(thioether) networks, prepared through a straightforward thiol–ene photopolymerization, that can be turned into catalyst-free vitrimer materials by partial alkylation of the thioethers (1–10%) to the corresponding trialkylsulfonium salts. Based on a classical SN2-type substitution, the resulting polyionic networks can be reshaped upon heating via swift transalkylation reactions. This novel exchange reaction for the design of vitrimers was studied both on low MW model compounds as well as on a material level. In addition, we demonstrated the recycling of these networks without significant loss of mechanical properties.
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
High-performance vitrimers from commodity thermoplastics through dioxaborolane metathesis
Röttger, M., Domenech, T., van der Weegen, R., Breuillac, A., Nicolaÿ, R., & Leibler, L. (2017) · Science · doi:10.1126/science.aah5281 · Cited by 1,394
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Mechanically Activated, Catalyst-Free Polyhydroxyurethane Vitrimers
Fortman, D. J., Brutman, J. P., Cramer, C. J., Hillmyer, M. A., & Dichtel, W. R. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b08084 · Cited by 811
Making Insoluble Polymer Networks Malleable via Olefin Metathesis
Lu, Y.-X., Tournilhac, F., Leibler, L., & Guan, Z. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303356z · Cited by 568
Cited by
Dynamic Covalent Bonds in Polymeric Materials
Chakma, P., & Konkolewicz, D. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201813525 · Cited by 1,014
Scheutz, G. M., Lessard, J. J., Sims, M. B., & Sumerlin, B. S. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07922 · Cited by 934
Dynamic covalent chemistry in polymer networks: a mechanistic perspective
Winne, J. M., Leibler, L., & Du Prez, F. E. (2019) · Polymer Chemistry · doi:10.1039/c9py01260e · Cited by 736
Self-citationZhang, Z. P., Rong, M. Z., & Zhang, M. Q. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.03.002 · Cited by 586
Li, L., Chen, X., Jin, K., & Torkelson, J. M. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b00922 · Cited by 424
Metadata
- Authors
- Hendriks, B., Waelkens, J., Winne, J. M., & Du Prez, F. E.
- Venue
- ACS Macro Letters
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-08-15
- Volume
- 6
- Issue
- 9
- Pages
- 930-934
- ISSN
- 2161-1653 (ISSN-L)
- OpenAlex
- W2750225980
- Cited by
- 290
- References
- 5
- FWCI
- 15.88
- Type
- journal article
- Language
- en
- Open access
- hybrid
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- Hendriks, B., Waelkens, J., Winne, J. M., & Du Prez, F. E. (2017). Poly(thioether) Vitrimers via Transalkylation of Trialkylsulfonium Salts. ACS Macro Letters. https://doi.org/10.1021/acsmacrolett.7b00494
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