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CsPbxMn1–xCl3 Perovskite Quantum Dots with High Mn Substitution Ratio
Abstract
CsPbX 3 (X = Cl, Br, I) perovskite quantum dots (QDs) are potential emitting materials for illumination and display applications, but toxic Pb is not environment- and user-friendly. In this work, we demonstrate the partial replacement of Pb with Mn through phosphine-free hot-injection preparation of CsPb x Mn 1– x Cl 3 QDs in colloidal solution. The Mn substitution ratio is up to 46%, and the as-prepared QDs maintain the tetragonal crystalline structure of the CsPbCl 3 host. Meaningfully, Mn substitution greatly enhances the photoluminescence quantum yields of CsPbCl 3 from 5 to 54%. The enhanced emission is attributed to the energy transfer of photoinduced excitons from the CsPbCl 3 host to the doped Mn, which facilitates exciton recombination via a radiative pathway. The intensity and position of this Mn-related emission are also tunable by altering the experimental parameters, such as reaction temperature and the Pb-to-Mn feed ratio. A light-emitting diode (LED) prototype is further fabricated by employing the as-prepared CsPb x Mn 1– x Cl 3 QDs as color conversion materials on a commercially available 365 nm GaN LED chip.
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Metadata
- Authors
- Liu, H., Wu, Z., Shao, J., Yao, D., Gao, H., Liu, Y., Yu, W., Zhang, H., & Yang, B.
- Venue
- ACS Nano
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-02-01
- Volume
- 11
- Issue
- 2
- Pages
- 2239-2247
- ISSN
- 1936-0851 (ISSN-L)
- 1936-086X
- OpenAlex
- W2585726241
- Cited by
- 587
- References
- 58
- FWCI
- 33.56
- Type
- journal article
- Language
- en
- Open access
- closed
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