Aliphatic Polyester Block Polymers: Renewable, Degradable, and Sustainable

Hillmyer, Marc A., Tolman, William B.·2014·Accounts of Chemical Research

Cited by (636)

Items 101–200 of 636

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    Benjamin R. Elling, Jessica K. Su, Yan Xia · 2020 · ACS Macro Letters
  2. Chemical modifications of PLA through copolymerization
    Manju Puthumana, Palaniandavar Santhana Gopala Krishnan, Sanjay K. Nayak · 2020 · International Journal of Polymer Analysis and Characterization
  3. Organo-catalyzed/initiated ring opening co-polymerization of cyclic anhydrides and epoxides: an emerging story
    Dmytro Ryzhakov, Gaël Printz, Béatrice Jacques, Samir Messaoudi, Françoise Dumas, Samuel Dagorne, Franck Le Bideau · 2021 · Polymer Chemistry
  4. A broad scope of aliphatic polyesters prepared by elimination of small molecules from sustainable 1,3-dioxolan-4-ones
    Stefan A. Cairns, Amélie Schultheiss, Michael P. Shaver · 2017 · Polymer Chemistry
  5. Ring opening polymerization of macrolactones: high conversions and activities using an yttrium catalyst
    Dominic Myers, Timo Witt, Anish Cyriac, Mark Bown, Stefan Mecking, Charlotte K. Williams · 2017 · Polymer Chemistry
  6. Scalable Synthesis of Bio-Based Functional Styrene: Protected Vinyl Catechol from Caffeic Acid and Controlled Radical and Anionic Polymerizations Thereof
    Hisaaki Takeshima, Kotaro Satoh, Masami Kamigaito · 2018 · ACS Sustainable Chemistry & Engineering
  7. Plant Oil and Lignin-Derived Elastomers via Thermal Azide–Alkyne Cycloaddition Click Chemistry
    Liang Yuan, Yaqiong Zhang, Zhongkai Wang, Yanming Han, Chuanbing Tang · 2018 · ACS Sustainable Chemistry & Engineering
  8. Design of 2,5-furandicarboxylic based polyesters degraded in different environmental conditions: Comprehensive experimental and theoretical study
    Han Hu, Jiayi Li, Shenggan Luo, Ying Tian, Jinggang Wang, Yi‐Lei Zhao, Ruoyu Zhang, Jin Zhu · 2021 · Journal of Hazardous Materials
  9. Block–Stereoblock Copolymers of Poly(ϵ‐Caprolactone) and Poly(Lactic Acid)
    Tomer Rosen, Israel Goldberg, Wanda Navarra, Vincenzo Venditto, Moshe Kol · 2018 · Angewandte Chemie International Edition
  10. Zr(IV) Catalyst for the Ring-Opening Copolymerization of Anhydrides (A) with Epoxides (B), Oxetane (B), and Tetrahydrofurans (C) to Make ABB- and/or ABC-Poly(ester-alt-ethers)
    Ryan W. F. Kerr, Charlotte K. Williams · 2022 · Journal of the American Chemical Society
  11. Amidation of triglycerides by amino alcohols and their impact on plant oil-derived polymers
    Liang Yuan, Zhongkai Wang, Nathan M. Trenor, Chuanbing Tang · 2016 · Polymer Chemistry
  12. Designing Block Copolymer Architectures toward Tough Bioplastics from Natural Rosin
    Md Anisur Rahman, Hasala Nadeesini Lokupitiya, Mitra S. Ganewatta, Liang Yuan, Morgan Stefik, Chuanbing Tang · 2017 · Macromolecules
  13. Renewable Thermosets and Thermoplastics from Itaconic Acid
    Jacob T. Trotta, Annabelle Watts, Allison R. Wong, Anne M. LaPointe, Marc A. Hillmyer, Brett P. Fors · 2018 · ACS Sustainable Chemistry & Engineering
  14. Insights into the mechanism for ring-opening polymerization of lactide catalyzed by Zn(C 6 F 5 ) 2 /organic superbase Lewis pairs
    Xiaoqing Li, Bin Wang, He‐Yuan Ji, Yue‐Sheng Li · 2016 · Catalysis Science & Technology
  15. Supramolecular Polymer Nanocomposites Derived from Plant Oils and Cellulose Nanocrystals
    Lingzhi Song, Zhongkai Wang, Meghan E. Lamm, Liang Yuan, Chuanbing Tang · 2017 · Macromolecules
  16. High-Efficiency Construction of CO2-Based Healable Thermoplastic Elastomers via a Tandem Synthetic Strategy
    Guan‐Wen Yang, Guang‐Peng Wu · 2018 · ACS Sustainable Chemistry & Engineering
  17. Renewable atom-efficient polyesters and thermosetting resins derived from high oleic soybean oil
    Shichao Xu, Meghan E. Lamm, Md Anisur Rahman, Xinzhou Zhang, Tianyu Zhu, Zhao Zhen, Chuanbing Tang · 2018 · Green Chemistry
  18. A decade of innovation: Synthesis, properties and applications of PLA copolymers
    Zoi N. Terzopoulou, Alexandra Zamboulis, Nikolaos D. Bikiaris, Eleftheria Xanthopoulou, Rafail O. Ioannidis, Dimitrios Ν. Bikiaris · 2025 · Progress in Polymer Science
  19. Controlled Photoredox Ring-Opening Polymerization of O-Carboxyanhydrides
    Quanyou Feng, Rong Tong · 2017 · Journal of the American Chemical Society
  20. Mechanistic Studies of ε-Caprolactone Polymerization by (salen)AlOR Complexes and a Predictive Model for Cyclic Ester Polymerizations
    Marlier, Elodie E., Macaranas, Joahanna A., Marell, Daniel J., Dunbar, Christine R., Johnson, Michelle A., DePorre, Yvonne, Miranda, Maria O., Neisen, Benjamin D., Cramer, Christopher J., Hillmyer, Marc A. et al. · 2016 · ACS Catalysis
  21. Preparation of biorenewable poly(γ-butyrolactone)- b -poly( l -lactide) diblock copolyesters via one-pot sequential metal-free ring-opening polymerization
    Yong Shen, Jinbo Zhang, Na Zhao, Fusheng Liu, Zhibo Li · 2018 · Polymer Chemistry
  22. Degradable Polyphosphoramidate via Ring-Opening Metathesis Polymerization
    Yifei Liang, Hao Ran Sun, Wei Cao, Matthew P. Thompson, Nathan C. Gianneschi · 2020 · ACS Macro Letters
  23. Towards Truly Sustainable Polymers: A Metal‐Free Recyclable Polyester from Biorenewable Non‐Strained γ‐Butyrolactone
    Miao Hong, Eugene Y.‐X. Chen · 2016 · Angewandte Chemie
  24. Aliphatic Polyester Thermoplastic Elastomers Containing Hydrogen-Bonding Ureidopyrimidinone Endgroups
    Watts, Annabelle, Hillmyer, Marc A. · 2019 · Biomacromolecules
  25. Isotactic-Alternating, Heterotactic-Alternating, and ABAA-Type Sequence-Controlled Copolyester Syntheses via Highly Stereoselective and Regioselective Ring-Opening Polymerization of Cyclic Diesters
    Zhaowei Jia, Jinxing Jiang, Xiaofei Zhang, Yaqin Cui, Zhichun Chen, Xiaobo Pan, Jincai Wu · 2021 · Journal of the American Chemical Society
  26. Crystallization‐Driven Controlled Two‐Dimensional (2D) Assemblies from Chromophore‐Appended Poly(L‐lactide)s: Highly Efficient Energy Transfer on a 2D Surface
    Aritra Rajak, Anindita Das · 2022 · Angewandte Chemie International Edition
  27. Facile Synthesis of Aliphatic ω-Pentadecalactone Containing Diblock Copolyesters via Sequential ROP with l -Lactide, ε-Caprolactone, and δ-Valerolactone Catalyzed by Cyclic Trimeric Phosphazene Base with Inherent Tribasic Characteristics
    Na Zhao, Chuanli Ren, Yong Shen, Shaofeng Liu, Zhibo Li · 2019 · Macromolecules
  28. Enhanced Mechanical and Adhesion Properties in Sustainable Triblock Copolymers via Non-covalent Interactions
    Mohammadreza Nasiri, Derek J. Saxon, Theresa M. Reineke · 2018 · Macromolecules
  29. Ring-opening (co)polymerization of γ-butyrolactone: a review
    Qilei Song, Junpeng Zhao, Guangzhao Zhang, Frédéric Peruch, Stéphane Carlotti · 2019 · Polymer Journal
  30. Copolymerization of l -lactide and ε-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6′-dimethylbipheyl-bridge: random and tapered copolymer
    Chao Kan, Haiyan Ma · 2016 · RSC Advances
  31. The mechanistic duality of (thio)urea organocatalysts for ring-opening polymerization
    Nayanthara U. Dharmaratne, Jinal U. Pothupitiya, Matthew K. Kiesewetter · 2019 · Organic & Biomolecular Chemistry
  32. High-Performance Pressure-Sensitive Adhesives from Renewable Triblock Copolymers
    Keying Ding, Alex John, Jihoon Shin, Youngmin Lee, Tom Quinn, William B. Tolman, Marc A. Hillmyer · 2015 · Biomacromolecules
  33. Are Well Performing Catalysts for the Ring Opening Polymerization of l -Lactide under Mild Laboratory Conditions Suitable for the Industrial Process? The Case of New Highly Active Zn(II) Catalysts
    Massimo Christian D’Alterio, Ilaria D’Auria, Licia Gaeta, Consiglia Tedesco, Stefano Brenna, Claudio Pellecchia · 2022 · Macromolecules
  34. Block Poly(carbonate‐ester) Ionomers as High‐Performance and Recyclable Thermoplastic Elastomers
    Georgina L. Gregory, Gregory S. Sulley, Joost Kimpel, Matylda Szewczyk‐Łagodzińska, Lisa Häfele, Leticia Peña Carrodeguas, Charlotte K. Williams · 2022 · Angewandte Chemie International Edition
  35. Synthesis, characterization and drug loading property of Monomethoxy-Poly(ethylene glycol)-Poly(ε-caprolactone)-Poly(D,L-lactide) (MPEG-PCLA) copolymers
    Bingyang Chu, Lan Zhang, Ying Qu, Xiaoxin Chen, Jinrong Peng, Yixing Huang, Zhiyong Qian · 2016 · Scientific Reports
  36. Toughening Modification of Polylactic Acid by Thermoplastic Silicone Polyurethane Elastomer
    Mingtao Sun, Shuang Huang, Muhuo Yu, Keqing Han · 2021 · Polymers
  37. Sustainability and Polyesters: Beyond Metals and Monomers to Function and Fate
    Guilhem X. De Hoe, Theona Şucu, Michael P. Shaver · 2022 · Accounts of Chemical Research
  38. Star-shaped PHB–PLA block copolymers: immortal polymerization with dinuclear indium catalysts
    Insun Yu, Tannaz Ebrahimi, Savvas George Hatzikiriakos, P. Mehrkhodavandi · 2015 · Dalton Transactions
  39. Towards being genuinely smart: ‘isothermally-responsive’ polymers as versatile, programmable scaffolds for biologically-adaptable materials
    Daniel J. Phillips, Matthew I. Gibson · 2014 · Polymer Chemistry
  40. Printable, Degradable, and Biocompatible Ion Gels from a Renewable ABA Triblock Polyester and a Low Toxicity Ionic Liquid
    Boxin Tang, Deborah K. Schneiderman, Fazel Zare Bidoky, C. Daniel Frisbie, Timothy P. Lodge · 2017 · ACS Macro Letters
  41. Unimolecular Anion‐Binding Catalysts for Selective Ring‐Opening Polymerization of O‐carboxyanhydrides
    Maosheng Li, Shuai Zhang, Xiaoyong Zhang, Yanchao Wang, Jinlong Chen, Youhua Tao, Xianhong Wang · 2020 · Angewandte Chemie International Edition
  42. One-Pot Synthesis of Supertough, Sustainable Polyester Thermoplastic Elastomers Using Block-Like, Gradient Copolymer as Soft Midblock
    Zhao, Wuchao, Li, Chengkai, Yang, Xiao, He, Jianghua, Pang, Xuan, Zhang, Yuetao, Men, Yongfeng, Chen, Xuesi · 2022 · CCS Chemistry
  43. Macromolecular Design via an Organocatalytic, Monomer-Specific and Temperature-Dependent “On/Off Switch”. High Precision Synthesis of Polyester/Polycarbonate Multiblock Copolymers
    Peter Olsén, Karin Odelius, Helmut Keul, Ann‐Christine Albertsson · 2015 · Macromolecules
  44. Synthesis and Postpolymerization Modification of One-Pot ω-Pentadecalactone Block-like Copolymers
    James A. Wilson, Sally A. Hopkins, Peter M. Wright, Andrew P. Dove · 2015 · Biomacromolecules
  45. Synthesis of Functional Polycaprolactones via Passerini Multicomponent Polymerization of 6-Oxohexanoic Acid and Isocyanides
    Jian Zhang, Mei Zhang, Fu‐Sheng Du, Zichen Li · 2016 · Macromolecules
  46. Degradable, Ultraviolet‐Crosslinked Pressure‐Sensitive Adhesives Made from Thioester‐Functional Acrylate Copolymers
    Rohani Abu Bakar, Kyle S. Hepburn, Joseph L. Keddie, Peter J. Roth · 2023 · Angewandte Chemie International Edition
  47. Conversion of a Biorenewable Plant Oil (Anethole) to a New Fluoropolymer with Both Low Dielectric Constant and Low Water Uptake
    Fengkai He, Yu Xin Gao, Kaikai Jin, Jiajia Wang, Jing Sun, Qiang Fang · 2016 · ACS Sustainable Chemistry & Engineering
  48. Enantiomeric blends of high-molecular-weight poly(lactic acid)/poly(ethylene glycol) triblock copolymers: Enhanced stereocomplexation and thermomechanical properties
    Lili Han, Chengtao Yu, Jian Zhou, Guorong Shan, Yongzhong Bao, Xueyan Yun, Tungalag Dong, Pengju Pan · 2016 · Polymer
  49. Zinc versus Magnesium: Orthogonal Catalyst Reactivity in Selective Polymerizations of Epoxides, Bio‐derived Anhydrides and Carbon Dioxide
    Prabhjot K. Saini, Giulia Fiorani, Robert T. Mathers, Charlotte K. Williams · 2017 · Chemistry - A European Journal
  50. Paving the Way to Sustainable Waterborne Pressure-Sensitive Adhesives Using Terpene-Based Triblock Copolymers
    Sayrung Noppalit, Alexandre Simula, Laurent Billon, José M. Asúa · 2019 · ACS Sustainable Chemistry & Engineering
  51. A recyclable polyester library from reversible alternating copolymerization of aldehyde and cyclic anhydride
    Xun Zhang, Wenqi Guo, Chengjian Zhang, Xinghong Zhang · 2023 · Nature Communications
  52. Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate)
    Duy Le, Chanatip Samart, Suwadee Kongparakul, Kotohiro Nomura · 2019 · RSC Advances
  53. Fabricating Strong and Stiff Bioplastics from Whole Spirulina Cells
    Hareesh Iyer, Paul Grandgeorge, Andrew M. Jimenez, Ian R. Campbell, Mallory Parker, Michael Holden, Mathangi Venkatesh, Marissa Nelsen, Bichlien H. Nguyen, Eleftheria Roumeli · 2023 · Advanced Functional Materials
  54. Mechanism of the Polymerization of <i>rac</i>-Lactide by Fast Zinc Alkoxide Catalysts
    Stasiw, Daniel E., Luke, Anna M., Rosen, Tomer, League, Aaron B., Mandal, Mukunda, Neisen, Benjamin D., Cramer, Christopher J., Kol, Moshe, Tolman, William B. · 2017 · Inorganic Chemistry
  55. Exploiting Sodium Coordination in Alternating Monomer Sequences to Toughen Degradable Block Polyester Thermoplastic Elastomers
    Georgina L. Gregory, Charlotte K. Williams · 2022 · Macromolecules
  56. Bio-Based Polyesters with High Glass-Transition Temperatures and Gas Barrier Properties Derived from Renewable Rigid Tricyclic Diacid or Tetracyclic Anhydride
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  57. Tannic acid: A sustainable crosslinking agent for high glass transition epoxy materials
    Matthew Korey, Gamini Mendis, Jeffrey P. Youngblood, John A. Howarter · 2018 · Journal of Polymer Science Part A Polymer Chemistry
  58. Versatile Ring-Opening Copolymerization and Postprinting Functionalization of Lactone and Poly(propylene fumarate) Block Copolymers: Resorbable Building Blocks for Additive Manufacturing
    Shannon R. Petersen, James A. Wilson, Matthew L. Becker · 2018 · Macromolecules
  59. Multicomponent Coupling Approach to Cross-Conjugated Polymers from Vanillin-Based Monomers
    Laure V. Kayser, Elizabeth M. Hartigan, Bruce A. Arndtsen · 2016 · ACS Sustainable Chemistry & Engineering
  60. Crystallization-driven assembly of fully degradable, natural product-based poly(l-lactide)-block-poly(α-d-glucose carbonate)s in aqueous solution
    Yue Hong Song, Yingchao Chen, Lu Su, Richen Li, Rachel A. Letteri, Karen L. Wooley · 2017 · Polymer
  61. Biocatalytic Routes to Lactone Monomers for Polymer Production
    Hanan L. Messiha, Syed T. Ahmed, Vijaykumar Karuppiah, Reynier Suardíaz, Gabriel A. Ascue Avalos, Natalie Fey, Stephen George Yeates, Helen S. Toogood, Adrian John Mulholland, Nigel Shaun Scrutton · 2018 · Biochemistry
  62. Poly(ε-caprolactone) filled with polydopamine-coated high aspect ratio layered double hydroxide: Simultaneous enhancement of mechanical and barrier properties
    Long Mao, Yuejun Liu, Huiqing Wu, Jianhong Chen, Jin Bo Yao · 2017 · Applied Clay Science
  63. Ortho -vanillin derived Al( iii ) and Co( iii ) catalyst systems for switchable catalysis using ε-decalactone, phthalic anhydride and cyclohexene oxide
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  64. Bioelastomers: current state of development
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  65. Microfluidic Processing Approach to Controlling Drug Delivery Properties of Curcumin-Loaded Block Copolymer Nanoparticles
    Ruyao Chen, Jeremy E. Wulff, Matthew G. Moffitt · 2018 · Molecular Pharmaceutics
  66. Synthesis of Tris-Phosphazene Bases with Triazine as Core and Their Applications for Efficient Ring-Opening Alternating Copolymerization of Epoxide and Anhydride: Notable Effect of Basicity and Molecular Size
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  67. Development of completely furfural-based renewable polyesters with controllable properties
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  68. Bioderived and degradable polymers for transient electronics
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  69. One‐Pot Construction of Sulfur‐Rich Thermoplastic Elastomers Enabled by Metal‐Free Self‐Switchable Catalysis and Air‐Assisted Coupling
    Xiaofeng Zhu, Guan‐Wen Yang, Rui Juan Xie, Guang‐Peng Wu · 2021 · Angewandte Chemie International Edition
  70. Significant Trends in Rubber Research Driven by Environment, Resource, and Sustainability
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  71. Waste not, want not: CO 2 (re)cycling into block polymers
    Sumesh K. Raman, Robert Raja, Polly Louise Arnold, Matthew G. Davidson, Charlotte K. Williams · 2019 · Chemical Communications
  72. Design and structure of catalysts: syntheses of carbon dioxide-based copolymers with cyclic anhydrides and/or cyclic esters
    Jiaxin Liang, Shuxian Ye, Shuanjin Wang, Min Xiao, Yuezhong Meng · 2020 · Polymer Journal
  73. Recyclable Polyhydroxyalkanoates via a Regioselective Ring-Opening Polymerization of α,β-Disubstituted β-Lactone Monomers
    Yu-Tong Li, Hui-Ying Yu, Wenbing Li, Ye Liu, Xiao‐Bing Lu · 2021 · Macromolecules
  74. Controlled Ring-Opening Polymerization of β-Butyrolactone Via Bifunctional Organoboron Catalysts
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  75. Selective Ring‐Opening Polymerization of Non‐Strained γ‐Butyrolactone Catalyzed by A Cyclic Trimeric Phosphazene Base
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  76. Tailor-made block copolymers of <scp>l</scp> -, <scp>d</scp> - and <i>rac</i> -lactides and ε-caprolactone <i>via</i> one-pot sequential ring opening polymerization by pyridylamidozinc( <scp>ii</scp> ) catalysts
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  77. Fast and Controlled Ring-Opening Polymerization of Cyclic Esters by Alkoxides and Cyclic Amides
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  78. Dinuclear iron( iii ) complexes bearing phenylene-bridged bis(amino triphenolate) ligands as catalysts for the copolymerization of cyclohexene oxide with carbon dioxide or phthalic anhydride
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  79. Controlled Radical Copolymerization of Cinnamic Derivatives as Renewable Vinyl Monomers with Both Acrylic and Styrenic Substituents: Reactivity, Regioselectivity, Properties, and Functions
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  80. Amphiphilic block copolymers from a renewable ε-decalactone monomer: prediction and characterization of micellar core effects on drug encapsulation and release
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  82. Investigation of a zirconium compound for redox switchable ring opening polymerization
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  83. Block Copolymer Pressure-Sensitive Adhesives Derived from Fatty Acids and Triacetic Acid Lactone
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  84. Stereoselective Ring-Opening Polymerization of Lactones with a Fused Ring Leading to Semicrystalline Polyesters
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  85. Toughening CO 2 ‐Derived Copolymer Elastomers Through Ionomer Networking
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  86. Monomer-Promoting Asymmetric Kinetic Resolution-Alternating Copolymerization To Afford AAB-Type Copolyesters
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  87. Reinforced Mechanical Properties and Tunable Biodegradability in Nanoporous Cellulose Gels: Poly( l -lactide-co-caprolactone) Nanocomposites
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  88. Material properties of degradable Poly(butylene succinate-co-fumarate) copolymer networks synthesized by polycondensation of pre-homopolyesters
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  89. SaBOX/Copper Catalysts for Highly Syndio-Specific Atom Transfer Radical Polymerization of Methyl Methacrylate
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  90. Ring‐Opening Copolymerization of Maleic Anhydride with Functional Epoxides: Poly(propylene fumarate) Analogues Capable of Post‐Polymerization Modification
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  91. Weak Lewis Pairs as Catalysts for Highly Isoselective Ring-Opening Polymerization of Epimerically Labile rac-O-Carboxyanhydride of Mandelic Acid
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  92. Recent Advances in Monomer Design for Recyclable Polymers
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  93. A General Strategy for Radical Ring-Opening Polymerization of Macrocyclic Allylic Sulfides
    Shuai Zhang, Chi Cao, Suqiu Jiang, Hanchu Huang · 2022 · Macromolecules
  94. Ultraviolet light blocking optically clear adhesives for foldable displays via highly efficient visible-light curing
    Yonghwan Kwon, Seokju Lee, Junkyu Kim, Jinwon Jun, Woojin Jeon, Youngjoo Park, Hyun‐Joong Kim, Johannes Gierschner, Jaesang Lee, Youngdo Kim et al. · 2024 · Nature Communications
  95. Highly Regioselective Isomerizing Hydroformylation of Long‐Chain Internal Olefins Catalyzed by a Rhodium Bis(Phosphite) Complex
    Swechchha Pandey, Samir H. Chikkali · 2015 · ChemCatChem
  96. Synthesis of Biobased Long-Chain Polyesters by Acyclic Diene Metathesis Polymerization and Tandem Hydrogenation and Depolymerization with Ethylene
    Kotohiro Nomura, Permpoon Chaijaroen, Mohamed Mehawed Abdellatif · 2020 · ACS Omega
  97. Biomass- and calcium carbide-based recyclable polymers
    Svetlana A. Metlyaeva, Konstantin S. Rodygin, Kristina A. Lotsman, Dmitriy E. Samoylenko, Valentine P. Ananikov · 2021 · Green Chemistry
  98. Resilient Poly(α-hydroxy acids) with Improved Strength and Ductility via Scalable Stereosequence-Controlled Polymerization
    Xiaoqian Wang, Ai Lin Chin, Jingyi Zhou, Hua Wang, Rong Tong · 2021 · Journal of the American Chemical Society
  99. Synthesis and Properties of Functionalized Poly(ε-caprolactone); Chain Polymerization Followed by Polycondensation in One Pot with Initiator and Catalyst in One Molecule. Synthesis and Molecular Structures
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  100. The Role of Alkoxide Initiator, Spin State, and Oxidation State in Ring-Opening Polymerization of ε-Caprolactone Catalyzed by Iron Bis(imino)pyridine Complexes
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