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Efficient, Saturated Red Organic Light Emitting Devices Based on Phosphorescent Platinum(II) Porphyrins
Abstract
Two new platinum(II) porphyrins have been synthesized and their luminescent properties have been studied. The platinum porphyrins exhibited strong phosphorescence in the red with narrow line widths. When they were doped into aluminum(III) tris(8-hydroxyquinolate) (AlQ 3 ) in the electron-transporting and -emitting layer of an organic light-emitting device, energy transfer occurred between the host AlQ 3 and the platinum porphyrin. Bright saturated red emission with high efficiency at low to moderate current density has been achieved. In the high current regime, the electroluminescence efficiency decreased and the perceived emission color blue shifted as a result of mixed emission from the platinum porphyrin and AlQ 3 . This current dependence was due to the saturation of triplet emissive sites, because of the long-lived phosphorescence state of the platinum porphyrin complex.
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Cited by
Umeyama, T., Takamatsu, T., Tezuka, N., Matano, Y., Araki, Y., Wada, T., Yoshikawa, O., Sagawa, T., Yoshikawa, S., & Imahori, H. (2009) · The Journal of Physical Chemistry C · doi:10.1021/jp902001z · Cited by 119
Photosensitizing porphyrin–triazine compound for bulk heterojunction solar cells
Luechai, A., Gasiorowski, J., Petsom, A., Neugebauer, H., Sariciftci, N. S., & Thamyongkit, P. (2012) · Journal of Materials Chemistry · doi:10.1039/c2jm33840h · Cited by 30
On the potential of porphyrin-spiked triarylamine stars for bulk heterojunction solar cells
Kengthanomma, T., Thamyongkit, P., Gasiorowski, J., Ramil, A. M., & Sariciftci, N. S. (2013) · Journal of Materials Chemistry A · doi:10.1039/c3ta11095h · Cited by 24
Reanprayoon, C., Gasiorowski, J., Sukwattanasinitt, M., Sariciftci, N. S., & Thamyongkit, P. (2014) · RSC Adv. · doi:10.1039/c3ra45373a · Cited by 19
Structure–charge transport relationship of 5,15-dialkylated porphyrins
Zhou, L., Xu, Z.-X., Zhou, Y., Feng, Y., Zhou, X.-G., Xiang, H.-F., & Roy, V. A. L. (2012) · Chemical Communications · doi:10.1039/c2cc31137b · Cited by 13
Metadata
- Authors
- Kwong, R. C., Sibley, S., Dubovoy, T., Baldo, M., Forrest, S. R., & Thompson, M. E.
- Venue
- Chemistry of Materials
- Publisher
- American Chemical Society (ACS)
- Published
- 1999-11-24
- Volume
- 11
- Issue
- 12
- Pages
- 3709-3713
- ISSN
- 0897-4756 (ISSN-L)
- 1520-5002
- OpenAlex
- W1987897767
- Cited by
- 308
- References
- 0
- FWCI
- 16.91
- Type
- journal article
- Language
- en
- Open access
- closed
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- CoChat. (2026). Citation check: Efficient, Saturated Red Organic Light Emitting Devices Based on Phosphorescent Platinum(II) Porphyrins. https://app.cochat.ai/papers/10.1021/cm9906248
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- Kwong, R. C., Sibley, S., Dubovoy, T., Baldo, M., Forrest, S. R., & Thompson, M. E. (1999). Efficient, Saturated Red Organic Light Emitting Devices Based on Phosphorescent Platinum(II) Porphyrins. Chemistry of Materials. https://doi.org/10.1021/cm9906248
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