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Rashba and Dresselhaus Effects in Hybrid Organic–Inorganic Perovskites: From Basics to Devices
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We use symmetry analysis, density functional theory calculations, and k·p modeling to scrutinize Rashba and Dresselhaus effects in hybrid organic-inorganic halide perovskites. These perovskites are at the center of a recent revolution in the field of photovoltaics but have also demonstrated potential for optoelectronic applications such as transistors and light emitters. Due to a large spin-orbit coupling of the most frequently used metals, they are also predicted to offer a promising avenue for spin-based applications. With an in-depth inspection of the electronic structures and bulk lattice symmetries of a variety of systems, we analyze the origin of the spin splitting in two- and three-dimensional hybrid perovskites. It is shown that low-dimensional nanostructures made of CH3NH3PbX3 (X = I, Br) lead to spin splittings that can be controlled by an applied electric field. These findings further open the door for a perovskite-based spintronics.
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Citations
Cites
Generalized Gradient Approximation Made Simple
Perdew, J. P., Burke, K., & Ernzerhof, M. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3865 · Cited by 215,824
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
Kresse, G., & Furthmüller, J. (1996) · Physical Review B · doi:10.1103/physrevb.54.11169 · Cited by 123,652
Kresse, G., & Furthmüller, J. (1996) · Computational Materials Science · doi:10.1016/0927-0256(96)00008-0 · Cited by 75,638
Organometal Halide Perovskites as Visible-Light Sensitizers for Photovoltaic Cells
Kojima, A., Teshima, K., Shirai, Y., & Miyasaka, T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809598r · Cited by 23,090
Efficient pseudopotentials for plane-wave calculations
Troullier, N., & Martins, J. L. (1991) · Physical Review B · doi:10.1103/physrevb.43.1993 · Cited by 16,148
The SIESTA method for ab initio order-N materials simulation
Soler, J. M., Artacho, E., Gale, J. D., García, A., Junquera, J., Ordejón, P., & Sánchez-Portal, D. (2002) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/14/11/302 · Cited by 12,218
Spintronics: Fundamentals and applications
Žutić, I., Fabian, J., & Das Sarma, S. (2004) · Reviews of Modern Physics · doi:10.1103/revmodphys.76.323 · Cited by 11,268
Quantum Spin Hall Effect in Graphene
Kane, C. L., & Mele, E. J. (2005) · Physical Review Letters · doi:10.1103/physrevlett.95.226801 · Cited by 8,197
The emergence of perovskite solar cells
Green, M. A., Ho-Baillie, A., & Snaith, H. J. (2014) · Nature Photonics · doi:10.1038/nphoton.2014.134 · Cited by 7,432
Interface engineering of highly efficient perovskite solar cells
Zhou, H., Chen, Q., Li, G., Luo, S., Song, T.-B., Duan, H.-S., Hong, Z., You, J., Liu, Y., & Yang, Y. (2014) · Science · doi:10.1126/science.1254050 · Cited by 6,632
Stoumpos, C. C., Malliakas, C. D., & Kanatzidis, M. G. (2013) · Inorganic Chemistry · doi:10.1021/ic401215x · Cited by 5,416
Electronic analog of the electro-optic modulator
Datta, S., & Das, B. (1990) · Applied Physics Letters · doi:10.1063/1.102730 · Cited by 4,800
Spin-Orbit Coupling Effects in Zinc Blende Structures
Dresselhaus, G. (1955) · Physical Review · doi:10.1103/physrev.100.580 · Cited by 3,695
Perovskites: The Emergence of a New Era for Low-Cost, High-Efficiency Solar Cells
Snaith, H. J. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz4020162 · Cited by 3,042
Baikie, T., Fang, Y., Kadro, J. M., Schreyer, M., Wei, F., Mhaisalkar, S. G., Graetzel, M., & White, T. J. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta10518k · Cited by 2,534
Spin—Orbit Coupling Effects in Two-Dimensional Electron and Hole Systems
Winkler, R. (2003) · Springer Tracts in Modern Physics · doi:10.1007/b13586 · Cited by 2,489
Gate Control of Spin-Orbit Interaction in an Inverted In0.53Ga0.47As/In0.52Al0.48As Heterostructure
Nitta, J., Akazaki, T., Takayanagi, H., & Enoki, T. (1997) · Physical Review Letters · doi:10.1103/physrevlett.78.1335 · Cited by 2,284
The light and shade of perovskite solar cells
Grätzel, M. (2014) · Nature Materials · doi:10.1038/nmat4065 · Cited by 2,258
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors
Kagan, C. R., Mitzi, D. B., & Dimitrakopoulos, C. D. (1999) · Science · doi:10.1126/science.286.5441.945 · Cited by 2,110
Generic New Platform for Topological Quantum Computation Using Semiconductor Heterostructures
Sau, J. D., Lutchyn, R. M., Tewari, S., & Das Sarma, S. (2010) · Physical Review Letters · doi:10.1103/physrevlett.104.040502 · Cited by 1,940
Non-Abelian statistics and topological quantum information processing in 1D wire networks
Alicea, J., Oreg, Y., Refael, G., von Oppen, F., & Fisher, M. P. A. (2011) · Nature Physics · doi:10.1038/nphys1915 · Cited by 1,636
Dynamic disorder in methylammoniumtrihalogenoplumbates (II) observed by millimeter-wave spectroscopy
Poglitsch, A., & Weber, D. (1987) · The Journal of Chemical Physics · doi:10.1063/1.453467 · Cited by 1,625
Relativistic GW calculations on CH3NH3PbI3 and CH3NH3SnI3 Perovskites for Solar Cell Applications
Umari, P., Mosconi, E., & De Angelis, F. (2014) · Scientific Reports · doi:10.1038/srep04467 · Cited by 1,325
Even, J., Pedesseau, L., Jancu, J.-M., & Katan, C. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz401532q · Cited by 1,289
Self-citationAmat, A., Mosconi, E., Ronca, E., Quarti, C., Umari, P., Nazeeruddin, M. K., Grätzel, M., & De Angelis, F. (2014) · Nano Letters · doi:10.1021/nl5012992 · Cited by 1,285
Conducting tin halides with a layered organic-based perovskite structure
Mitzi, D. B., Feild, C. A., Harrison, W. T. A., & Guloy, A. M. (1994) · Nature · doi:10.1038/369467a0 · Cited by 1,100
Linear-Scaling ab-initio Calculations for Large and Complex Systems
Artacho, E., S�nchez-Portal, D., Ordej�n, P., Garc�a, A., & Soler, J. M. (1999) · physica status solidi (b) · doi:10.1002/(sici)1521-3951(199909)215:1<809::aid-pssb809>3.0.co;2-0 · Cited by 1,085
Steric engineering of metal-halide perovskites with tunable optical band gaps
Filip, M. R., Eperon, G. E., Snaith, H. J., & Giustino, F. (2014) · Nature Communications · doi:10.1038/ncomms6757 · Cited by 1,081
LaShell, S., McDougall, B. A., & Jensen, E. (1996) · Physical Review Letters · doi:10.1103/physrevlett.77.3419 · Cited by 1,079
Stoumpos, C. C., Frazer, L., Clark, D. J., Kim, Y. S., Rhim, S. H., Freeman, A. J., Ketterson, J. B., Jang, J. I., & Kanatzidis, M. G. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b01025 · Cited by 945
Giant Rashba-type spin splitting in bulk BiTeI
Ishizaka, K., Bahramy, M. S., Murakawa, H., Sakano, M., Shimojima, T., Sonobe, T., Koizumi, K., Shin, S., Miyahara, H., Kimura, A., et al. (2011) · Nature Materials · doi:10.1038/nmat3051 · Cited by 897
Giant Spin Splitting through Surface Alloying
Ast, C. R., Henk, J., Ernst, A., Moreschini, L., Falub, M. C., Pacilé, D., Bruno, P., Kern, K., & Grioni, M. (2007) · Physical Review Letters · doi:10.1103/physrevlett.98.186807 · Cited by 850
The SIESTA method; developments and applicability
Artacho, E., Anglada, E., Diéguez, O., Gale, J. D., García, A., Junquera, J., Martin, R. M., Ordejón, P., Pruneda, J. M., Sánchez-Portal, D., et al. (2008) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/20/6/064208 · Cited by 829
Conducting Layered Organic-inorganic Halides Containing 〈110〉-Oriented Perovskite Sheets
Mitzi, D. B., Wang, S., Feild, C. A., Chess, C. A., & Guloy, A. M. (1995) · Science · doi:10.1126/science.267.5203.1473 · Cited by 808
Umari, P., Mosconi, E., & Angelis, F. D. (2013) · arXiv (Cornell University) · doi:10.48550/arxiv.1309.4895 · Cited by 759
Brivio, F., Butler, K. T., Walsh, A., & van Schilfgaarde, M. (2014) · Physical Review B · doi:10.1103/physrevb.89.155204 · Cited by 755
A lead-halide perovskite molecular ferroelectric semiconductor
Liao, W.-Q., Zhang, Y., Hu, C.-L., Mao, J.-G., Ye, H.-Y., Li, P.-F., Huang, S. D., & Xiong, R.-G. (2015) · Nature Communications · doi:10.1038/ncomms8338 · Cited by 710
Strong Spin-Orbit Splitting on Bi Surfaces
Koroteev, Y. M., Bihlmayer, G., Gayone, J. E., Chulkov, E. V., Blügel, S., Echenique, P. M., & Hofmann, P. (2004) · Physical Review Letters · doi:10.1103/physrevlett.93.046403 · Cited by 690
Hidden spin polarization in inversion-symmetric bulk crystals
Zhang, X., Liu, Q., Luo, J.-W., Freeman, A. J., & Zunger, A. (2014) · Nature Physics · doi:10.1038/nphys2933 · Cited by 570
Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating
Knutson, J. L., Martin, J. D., & Mitzi, D. B. (2005) · Inorganic Chemistry · doi:10.1021/ic050244q · Cited by 562
Engels, G., Lange, J., Schäpers, T., & Lüth, H. (1997) · Physical Review B · doi:10.1103/physrevb.55.r1958 · Cited by 549
Tight-binding theory of the spin-orbit coupling in graphene
Konschuh, S., Gmitra, M., & Fabian, J. (2010) · Physical Review B · doi:10.1103/physrevb.82.245412 · Cited by 517
Jansen, R. (2012) · Nature Materials · doi:10.1038/nmat3293 · Cited by 486
Electric Control of the Giant Rashba Effect in Bulk GeTe
Di Sante, D., Barone, P., Bertacco, R., & Picozzi, S. (2013) · Advanced Materials · doi:10.1002/adma.201203199 · Cited by 466
Direct Observation of Ferroelectric Domains in Solution-Processed CH3NH3PbI3 Perovskite Thin Films
Kutes, Y., Ye, L., Zhou, Y., Pang, S., Huey, B. D., & Padture, N. P. (2014) · The Journal of Physical Chemistry Letters · doi:10.1021/jz501697b · Cited by 451
A simple tight-binding model of spin–orbit splitting of sp-derived surface states
Petersen, L., & Hedegård, P. (2000) · Surface Science · doi:10.1016/s0039-6028(00)00441-6 · Cited by 379
Spin splitting in semiconductor heterostructures for B→0
Lommer, G., Malcher, F., & Rossler, U. (1988) · Physical Review Letters · doi:10.1103/physrevlett.60.728 · Cited by 355
Switchable S = 1/2 and J = 1/2 Rashba bands in ferroelectric halide perovskites
Kim, M., Im, J., Freeman, A. J., Ihm, J., & Jin, H. (2014) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1405780111 · Cited by 302
Stroppa, A., Di Sante, D., Barone, P., Bokdam, M., Kresse, G., Franchini, C., Whangbo, M.-H., & Picozzi, S. (2014) · Nature Communications · doi:10.1038/ncomms6900 · Cited by 299
Bihlmayer, G., Rader, O., & Winkler, R. (2015) · New Journal of Physics · doi:10.1088/1367-2630/17/5/050202 · Cited by 286
Interplay of Rashba/Dresselhaus spin splittings probed by photogalvanic spectroscopy –A review
Ganichev, S. D., & Golub, L. E. (2014) · physica status solidi (b) · doi:10.1002/pssb.201350261 · Cited by 216
Even, J., Pedesseau, L., Jancu, J., & Katan, C. (2014) · physica status solidi (RRL) – Rapid Research Letters · doi:10.1002/pssr.201308183 · Cited by 213
Self-citationEremeev, S. V., Nechaev, I. A., Koroteev, Y. M., Echenique, P. M., & Chulkov, E. V. (2012) · Physical Review Letters · doi:10.1103/physrevlett.108.246802 · Cited by 188
Phase transitions in the perovskite methylammonium lead bromide, CH3ND3PbBr3
Swainson, I. P., Hammond, R. P., Soullière, C., Knop, O., & Massa, W. (2003) · Journal of Solid State Chemistry · doi:10.1016/s0022-4596(03)00352-9 · Cited by 186
Strong Tuning of Rashba Spin–Orbit Interaction in Single InAs Nanowires
Liang, D., & Gao, X. P. A. (2012) · Nano Letters · doi:10.1021/nl301325h · Cited by 180
Giant spin splitting of the two-dimensional electron gas at the surface of SrTiO3
Santander-Syro, A. F., Fortuna, F., Bareille, C., Rödel, T. C., Landolt, G., Plumb, N. C., Dil, J. H., & Radović, M. (2014) · Nature Materials · doi:10.1038/nmat4107 · Cited by 166
Vajna, S., Simon, E., Szilva, A., Palotás, K., Ujfalussy, B., & Szunyogh, L. (2012) · Physical Review B · doi:10.1103/physrevb.85.075404 · Cited by 162
Spin and angle resolved photoemission on non-magnetic low-dimensional systems
Dil, J. H. (2009) · Journal of Physics: Condensed Matter · doi:10.1088/0953-8984/21/40/403001 · Cited by 153
Liu, Q., Guo, Y., & Freeman, A. J. (2013) · Nano Letters · doi:10.1021/nl4027346 · Cited by 128
Fernández-Seivane, L., Oliveira, M. A. S., Sanvito, S., & Ferrer, J. (2006) · Journal of Physics Condensed Matter · doi:10.1088/0953-8984/18/34/012 · Cited by 122
Spin orientation and spin precession in inversion-asymmetric quasi-two-dimensional electron systems
Winkler, R. (2004) · Physical Review B · doi:10.1103/physrevb.69.045317 · Cited by 121
Rashba spin splitting in a gated HgTe quantum well
Schultz, M., Heinrichs, F., Merkt, U., et al. (1996) · Semiconductor Science and Technology · doi:10.1088/0268-1242/11/8/009 · Cited by 120
Katan, C., Pédesseau, L., Képénékian, M., Rolland, A., & Even, J. (2015) · Journal of Materials Chemistry A · doi:10.1039/c4ta06418f · Cited by 116
Self-citationThe ordered phase of methylammonium lead chloride CH3ND3PbCl3
Chi, L., Swainson, I. P., Cranswick, L. M. D., Her, J., Stephens, P. W., & Knop, O. (2005) · Journal of Solid State Chemistry · doi:10.1016/j.jssc.2004.12.037 · Cited by 97
Robust Surface Doping of Bi2Se3 by Rubidium Intercalation
Bianchi, M., Hatch, R. C., Li, Z., Hofmann, P., Song, F., Mi, J., Iversen, B. B., El‐Fattah, Z. M. A., Löptien, P., Zhou, L., et al. (2012) · ACS Nano · doi:10.1021/nn3021822 · Cited by 81
Tunable Spin Polarization in Bismuth Ultrathin Film on Si(111)
Takayama, A., Sato, T., Souma, S., Oguchi, T., & Takahashi, T. (2012) · Nano Letters · doi:10.1021/nl2035018 · Cited by 73
Search and design of nonmagnetic centrosymmetric layered crystals with large local spin polarization
Liu, Q., Zhang, X., Jin, H., Lam, K., Im, J., Freeman, A. J., & Zunger, A. (2015) · Physical Review B · doi:10.1103/physrevb.91.235204 · Cited by 70
Ast, C. R., & Gierz, I. (2012) · Physical Review B · doi:10.1103/physrevb.86.085105 · Cited by 66
Rashba split surface states in BiTeBr
Eremeev, S. V., Rusinov, I. P., Nechaev, I. A., & Chulkov, E. V. (2013) · New Journal of Physics · doi:10.1088/1367-2630/15/7/075015 · Cited by 59
Amnon Aharony, A., 都倉, 康., Cohen, G., Ora Entin-wohlman, A., & Katsumoto, S. (2011) · Physical Review B · doi:10.1103/physrevb.84.035323 · Cited by 56
Katan, C., Pédesseau, L., Képénékian, M., Rolland, A., & Even, J. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta90200f · Cited by 49
Self-citationTunable Surface Electron Spin Splitting with Electric Double-Layer Transistors Based on InN
Yin, C., Yuan, H., Wang, X., Liu, S., Zhang, S., Tang, N., Xu, F., Chen, Z., Shimotani, H., Iwasa, Y., et al. (2013) · Nano Letters · doi:10.1021/nl400153p · Cited by 47
Wang, E., Tang, P., Wan, G., Fedorov, A. V., Miotkowski, I., Chen, Y. P., Duan, W., & Zhou, S. (2015) · Nano Letters · doi:10.1021/nl504900s · Cited by 38
Spin density matrix of spin- 32 hole systems
Winkler, R. (2004) · Physical Review B · doi:10.1103/physrevb.70.125301 · Cited by 34
Chen, Y. P., Duan, W., & Zhou, S. (2016) · Cited by 34
Ideue, T., Checkelsky, J. G., Bahramy, M. S., Murakawa, H., Kaneko, Y., Nagaosa, N., & Tokura, Y. (2014) · Physical Review B · doi:10.1103/physrevb.90.161107 · Cited by 33
Spin polarization of quasi-two-dimensional hole systems
Winkler, R. (2005) · Physical Review B · doi:10.1103/physrevb.71.113307 · Cited by 28
Spin filtering in a Rashba–Dresselhaus–Aharonov–Bohm double-dot interferometer
Matityahu, S., Amnon Aharony, A., Ora Entin-wohlman, A., & Tarucha, S. (2013) · New Journal of Physics · doi:10.1088/1367-2630/15/12/125017 · Cited by 20
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Lu, H., Wang, J., Xiao, C., Pan, X., Chen, X., Brunecky, R., Berry, J. J., Zhu, K., Beard, M. C., & Vardeny, Z. V. (2019) · Science Advances · doi:10.1126/sciadv.aay0571 · Cited by 533
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Zheng, F., Tan, L. Z., Liu, S., & Rappe, A. M. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b01854 · Cited by 507
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Frost, J. M., & Walsh, A. (2016) · Accounts of Chemical Research · doi:10.1021/acs.accounts.5b00431 · Cited by 490
Neukirch, A. J., Nie, W., Blancon, J.-C., Appavoo, K., Tsai, H., Sfeir, M. Y., Katan, C., Pedesseau, L., Even, J., Crochet, J. J., et al. (2016) · Nano Letters · doi:10.1021/acs.nanolett.6b01218 · Cited by 299
Self-citation
Metadata
- Authors
- Kepenekian, M., Robles, R., Katan, C., Sapori, D., Pedesseau, L., & Even, J.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-09-14
- Volume
- 9
- Issue
- 12
- Pages
- 11557-11567
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W1652323284
- Cited by
- 419
- References
- 78
- FWCI
- 17.80
- Type
- journal article
- Language
- en
- Open access
- green
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