The DOI matches its Crossref record; 38 of the 38 references it cites were found in a registry or an index.
Porous Polymer Networks: Synthesis, Porosity, and Applications in Gas Storage/Separation
Abstract
Three porous polymer networks (PPNs) have been synthesized by the homocoupling of tetrahedral monomers. Like other hyper-cross-linked polymer networks, these materials are insoluble in conventional solvents and exhibit high thermal and chemical stability. Their porosity was confirmed by N 2 sorption isotherms at 77 K. One of these materials, PPN-3, has a Langmuir surface area of 5323 m 2 g −1 . Their clean energy applications, especially in H 2, CH 4, and CO 2 storage, as well as CO 2 /CH 4 separation, have been carefully investigated. Although PPN-1 has the highest gas affinity because of its smaller pore size, the maximal gas uptake capacity is directly proportional to their surface area. PPN-3 has the highest H 2 uptake capacity among these three (4.28 wt %, 77 K). Although possessing the lowest surface area, PPN-1 shows the best CO 2 /CH 4 selectivity among them.
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Metadata
- Authors
- Lu, W., Yuan, D., Zhao, D., Schilling, C. I., Plietzsch, O., Muller, T., Bräse, S., Guenther, J., Blümel, J., Krishna, R., Li, Z., & Zhou, H.-C.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2010-10-05
- Volume
- 22
- Issue
- 21
- Pages
- 5964-5972
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2048575095
- Cited by
- 577
- References
- 38
- FWCI
- 68.14
- Type
- journal article
- Language
- en
- Open access
- closed
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