Cellulose Solvents – Remarkable History, Bright Future
Abstract
The paper summarizes different approaches for the dissolution of cellulose and the use of these cellulose solutions for analysis, regeneration, and homogeneous modification of the polymer. Aqueous and non-aqueous solvents, melts, and soluble cellulose intermediates are discussed with the focus on new developments for the shaping and the homogeneous conversion of cellulose. It will be shown that these media open up new paths towards nanostructured regenerated cellulose and tailored cellulose derivatives not accessible via heterogeneous reactions. Moreover, the preparation of conventional cellulose products with new structural features obtainable by conversion in cellulose solvents will be illustrated.
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Significant instability of the NMO/cellulose solution above 90 °C and redox activity of the NMO have been viewed as problems.
“Nevertheless, significant instability of the NMO/cellulose solution above 90 °C and redox activity of the NMO have been viewed as problems, 67 which could be addressed by the use of more stable cellulose dissolving ionic liquids.”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [67]
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- Authors
- Liebert, T.
- Affiliations
- Friedrich Schiller University Jena (DE)
- Corresponding author
- Liebert, Tim
- Venue
- ACS Symposium Series
- Publisher
- American Chemical Society
- Published
- 2010-01
- Pages
- 3-54
- ISSN
- 0097-6156 (ISSN-L)
- 1947-5918
- OpenAlex
- W2487001459
- Cited by
- 250
- References
- 220
- Citations by year
- 2026: 7 · 2025: 14 · 2024: 14 · 2023: 15 · 2022: 13 · 2021: 16 · 2020: 22 · 2019: 23 · 2018: 22 · 2017: 15 · 2016: 17 · 2015: 15 · 2014: 17 · 2013: 15 · 2012: 16
- FWCI
- 80.71
- Type
- conference paper
- Language
- en
- Open access
- closed
- Locations
- ACS symposium series (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Engineering › Biomedical Engineering › Lignin and Wood Chemistry
- Physical Sciences › Engineering › Biomedical Engineering › Catalysis for Biomass Conversion
- Keywords
- cellulose solvents, cellulose dissolution, non-aqueous solvents, cellulose regeneration, cellulose derivatives
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