Design of Cellulose Dissolving Ionic Liquids Inspired by Nature
Abstract
Stimulating the hunger of enzymes: The design of an ionic liquid that has the ability to dissolve cellulose has been attempted from the viewpoint of a cellulase. N,N-diethyl-N-(2-methoxyethyl)-N-methylammonium alanine ([N221ME][Ala]) is a good solvent for cellulose. Dissolution in [N221ME][Ala] converts the crystalline structure of cellulose from Type I to II, which is known to be a form easily digested by cellulases.
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A protic cation prevents cellulose solubilisation entirely in many cases.
“A protic cation prevents cellulose solubilisation entirely in many cases.57,91”
From Deconstruction of lignocellulosic biomass with ionic liquids (2013) · cites this paper as [91]
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Mostofian, B. (2014)
- Authors
- Ohira, K., Abe, Y., Kawatsura, M., Suzuki, K., Mizuno, M., Amano, Y., & Itoh, T.
- Affiliations
- Tottori University (JP)
- Idemitsu Kosan (Japan) (JP)
- Shinshu University (JP)
- Corresponding author
- Itoh, Toshiyuki
- Venue
- ChemSusChem
- Publisher
- Wiley
- Published
- 2012-01-19
- Volume
- 5
- Issue
- 2
- Pages
- 388-391
- ISSN
- 1864-5631 (ISSN-L)
- 1864-564X
- OpenAlex
- W2170461698
- Cited by
- 92
- References
- 34
- Citations by year
- 2025: 2 · 2024: 1 · 2023: 6 · 2022: 4 · 2021: 3 · 2020: 5 · 2019: 7 · 2018: 6 · 2017: 10 · 2016: 7 · 2015: 11 · 2014: 10 · 2013: 11 · 2012: 9
- FWCI
- 5.66
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- ChemSusChem (publishedVersion)
- PubMed (publishedVersion)
- Funders
- Japan Society for the Promotion of Science (23360369)
- Topics
- Physical Sciences › Chemical Engineering › Catalysis › Ionic liquids properties and applications
- Physical Sciences › Materials Science › Biomaterials › Advanced Cellulose Research Studies
- Physical Sciences › Engineering › Biomedical Engineering › Biofuel production and bioconversion
- Keywords
- cellulose dissolution, ionic liquids, cellulose crystallinity, biocatalysis
- MeSH terms
- Cellulose, Solubility, Biomimetics, Cellulases, Ionic Liquids
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