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A Facile One-Pot Method to Synthesize a Polypyrrole/Hemin Nanocomposite and Its Application in Biosensor, Dye Removal, and Photothermal Therapy
Abstract
In this work, we introduced a facile method for the construction of a polypyrrole/hemin (PPy/hemin) nanocomposite via one-pot chemical oxidative polymerization. In this process, a hemin molecule serving as a dopant was entrapped in the PPy nanocomposite during chemical oxidative polymerization. Scanning electron microscopy (SEM), transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR), and UV-visible spectroscopy results demonstrated that the PPy/hemin nanocomposite was successfully synthesized. The as-prepared nanocomposite exhibited intrinsic peroxidase-like catalytic activities, strong adsorption properties, and an excellent near-infrared (NIR) light-induced thermal effect. We utilized the nanomaterials to catalyze the oxidation of a peroxidase substrate 3,3,5,5-tetramethylbenzidine by H2O2 to the oxidized colored product which provided a colorimetric detection of glucose. As low as 50 μM glucose could be detected with a linear range from 0.05 to 8 mM. Moreover, the obtained nanocomposite also showed excellent removal efficiency for methyl orange and rhodamine B and a photothermal effect, which implied a promising application as the pollutant adsorbent and photothermal agent. The unique nature of the PPy/hemin nanocomposite makes it very promising for the fabrication of inexpensive, high-performance bioelectronic devices in the future.
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“but only two reports of peroxidase mimetic nanozymes for dye decolorisation exist (for an azo, a xanthene 209 and a thiazine dye 206 )”
From Degradation of anthraquinone dyes from effluents: A review focusing on enzymatic dye degradation with industrial potential (2020) · cites this paper as [209]
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Metadata
- Authors
- Hu, P., Han, L., & Dong, S.
- Venue
- ACS Applied Materials & Interfaces
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-12-11
- Volume
- 6
- Issue
- 1
- Pages
- 500-506
- ISSN
- 1944-8244
- 1944-8252
- Cited by
- 57
- References
- 65
- Language
- en
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