The DOI matches its Crossref record; 8 of the 8 references it cites were found in a registry or an index.
Hierarchical CoP–FeP Branched Heterostructures for Highly Efficient Electrocatalytic Water Splitting
Open accessAbstract
The development of efficient non-noble metal electrocatalysts for sustainable water splitting is crucial for clean energy conversion and has drawn extensive attention. Currently, nonprecious metal phosphides have emerged as efficient electrocatalysts to replace noble metals for both hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). However, it is still a great challenge for fabrication of universal, efficient and durable bifunctional electrocatalysts for these reactions via structural and component engineering. Herein, we report the design and construction of the hierarchical CoP–FeP branched heterostructures as high-performance and durable bifunctional electrocatalysts for both hydrogen and oxygen evolution electrocatalysis in various electrolytes. In such unique heterojunction, the intimate interfacial contact could induce built-in electric field at the interface, which effectively optimizes the surface electronic states of the FeP by the CoP, thus promoting the charge transfer and enhancing the electrocatalytic activity. As a consequence, the CoP–FeP heterostructures exhibit excellent performance for HER electrocatalysis, needing overpotentials as low as 30 and 71 mV to drive the 10 mA cm –2 current densities in 0.5 M H 2 SO 4 and 1.0 M KOH solutions, respectively, which are very close to that of Pt/C and rank it among the most HER-active electrocatalysts reported so far. Moreover, they can also behave as an efficient OER electrocatalyst with a very low overpotential of 250 mV at 10 mA cm –2 in 1.0 M KOH, outperforming most of the nonprecious-metal phosphides previously reported.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Platinum single-atom and cluster catalysis of the hydrogen evolution reaction
Cheng, N., Stambula, S., Wang, D., Banis, M. N., Liu, J., Riese, A., Xiao, B., Li, R., Sham, T.-K., Liu, L.-M., et al. (2016) · Nature Communications · doi:10.1038/ncomms13638 · Cited by 2,072
Wang, H., Lee, H.-W., Deng, Y., Lu, Z., Hsu, P.-C., Liu, Y., Lin, D., & Cui, Y. (2015) · Nature Communications · doi:10.1038/ncomms8261 · Cited by 1,257
Metallic Nickel Nitride Nanosheets Realizing Enhanced Electrochemical Water Oxidation
Xu, K., Chen, P., Li, X., Tong, Y., Ding, H., Wu, X., Chu, W., Peng, Z., Wu, C., & Xie, Y. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5119495 · Cited by 1,115
Han, N., Yang, K. R., Lu, Z., Li, Y., Xu, W., Gao, T., Cai, Z., Zhang, Y., Batista, V. S., Liu, W., et al. (2018) · Nature Communications · doi:10.1038/s41467-018-03429-z · Cited by 766
Zhang, Y., Ouyang, B., Xu, J., Jia, G., Chen, S., Rawat, R. S., & Fan, H. J. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201604372 · Cited by 737
Zhang, X., Zhang, X., Xu, H., Wu, Z., Wang, H., & Liang, Y. (2017) · Advanced Functional Materials · doi:10.1002/adfm.201606635 · Cited by 263
Cited by
Zhang, H., Maijenburg, A. W., Li, X., Schweizer, S. L., & Wehrspohn, R. B. (2020) · Advanced Functional Materials · doi:10.1002/adfm.202003261 · Cited by 666
Designing a Built-In Electric Field for Efficient Energy Electrocatalysis
Zhao, X., Liu, M., Wang, Y., Xiong, Y., Yang, P., Qin, J., Xiong, X., & Lei, Y. (2022) · ACS Nano · doi:10.1021/acsnano.2c09888 · Cited by 437
Shi, J., Qiu, F., Yuan, W., Guo, M., & Lu, Z.-H. (2021) · Chemical Engineering Journal · doi:10.1016/j.cej.2020.126312 · Cited by 346
Yan, P., Liu, Q., Zhang, H., Qiu, L., Wu, H. B., & Yu, X.-Y. (2021) · Journal of Materials Chemistry A · doi:10.1039/d1ta03362j · Cited by 292
Fan, Z., Jiang, J., Ai, L., Shao, Z., & Liu, S. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b15844 · Cited by 121
Self-citation
Metadata
- Authors
- Niu, Z., Qiu, C., Jiang, J., & Ai, L.
- Venue
- ACS Sustainable Chemistry & Engineering
- Publisher
- American Chemical Society (ACS)
- Published
- 2018-12-13
- Volume
- 7
- Issue
- 2
- Pages
- 2335-2342
- ISSN
- 2168-0485 (ISSN-L)
- OpenAlex
- W2904006969
- Cited by
- 183
- References
- 8
- FWCI
- 4.58
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Hierarchical CoP–FeP Branched Heterostructures for Highly Efficient Electrocatalytic Water Splitting. https://app.cochat.ai/papers/10.1021/acssuschemeng.8b05089
- The paper
- Niu, Z., Qiu, C., Jiang, J., & Ai, L. (2019). Hierarchical CoP–FeP Branched Heterostructures for Highly Efficient Electrocatalytic Water Splitting. ACS Sustainable Chemistry & Engineering. https://doi.org/10.1021/acssuschemeng.8b05089
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
