The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Room-Temperature Self-Healable and Remoldable Cross-linked Polymer Based on the Dynamic Exchange of Disulfide Bonds
Abstract
Tri- n -butylphosphine (TBP) has been shown to effectively catalyze an air-insensitive disulfide metathesis reaction under alkaline conditions at room temperature. A cross-linked polysulfide containing the phosphine exhibited repeated autonomous self-healing resulting in restoration of tensile strength as a result of the dynamic exchange of disulfide bonds. Interestingly, the cross-linked polysulfide can also be reshaped and reprocessed at room temperature via the TBP-mediated reshuffling of the macromolecular networks. The mechanical properties and self-healing ability of polymeric specimens made from chopped samples remain surprisingly constant. In sharp contrast, control specimens without the phosphine catalyst or S–S bonds are neither self-healable nor reprocessable.
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Cites
Silica-Like Malleable Materials from Permanent Organic Networks
Montarnal, D., Capelot, M., Tournilhac, F., & Leibler, L. (2011) · Science · doi:10.1126/science.1212648 · Cited by 3,625
Self-healing and thermoreversible rubber from supramolecular assembly
Cordier, P., Tournilhac, F., Soulié-Ziakovic, C., & Leibler, L. (2008) · Nature · doi:10.1038/nature06669 · Cited by 2,984
Lewis Base Catalysis in Organic Synthesis
Denmark, S. E., & Beutner, G. L. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200604943 · Cited by 1,264
Covalent Adaptable Networks (CANs): A Unique Paradigm in Cross-Linked Polymers
Kloxin, C. J., Scott, T. F., Adzima, B. J., & Bowman, C. N. (2010) · Macromolecules · doi:10.1021/ma902596s · Cited by 1,175
Self-Healing Materials Based on Disulfide Links
Canadell, J., Goossens, H., & Klumperman, B. (2011) · Macromolecules · doi:10.1021/ma2001492 · Cited by 1,007
Catalyst-free room-temperature self-healing elastomers based on aromatic disulfide metathesis
Rekondo, A., Martin, R., Ruiz de Luzuriaga, A., Cabañero, G., Grande, H. J., & Odriozola, I. (2014) · Mater. Horiz. · doi:10.1039/c3mh00061c · Cited by 901
Amamoto, Y., Otsuka, H., Takahara, A., & Matyjaszewski, K. (2012) · Advanced Materials · doi:10.1002/adma.201201928 · Cited by 703
Self-healing polymers based on thermally reversible Diels–Alder chemistry
Liu, Y.-L., & Chuo, T.-W. (2013) · Polymer Chemistry · doi:10.1039/c2py20957h · Cited by 684
Zheng, P., & McCarthy, T. J. (2012) · Journal of the American Chemical Society · doi:10.1021/ja2113257 · Cited by 625
Deng, G., Li, F., Yu, H., Liu, F., Liu, C., Sun, W., Jiang, H., & Chen, Y. (2012) · ACS Macro Letters · doi:10.1021/mz200195n · Cited by 620
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Zhao, X., Chen, X., Yuk, H., Lin, S., Liu, X., & Parada, G. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01088 · Cited by 1,161
Denissen, W., Rivero, G., Nicolaÿ, R., Leibler, L., Winne, J. M., & Du Prez, F. E. (2015) · Advanced Functional Materials · doi:10.1002/adfm.201404553 · Cited by 1,121
Advances in 4D Printing: Materials and Applications
Kuang, X., Roach, D. J., Wu, J., Hamel, C. M., Ding, Z., Wang, T., Dunn, M. L., & Qi, H. J. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201805290 · Cited by 1,095
Self-healing gels based on constitutional dynamic chemistry and their potential applications
Wei, Z., Yang, J. H., Zhou, J., Xu, F., Zrínyi, M., Dussault, P. H., Osada, Y., & Chen, Y. M. (2014) · Chem. Soc. Rev. · doi:10.1039/c4cs00219a · Cited by 896
Ruiz de Luzuriaga, A., Martin, R., Markaide, N., Rekondo, A., Cabañero, G., Rodríguez, J., & Odriozola, I. (2016) · Materials Horizons · doi:10.1039/c6mh00029k · Cited by 886
Room-Temperature Self-Healing Polymers Based on Dynamic-Covalent Boronic Esters
Cash, J. J., Kubo, T., Bapat, A. P., & Sumerlin, B. S. (2015) · Macromolecules · doi:10.1021/acs.macromol.5b00210 · Cited by 716
Lai, Y., Kuang, X., Zhu, P., Huang, M., Dong, X., & Wang, D. (2018) · Advanced Materials · doi:10.1002/adma.201802556 · Cited by 686
Zhang, Z. P., Rong, M. Z., & Zhang, M. Q. (2018) · Progress in Polymer Science · doi:10.1016/j.progpolymsci.2018.03.002 · Cited by 586
Self-citationChemical control of the viscoelastic properties of vinylogous urethane vitrimers
Denissen, W., Droesbeke, M., Nicolaÿ, R., Leibler, L., Winne, J. M., & Du Prez, F. E. (2017) · Nature Communications · doi:10.1038/ncomms14857 · Cited by 552
Wang, S., Ma, S., Li, Q., Xu, X., Wang, B., Yuan, W., Zhou, S., You, S., & Zhu, J. (2019) · Green Chemistry · doi:10.1039/c8gc03477j · Cited by 503
Recyclable and Malleable Epoxy Thermoset Bearing Aromatic Imine Bonds
Zhao, S., & Abu-Omar, M. M. (2018) · Macromolecules · doi:10.1021/acs.macromol.8b01976 · Cited by 435
Chen, Y., Tang, Z., Zhang, X., Liu, Y., Wu, S., & Guo, B. (2018) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.8b09863 · Cited by 431
Chen, M., Zhou, L., Wu, Y., Zhao, X., & Zhang, Y. (2019) · ACS Macro Letters · doi:10.1021/acsmacrolett.9b00015 · Cited by 389
Malleable and Recyclable Thermosets: The Next Generation of Plastics
Jin, Y., Lei, Z., Taynton, P., Huang, S., & Zhang, W. (2019) · Matter · doi:10.1016/j.matt.2019.09.004 · Cited by 359
Self-citationAzcune, I., & Odriozola, I. (2016) · European Polymer Journal · doi:10.1016/j.eurpolymj.2016.09.023 · Cited by 339
Delahaye, M., Winne, J. M., & Du Prez, F. E. (2019) · Journal of the American Chemical Society · doi:10.1021/jacs.9b07269 · Cited by 334
Imbernon, L., Oikonomou, E. K., Norvez, S., & Leibler, L. (2015) · Polymer Chemistry · doi:10.1039/c5py00459d · Cited by 329
Self-healing polyurethane with high strength and toughness based on a dynamic chemical strategy
Dong, F., Yang, X., Guo, L., Wang, Y., Shaghaleh, H., Huang, Z., Xu, X., Wang, S., & Liu, H. (2022) · Journal of Materials Chemistry A · doi:10.1039/d2ta00802e · Cited by 285
Elastic vitrimers: Beyond thermoplastic and thermoset elastomers
Luo, J., Demchuk, Z., Zhao, X., Saito, T., Tian, M., Sokolov, A. P., & Cao, P.-F. (2022) · Matter · doi:10.1016/j.matt.2022.04.007 · Cited by 281
High-Performance Lignin-Containing Polyurethane Elastomers with Dynamic Covalent Polymer Networks
Liu, W., Fang, C., Wang, S., Huang, J., & Qiu, X. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01413 · Cited by 258
Liu, Y.-Y., Liu, G.-L., Li, Y.-D., Weng, Y., & Zeng, J.-B. (2021) · ACS Sustainable Chemistry & Engineering · doi:10.1021/acssuschemeng.1c00231 · Cited by 257
Vitrimer composites: current status and future challenges
Schenk, V., Labastie, K., Destarac, M., Olivier, P., & Guerre, M. (2022) · Materials Advances · doi:10.1039/d2ma00654e · Cited by 253
Zhang, Z. P., Rong, M. Z., & Zhang, M. Q. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201706050 · Cited by 208
Self-citationDegradable epoxy resins prepared from diepoxide monomer with dynamic covalent disulfide linkage
Takahashi, A., Ohishi, T., Goseki, R., & Otsuka, H. (2016) · Polymer · doi:10.1016/j.polymer.2015.11.057 · Cited by 177
Recyclable and repolymerizable thiol–X photopolymers
Wang, C., Goldman, T. M., Worrell, B. T., McBride, M. K., Alim, M. D., & Bowman, C. N. (2018) · Materials Horizons · doi:10.1039/c8mh00724a · Cited by 81
Metadata
- Authors
- Lei, Z. Q., Xiang, H. P., Yuan, Y. J., Rong, M. Z., & Zhang, M. Q.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-04
- Volume
- 26
- Issue
- 6
- Pages
- 2038-2046
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W2047074031
- Cited by
- 578
- References
- 29
- FWCI
- 20.02
- Type
- journal article
- Language
- en
- Open access
- closed
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