The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Contribution of Functional Groups to the Raman Spectrum of Nanodiamond Powders
Abstract
In depth understanding of Raman spectra of carbon nanomaterials led to the extension of this technique from simple carbon allotrope detection (fingerprinting) to analysis of the dimensions and ordering of graphene, graphite and nanotubes. In characterization of nanodiamond powders, which have been attracting attention as one of the most promising carbon nanomaterials, Raman spectroscopy is still mainly used only for detecting the diamond phase because of poor understanding of other spectral features. In this paper, we critically examine different explanations of the broad asymmetric Raman band between 1500 and 1800 cm −1 present in all nanodiamond powders and provide an assignment of the contributing peaks, solving one of the major remaining mysteries in Raman spectroscopy of nanodiamond. By using nanodiamond powders with different and well-controlled surface chemistries, as well as in situ Raman measurements at elevated temperatures, we show that these peaks originate from O−H bending vibrations either from the surface functional groups or adsorbed water with contributions (shoulders) coming from sp 2 carbon and C═O stretching vibrations. The observation of a strong O−H contribution to the Raman spectrum of nanodiamond raises concerns regarding the use of water as a coolant during the Raman spectra acquisition, because water may affect Raman spectra in the wavenumber ranges corresponding to bending and stretching O−H vibrations.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Tuinstra, F., & Koenig, J. L. (1970) · The Journal of Chemical Physics · doi:10.1063/1.1674108 · Cited by 10,717
Ferrari, A. C. (2007) · Solid State Communications · doi:10.1016/j.ssc.2007.03.052 · Cited by 7,606
Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond
Ferrari, A. C., & Robertson, J. (2004) · Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2004.1452 · Cited by 2,689
Diameter-Selective Raman Scattering from Vibrational Modes in Carbon Nanotubes
Rao, A. M., Richter, E., Bandow, S., Chase, B., Eklund, P. C., Williams, K. A., Fang, S., Subbaswamy, K. R., Menon, M., Thess, A., et al. (1997) · Science · doi:10.1126/science.275.5297.187 · Cited by 2,077
Raman spectroscopy of graphite
Reich, S., & Thomsen, C. (2004) · Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2004.1454 · Cited by 1,312
Origin of the1150−cm−1Raman mode in nanocrystalline diamond
Ferrari, A. C., & Robertson, J. (2001) · Physical Review B · doi:10.1103/physrevb.63.121405 · Cited by 1,176
Osswald, S., Yushin, G., Mochalin, V., Kucheyev, S. O., & Gogotsi, Y. (2006) · Journal of the American Chemical Society · doi:10.1021/ja063303n · Cited by 918
Self-citationShenderova, O. A., Zhirnov, V. V., & Brenner, D. W. (2002) · Critical Reviews in Solid State and Materials Sciences · doi:10.1080/10408430208500497 · Cited by 797
Raman spectroscopy of diamond and doped diamond
Prawer, S., & Nemanich, R. J. (2004) · Philosophical Transactions of the Royal Society of London. Series A: Mathematical, Physical and Engineering Sciences · doi:10.1098/rsta.2004.1451 · Cited by 661
Monitoring oxidation of multiwalled carbon nanotubes by Raman spectroscopy
Osswald, S., Havel, M., & Gogotsi, Y. (2007) · Journal of Raman Spectroscopy · doi:10.1002/jrs.1686 · Cited by 627
Self-citation
Cited by
The properties and applications of nanodiamonds
Mochalin, V. N., Shenderova, O., Ho, D., & Gogotsi, Y. (2012) · Nature Nanotechnology · doi:10.1038/nnano.2011.209 · Cited by 2,745
Self-citationGeorgakilas, V., Perman, J. A., Tucek, J., & Zboril, R. (2015) · Chemical Reviews · doi:10.1021/cr500304f · Cited by 2,147
Functionality is Key: Recent Progress in the Surface Modification of Nanodiamond
Krueger, A., & Lang, D. (2012) · Advanced Functional Materials · doi:10.1002/adfm.201102670 · Cited by 584
Wet Chemistry Route to Hydrophobic Blue Fluorescent Nanodiamond
Mochalin, V. N., & Gogotsi, Y. (2009) · Journal of the American Chemical Society · doi:10.1021/ja9004514 · Cited by 403
Self-citationPhonon confinement effects in the Raman spectrum of nanodiamond
Osswald, S., Mochalin, V. N., Havel, M., Yushin, G., & Gogotsi, Y. (2009) · Physical Review B · doi:10.1103/physrevb.80.075419 · Cited by 256
Self-citation
Metadata
- Authors
- Mochalin, V., Osswald, S., & Gogotsi, Y.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 2008-12-30
- Volume
- 21
- Issue
- 2
- Pages
- 273-279
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1981581064
- Cited by
- 279
- References
- 17
- FWCI
- 3.37
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
How to cite
Cite CoChat for the checks on this page, and the paper for its own findings.
- This page
- CoChat. (2026). Citation check: Contribution of Functional Groups to the Raman Spectrum of Nanodiamond Powders. https://app.cochat.ai/papers/10.1021/cm802057q
- The paper
- Mochalin, V., Osswald, S., & Gogotsi, Y. (2009). Contribution of Functional Groups to the Raman Spectrum of Nanodiamond Powders. Chemistry of Materials. https://doi.org/10.1021/cm802057q
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
