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Cited by 309

The DOI matches its Crossref record; 9 of the 9 references it cites were found in a registry or an index.

Topochemical Synthesis of Sodium Metal Phosphate Olivines for Sodium-Ion Batteries

Lee, Kyu Tae, Ramesh, T. N., Nan, F., Botton, G., Nazar, Linda F.·2011·Chemistry of Materials

Abstract

New metastable olivine phases of sodium metal phosphates, Na[Mn 1– x M x ]PO 4 (M = Fe, Ca, Mg), nanorods are synthesized by a simple solid-state reaction at low temperature (≤100 °C) by means of a topotactic molten salt reaction that converts NH 4 [Mn 1– x M x ]PO 4 •H 2 O (M = Fe, Ca, Mg) to Na[Mn 1– x M x ]PO 4 . Their crystal structures are characterized via XRD Rietveld refinement and electron diffraction. A full range of solid solution behavior was observed for olivine Na 1– x Mn 0.5 Fe 0.5 PO 4, in contrast to that of LiMPO 4 (M = Fe, Mn) olivine materials, and is ascribed to ion size effects. The solid solution behavior of NaMn 0.5 Fe 0.5 PO 4 was confirmed by electrochemical characterization.

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Metadata

Authors
Lee, K. T., Ramesh, T. N., Nan, F., Botton, G., & Nazar, L. F.
Venue
Chemistry of Materials
Published
2011-07-20
Volume
23
Issue
16
Pages
3593-3600
ISSN
  • 0897-4756 (ISSN-L)
  • 1520-5002
OpenAlex
W2332110027
Cited by
309
References
9
FWCI
16.93
Type
journal article
Language
en
Open access
closed

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