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Facile Synthesis of Nb2O5@Carbon Core–Shell Nanocrystals with Controlled Crystalline Structure for High-Power Anodes in Hybrid Supercapacitors
Abstract
Hybrid supercapacitors (battery-supercapacitor hybrid devices, HSCs) deliver high energy within seconds (excellent rate capability) with stable cyclability. One of the key limitations in developing high-performance HSCs is imbalance in power capability between the sluggish Faradaic lithium-intercalation anode and rapid non-Faradaic capacitive cathode. To solve this problem, we synthesize Nb2O5@carbon core-shell nanocyrstals (Nb2O5@C NCs) as high-power anode materials with controlled crystalline phases (orthorhombic (T) and pseudohexagonal (TT)) via a facile one-pot synthesis method based on a water-in-oil microemulsion system. The synthesis of ideal T-Nb2O5 for fast Li(+) diffusion is simply achieved by controlling the microemulsion parameter (e.g., pH control). The T-Nb2O5@C NCs shows a reversible specific capacity of ∼180 mA h g(-1) at 0.05 A g(-1) (1.1-3.0 V vs Li/Li(+)) with rapid rate capability compared to that of TT-Nb2O5@C and carbon shell-free Nb2O5 NCs, mainly due to synergistic effects of (i) the structural merit of T-Nb2O5 and (ii) the conductive carbon shell for high electron mobility. The highest energy (∼63 W h kg(-1)) and power (16 528 W kg(-1) achieved at ∼5 W h kg(-1)) densities within the voltage range of 1.0-3.5 V of the HSC using T-Nb2O5@C anode and MSP-20 cathode are remarkable.
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Cites
Barrett, E. P., Joyner, L. G., & Halenda, P. P. (1951) · Journal of the American Chemical Society · doi:10.1021/ja01145a126 · Cited by 13,172
(1990) · Cited by 9,358
Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
Poizot, P., Laruelle, S., Grugeon, S., Dupont, L., & Tarascon, J.-M. (2000) · Nature · doi:10.1038/35035045 · Cited by 8,041
Where do batteries end and supercapacitors begin?
Simon, P., Gogotsi, Y., & Dunn, B. (2014) · Science · doi:10.1126/science.1249625 · Cited by 5,634
Pseudocapacitive Contributions to Electrochemical Energy Storage in TiO2 (Anatase) Nanoparticles
Wang, J., Polleux, J., Lim, J., & Dunn, B. (2007) · The Journal of Physical Chemistry C · doi:10.1021/jp074464w · Cited by 5,333
High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance
Augustyn, V., Come, J., Lowe, M. A., Kim, J. W., Taberna, P.-L., Tolbert, S. H., Abruña, H. D., Simon, P., & Dunn, B. (2013) · Nature Materials · doi:10.1038/nmat3601 · Cited by 5,177
Ultrahigh-power micrometre-sized supercapacitors based on onion-like carbon
Pech, D., Brunet, M., Durou, H., Huang, P., Mochalin, V., Gogotsi, Y., Taberna, P.-L., & Simon, P. (2010) · Nature Nanotechnology · doi:10.1038/nnano.2010.162 · Cited by 2,721
Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
Kang, K., Meng, Y. S., Bréger, J., Grey, C. P., & Ceder, G. (2006) · Science · doi:10.1126/science.1122152 · Cited by 2,638
Self-citationSoler-Illia, G. J. D. A. A., Sanchez, C., Lebeau, B., & Patarin, J. (2002) · Chemical Reviews · doi:10.1021/cr0200062 · Cited by 1,958
Monolithic Carbide-Derived Carbon Films for Micro-Supercapacitors
Chmiola, J., Largeot, C., Taberna, P.-L., Simon, P., & Gogotsi, Y. (2010) · Science · doi:10.1126/science.1184126 · Cited by 1,325
Shen, L., Yu, L., Wu, H. B., Yu, X.-Y., Zhang, X., & Lou, X. W. (2015) · Nature Communications · doi:10.1038/ncomms7694 · Cited by 1,272
Templated Nanocrystal-Based Porous TiO2 Films for Next-Generation Electrochemical Capacitors
Brezesinski, T., Wang, J., Polleux, J., Dunn, B., & Tolbert, S. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja8057309 · Cited by 1,076
Zhang, F., Zhang, T., Yang, X., Zhang, L., Leng, K., Huang, Y., & Chen, Y. (2013) · Energy & Environmental Science · doi:10.1039/c3ee40509e · Cited by 1,041
High‐Performance Supercapacitors Based on Intertwined CNT/V2O5 Nanowire Nanocomposites
Chen, Z., Augustyn, V., Wen, J., Zhang, Y., Shen, M., Dunn, B., & Lu, Y. (2011) · Advanced Materials · doi:10.1002/adma.201003658 · Cited by 861
Second generation ‘nanohybrid supercapacitor’: Evolution of capacitive energy storage devices
Naoi, K., Ishimoto, S., Miyamoto, J.-I., & Naoi, W. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21675b · Cited by 728
Peng, S., Li, L., Wu, H. B., Madhavi, S., & Lou, X. W. (. (2015) · Advanced Energy Materials · doi:10.1002/aenm.201401172 · Cited by 638
Lee, J., Christopher Orilall, M., Warren, S. C., Kamperman, M., DiSalvo, F. J., & Wiesner, U. (2008) · Nature Materials · doi:10.1038/nmat2111 · Cited by 629
Self-citationA Hybrid Supercapacitor Fabricated with a Carbon Nanotube Cathode and a TiO2–B Nanowire Anode
Wang, Q., Wen, Z. H., & Li, J. H. (2006) · Advanced Functional Materials · doi:10.1002/adfm.200500937 · Cited by 592
New Generation “Nanohybrid Supercapacitor”
Naoi, K., Naoi, W., Aoyagi, S., Miyamoto, J.-I., & Kamino, T. (2013) · Accounts of Chemical Research · doi:10.1021/ar200308h · Cited by 587
Liu, J., Zhang, L., Wu, H. B., Lin, J., Shen, Z., & Lou, X. W. (. (2014) · Energy Environ. Sci. · doi:10.1039/c4ee01475h · Cited by 583
Kim, H., Cho, M., Kim, M., Park, K., Gwon, H., Lee, Y., Roh, K. C., & Kang, K. (2013) · Advanced Energy Materials · doi:10.1002/aenm.201300467 · Cited by 568
Self-citationThe Effect of Crystallinity on the Rapid Pseudocapacitive Response of Nb2O5
Kim, J. W., Augustyn, V., & Dunn, B. (2012) · Advanced Energy Materials · doi:10.1002/aenm.201100494 · Cited by 559
Galvanic Replacement Reactions in Metal Oxide Nanocrystals
Oh, M. H., Yu, T., Yu, S.-H., Lim, B., Ko, K.-T., Willinger, M.-G., Seo, D.-H., Kim, B. H., Cho, M. G., Park, J.-H., et al. (2013) · Science · doi:10.1126/science.1234751 · Cited by 541
Self-citationElectric Double-Layer Capacitor Performance of a New Mesoporous Carbon
Yoon, S., Lee, J., Hyeon, T., & Oh, S. M. (2000) · Journal of The Electrochemical Society · doi:10.1149/1.1393561 · Cited by 432
Self-citationLim, E., Kim, H., Jo, C., Chun, J., Ku, K., Kim, S., Lee, H. I., Nam, I.-S., Yoon, S., Kang, K., et al. (2014) · ACS Nano · doi:10.1021/nn501972w · Cited by 421
Self-citationMesoporous Li4Ti5O12 Hollow Spheres with Enhanced Lithium Storage Capability
Yu, L., Wu, H. B., & Lou, X. W. (. (2013) · Advanced Materials · doi:10.1002/adma.201204912 · Cited by 373
Oh, M. H., Lee, N., Kim, H., Park, S. P., Piao, Y., Lee, J., Jun, S. W., Moon, W. K., Choi, S. H., & Hyeon, T. (2011) · Journal of the American Chemical Society · doi:10.1021/ja200120k · Cited by 367
Self-citationLee, S. H., Yu, S.-H., Lee, J. E., Jin, A., Lee, D. J., Lee, N., Jo, H., Shin, K., Ahn, T.-Y., Kim, Y.-W., et al. (2013) · Nano Letters · doi:10.1021/nl401952h · Cited by 362
Self-citationHigh‐Performance Supercapacitors Based on Nanocomposites of Nb2O5 Nanocrystals and Carbon Nanotubes
Wang, X., Li, G., Chen, Z., Augustyn, V., Ma, X., Wang, G., Dunn, B., & Lu, Y. (2011) · Advanced Energy Materials · doi:10.1002/aenm.201100332 · Cited by 352
Rani, R. A., Zoolfakar, A. S., O'Mullane, A. P., Austin, M. W., & Kalantar-Zadeh, K. (2014) · J. Mater. Chem. A · doi:10.1039/c4ta02561j · Cited by 326
Electrochemical Kinetics of Nanostructured Nb2O5Electrodes
Come, J., Augustyn, V., Kim, J. W., Rozier, P., Taberna, P.-L., Gogotsi, P., Long, J. W., Dunn, B., & Simon, P. (2014) · Journal of The Electrochemical Society · doi:10.1149/2.040405jes · Cited by 281
Kang, E., Jung, Y. S., Kim, G., Chun, J., Wiesner, U., Dillon, A. C., Kim, J. K., & Lee, J. (2011) · Advanced Functional Materials · doi:10.1002/adfm.201101123 · Cited by 276
Self-citationHigh‐Performance Hybrid Supercapacitor Enabled by a High‐Rate Si‐based Anode
Yi, R., Chen, S., Song, J., Gordin, M. L., Manivannan, A., & Wang, D. (2014) · Advanced Functional Materials · doi:10.1002/adfm.201402398 · Cited by 246
Aegerter, M. A. (2001) · Solar Energy Materials and Solar Cells · doi:10.1016/s0927-0248(00)00372-x · Cited by 210
Jung, H.-G., Venugopal, N., Scrosati, B., & Sun, Y.-K. (2013) · Journal of Power Sources · doi:10.1016/j.jpowsour.2012.08.039 · Cited by 200
Kodama, R., Terada, Y., Nakai, I., Komaba, S., & Kumagai, N. (2006) · Journal of The Electrochemical Society · doi:10.1149/1.2163788 · Cited by 183
Nanoparticle sintering simulations
Zeng, P., Zajac, S., Clapp, P. C., & Rifkin, J. A. (1998) · Materials Science and Engineering: A · doi:10.1016/s0921-5093(98)00665-0 · Cited by 183
Orthorhombic niobium oxide nanowires for next generation hybrid supercapacitor device
Wang, X., Yan, C., Yan, J. W., Sumboja, A., & Lee, P. S. (2014) · Nano Energy · doi:10.1016/j.nanoen.2014.11.020 · Cited by 179
Aravindan, V., Jayaraman, S., Jain, A., Kumar, P. S., Ling, W. C., Ramakrishna, S., Srinivasan, M. P., & Srinivasan, M. (2014) · ChemSusChem · doi:10.1002/cssc.201400157 · Cited by 171
High‐Performance Hybrid Supercapacitor Based on Graphene‐Wrapped Li4Ti5O12 and Activated Carbon
Kim, H., Park, K., Cho, M., Kim, M., Hong, J., Jung, S., Roh, K. C., & Kang, K. (2014) · ChemElectroChem · doi:10.1002/celc.201300186 · Cited by 166
Self-citationUnderstanding the origin of high-rate intercalation pseudocapacitance in Nb2O5 crystals
Lubimtsev, A. A., Kent, P. R. C., Sumpter, B. G., & Ganesh, P. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta13316h · Cited by 153
Ha, D., Islam, M. A., & Robinson, R. D. (2012) · Nano Letters · doi:10.1021/nl3019559 · Cited by 146
Mun, Y., Jo, C., Hyeon, T., Lee, J., Ha, K., Jun, K., Lee, S., Hong, S. W., Lee, H. I., Yoon, S., et al. (2013) · Carbon · doi:10.1016/j.carbon.2013.07.092 · Cited by 94
Self-citationLee, J., Jung, Y. S., Warren, S. C., Kamperman, M., Oh, S. M., DiSalvo, F. J., & Wiesner, U. B. (2011) · Macromolecular Chemistry and Physics · doi:10.1002/macp.201000687 · Cited by 40
Self-citationJo, C., An, S., Kim, Y., Shim, J., Yoon, S., & Lee, J. (2012) · Physical Chemistry Chemical Physics · doi:10.1039/c2cp40657h · Cited by 29
Self-citation
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Wang, Q., Yan, J., & Fan, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03109e · Cited by 1,225
Review of energy storage systems for electric vehicle applications: Issues and challenges
Hannan, M. A., Hoque, M. M., Mohamed, A., & Ayob, A. (2017) · Renewable and Sustainable Energy Reviews · doi:10.1016/j.rser.2016.11.171 · Cited by 1,050
Schoetz, T., Gordon, L. W., Ivanov, S., Bund, A., Mandler, D., & Messinger, R. J. (2022) · Electrochimica Acta · doi:10.1016/j.electacta.2022.140072 · Cited by 404
Engineered Nanomaterials for Renewable Energy
Salame, P. H., Pawade, V. B., & Bhanvase, B. A. (2018) · Handbook of Nanomaterials for Industrial Applications · doi:10.1016/b978-0-12-813351-4.00047-x · Cited by 4
Metadata
- Authors
- Lim, E., Jo, C., Kim, H., Kim, M.-H., Mun, Y., Chun, J., Ye, Y., Hwang, J., Ha, K.-S., Roh, K. C., Kang, K., Yoon, S., & Lee, J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-06-24
- Volume
- 9
- Issue
- 7
- Pages
- 7497-7505
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2409015258
- Cited by
- 459
- References
- 45
- FWCI
- 15.95
- Type
- journal article
- Language
- en
- Open access
- closed
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