Janus Particles: Synthesis, Self-Assembly, Physical Properties, and Applications

Block Copolymers—Designer Soft Materials

Bates, F. S., & Fredrickson, G. H. (1999) · Physics Today · doi:10.1063/1.882522 · Cited by 3,219

Anisotropy of building blocks and their assembly into complex structures

Glotzer, S. C., & Solomon, M. J. (2007) · Nature Materials · doi:10.1038/nmat1949 · Cited by 2,790

Self-Motile Colloidal Particles: From Directed Propulsion to Random Walk

Howse, J. R., Jones, R. A. L., Ryan, A. J., Gough, T., Vafabakhsh, R., & Golestanian, R. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.048102 · Cited by 2,230

Two-Dimensional Interfacial Colloidal Crystals

Pieranski, P. (1980) · Physical Review Letters · doi:10.1103/physrevlett.45.569 · Cited by 1,392

Directed self-assembly of a colloidal kagome lattice

Chen, Q., Bae, S. C., & Granick, S. (2011) · Nature · doi:10.1038/nature09713 · Cited by 1,223

Dumbbell-like Bifunctional Au−Fe3O4 Nanoparticles

Yu, H., Chen, M., Rice, P. M., Wang, S. X., White, R. L., & Sun, S. (2005) · Nano Letters · doi:10.1021/nl047955q · Cited by 1,222

Nanogap-engineerable Raman-active nanodumbbells for single-molecule detection

Lim, D.-K., Jeon, K.-S., Kim, H. M., Nam, J.-M., & Suh, Y. D. (2010) · Nature Materials · doi:10.1038/nmat2596 · Cited by 1,189

Continuous-flow lithography for high-throughput microparticle synthesis

Dendukuri, D., Pregibon, D. C., Collins, J., Hatton, T. A., & Doyle, P. S. (2006) · Nature Materials · doi:10.1038/nmat1617 · Cited by 1,040

General Strategies for Nanoparticle Dispersion

Mackay, M. E., Tuteja, A., Duxbury, P. M., Hawker, C. J., Van Horn, B., Guan, Z., Chen, G., & Krishnan, R. S. (2006) · Science · doi:10.1126/science.1122225 · Cited by 960

Template-Assisted Self-Assembly: A Practical Route to Complex Aggregates of Monodispersed Colloids with Well-Defined Sizes, Shapes, and Structures

Yin, Y., Lu, Y., Gates, B., & Xia, Y. (2001) · Journal of the American Chemical Society · doi:10.1021/ja011048v · Cited by 915

Janus Particle Synthesis and Assembly

Jiang, S., Chen, Q., Tripathy, M., Luijten, E., Schweizer, K. S., & Granick, S. (2010) · Advanced Materials · doi:10.1002/adma.200904094 · Cited by 803

Lock and key colloids

Sacanna, S., Irvine, W. T. M., Chaikin, P. M., & Pine, D. J. (2010) · Nature · doi:10.1038/nature08906 · Cited by 793

Aggregation and vesiculation of membrane proteins by curvature-mediated interactions

Reynwar, B. J., Illya, G., Harmandaris, V. A., Müller, M. M., Kremer, K., & Deserno, M. (2007) · Nature · doi:10.1038/nature05840 · Cited by 761

Colloidal Assembly: The Road from Particles to Colloidal Molecules and Crystals

Li, F., Josephson, D. P., & Stein, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201001451 · Cited by 737

Self-Assembly of Janus Dendrimers into Uniform Dendrimersomes and Other Complex Architectures

Percec, V., Wilson, D. A., Leowanawat, P., Wilson, C. J., Hughes, A. D., Kaucher, M. S., Hammer, D. A., Levine, D. H., Kim, A. J., Bates, F. S., et al. (2010) · Science · doi:10.1126/science.1185547 · Cited by 732

Multifunctional Encoded Particles for High-Throughput Biomolecule Analysis

Pregibon, D. C., Toner, M., & Doyle, P. S. (2007) · Science · doi:10.1126/science.1134929 · Cited by 726

Biphasic Janus particles with nanoscale anisotropy

Roh, K.-H., Martin, D. C., & Lahann, J. (2005) · Nature Materials · doi:10.1038/nmat1486 · Cited by 725

Synthesis of Monodisperse Bicolored Janus Particles with Electrical Anisotropy Using a Microfluidic Co‐Flow System

Nisisako, T., Torii, T., Takahashi, T., & Takizawa, Y. (2006) · Advanced Materials · doi:10.1002/adma.200502431 · Cited by 724

Hydrophobins: Multipurpose Proteins

Wösten, H. A. B. (2001) · Annual Review of Microbiology · doi:10.1146/annurev.micro.55.1.625 · Cited by 704

An Efficient Bicomponent TiO2/SnO2 Nanofiber Photocatalyst Fabricated by Electrospinning with a Side-by-Side Dual Spinneret Method

Liu, Z., Sun, D. D., Guo, P., & Leckie, J. O. (2007) · Nano Letters · doi:10.1021/nl061898e · Cited by 694

Colloidal heterostructured nanocrystals: Synthesis and growth mechanisms

Carbone, L., & Cozzoli, P. D. (2010) · Nano Today · doi:10.1016/j.nantod.2010.08.006 · Cited by 691

Janus and Ternary Particles Generated by Microfluidic Synthesis: Design, Synthesis, and Self-Assembly

Nie, Z., Li, W., Seo, M., Xu, S., & Kumacheva, E. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060882n · Cited by 689

Self-Assembly of Mesoscopic Metal-Polymer Amphiphiles

Park, S., Lim, J.-H., Chung, S.-W., & Mirkin, C. A. (2004) · Science · doi:10.1126/science.1093276 · Cited by 668

Hydrophobins: the protein-amphiphiles of filamentous fungi

Linder, M. B., Szilvay, G. R., Nakari-Setälä, T., & Penttilä, M. E. (2005) · FEMS Microbiology Reviews · doi:10.1016/j.femsre.2005.01.004 · Cited by 657

The Synthesis and Assembly of Polymeric Microparticles Using Microfluidics

Dendukuri, D., & Doyle, P. S. (2009) · Advanced Materials · doi:10.1002/adma.200803386 · Cited by 654

In pursuit of propulsion at the nanoscale

Ebbens, S. J., & Howse, J. R. (2010) · Soft Matter · doi:10.1039/b918598d · Cited by 639

Autonomous Movement and Self-Assembly

Ismagilov, R. F., Schwartz, A., Bowden, N., & Whitesides, G. M. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020215)41:4<652::aid-anie652>3.0.co;2-u · Cited by 601

Synthesis, properties and applications of Janus nanoparticles

Lattuada, M., & Hatton, T. A. (2011) · Nano Today · doi:10.1016/j.nantod.2011.04.008 · Cited by 581

Particles Adsorbed at the Oil−Water Interface: A Theoretical Comparison between Spheres of Uniform Wettability and “Janus” Particles

Binks, B. P., & Fletcher, P. D. I. (2001) · Langmuir · doi:10.1021/la0103315 · Cited by 574

Fabrication, Assembly, and Application of Patchy Particles

Pawar, A. B., & Kretzschmar, I. (2010) · Macromolecular Rapid Communications · doi:10.1002/marc.200900614 · Cited by 567

Symmetry and Human Facial Attractiveness

Perrett, D. I., Burt, D. M., Penton-Voak, I. S., Lee, K. J., Rowland, D. A., & Edwards, R. (1999) · Evolution and Human Behavior · doi:10.1016/s1090-5138(99)00014-8 · Cited by 551

Precise hierarchical self-assembly of multicompartment micelles

Gröschel, A. H., Schacher, F. H., Schmalz, H., Borisov, O. V., Zhulina, E. B., Walther, A., & Müller, A. H. E. (2012) · Nature Communications · doi:10.1038/ncomms1707 · Cited by 550

Supracolloidal Reaction Kinetics of Janus Spheres

Chen, Q., Whitmer, J. K., Jiang, S., Bae, S. C., Luijten, E., & Granick, S. (2011) · Science · doi:10.1126/science.1197451 · Cited by 526

Au–Fe3O4 Dumbbell Nanoparticles as Dual‐Functional Probes

Xu, C., Xie, J., Ho, D., Wang, C., Kohler, N., Walsh, E. G., Morgan, J. R., Chin, Y. E., & Sun, S. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200704392 · Cited by 526

Heterodimers of Nanoparticles: Formation at a Liquid−Liquid Interface and Particle-Specific Surface Modification by Functional Molecules

Gu, H., Yang, Z., Gao, J., Chang, C. K., & Xu, B. (2005) · Journal of the American Chemical Society · doi:10.1021/ja045220h · Cited by 518

Anisotropic particles with patchy, multicompartment and Janus architectures: preparation and application

Du, J., & O'Reilly, R. K. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00216j · Cited by 516

Unimolecular micelles and globular amphiphiles: dendritic macromolecules as novel recyclable solubilization agents

Hawker, C. J., Wooley, K. L., & Fréchet, J. M. J. (1993) · J. Chem. Soc., Perkin Trans. 1 · doi:10.1039/p19930001287 · Cited by 513

Efficient Synthesis of Narrowly Dispersed Brush Copolymers and Study of Their Assemblies: The Importance of Side Chain Arrangement

Xia, Y., Olsen, B. D., Kornfield, J. A., & Grubbs, R. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja908379q · Cited by 504

Versatile Bifunctional Magnetic‐Fluorescent Responsive Janus Supraballs Towards the Flexible Bead Display

Yin, S., Wang, C., Yu, Z., Wang, J., Liu, S., & Chen, S. (2011) · Advanced Materials · doi:10.1002/adma.201100203 · Cited by 489

Template‐Assisted Self‐Assembly of Spherical Colloids into Complex and Controllable Structures

Xia, Y., Yin, Y., Lu, Y., & McLellan, J. (2003) · Advanced Functional Materials · doi:10.1002/adfm.200300002 · Cited by 464

Linking synchronization to self-assembly using magnetic Janus colloids

Yan, J., Bloom, M., Bae, S. C., Luijten, E., & Granick, S. (2012) · Nature · doi:10.1038/nature11619 · Cited by 430

Janus Particles at Liquid−Liquid Interfaces

Glaser, N., Adams, D. J., Böker, A., & Krausch, G. (2006) · Langmuir · doi:10.1021/la060693i · Cited by 416

“Janus Beads”: Realization and Behaviour at Water/Oil Interfaces

Casagrande, C., Fabre, P., Raphaël, É., & Veyssié, M. (1989) · Europhysics Letters (EPL) · doi:10.1209/0295-5075/9/3/011 · Cited by 398

Janus Micelles

Erhardt, R., Böker, A., Zettl, H., Kaya, H., Pyckhout-Hintzen, W., Krausch, G., Abetz, V., & Müller, A. H. E. (2001) · Macromolecules · doi:10.1021/ma000670p · Cited by 396

Hydrophobins: Proteins that self assemble at interfaces

Linder, M. B. (2009) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2009.04.001 · Cited by 379

Janus Microspheres for a Highly Flexible and Impregnable Water‐Repelling Interface

Kim, S., Lee, S. Y., & Yang, S. (2010) · Angewandte Chemie · doi:10.1002/ange.201000108 · Cited by 379

Hydrophobins, the fungal coat unravelled

Wösten, H. A. B., & de Vocht, M. L. (2000) · Biochimica et Biophysica Acta (BBA) - Reviews on Biomembranes · doi:10.1016/s0304-4157(00)00002-2 · Cited by 374

Surface-plasmon dispersion and size dependence of Mie resonance: Silver versus simple metals

Liebsch, A. (1993) · Physical Review B · doi:10.1103/physrevb.48.11317 · Cited by 372

Non-Centrosymmetric Cylindrical Micelles by Unidirectional Growth

Rupar, P. A., Chabanne, L., Winnik, M. A., & Manners, I. (2012) · Science · doi:10.1126/science.1221206 · Cited by 369

Chiral colloidal clusters

Zerrouki, D., Baudry, J., Pine, D. J., Chaikin, P. M., & Bibette, J. (2008) · Nature · doi:10.1038/nature07237 · Cited by 368

Fabrication and Wetting Properties of Metallic Half-Shells with Submicron Diameters

Love, J. C., Gates, B. D., Wolfe, D. B., Paul, K. E., & Whitesides, G. M. (2002) · Nano Letters · doi:10.1021/nl025633l · Cited by 360

Amphiphilic Janus Micelles with Polystyrene and Poly(methacrylic acid) Hemispheres

Erhardt, R., Zhang, M., Böker, A., Zettl, H., Abetz, C., Frederik, P., Krausch, G., Abetz, V., & Müller, A. H. E. (2003) · Journal of the American Chemical Society · doi:10.1021/ja028982q · Cited by 359

Clusters of Charged Janus Spheres

Hong, L., Cacciuto, A., Luijten, E., & Granick, S. (2006) · Nano Letters · doi:10.1021/nl061857i · Cited by 355

How a fungus escapes the water to grow into the air

Wösten, H. A. B., van Wetter, M.-A., Lugones, L. G., van der Mei, H. C., Busscher, H. J., & Wessels, J. G. H. (1999) · Current Biology · doi:10.1016/s0960-9822(99)80019-0 · Cited by 346

Phase Separation of Mixed-Composition Self-Assembled Monolayers into Nanometer Scale Molecular Domains

Stranick, S. J., Parikh, A. N., Tao, Y.-T., Allara, D. L., & Weiss, P. S. (1994) · The Journal of Physical Chemistry · doi:10.1021/j100082a040 · Cited by 339

Asymmetric Functionalization of Gold Nanoparticles with Oligonucleotides

Xu, X., Rosi, N. L., Wang, Y., Huo, F., & Mirkin, C. A. (2006) · Journal of the American Chemical Society · doi:10.1021/ja061980b · Cited by 337

Synthetic Tuning of the Catalytic Properties of Au‐Fe3O4 Nanoparticles

Lee, Y., Garcia, M. A., Frey Huls, N. A., & Sun, S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200906130 · Cited by 330

Recent Progress in Syntheses and Applications of Dumbbell‐like Nanoparticles

Wang, C., Xu, C., Zeng, H., & Sun, S. (2009) · Advanced Materials · doi:10.1002/adma.200900320 · Cited by 318

Engineering Nanostructured Polymer Blends with Controlled Nanoparticle Location using Janus Particles

Walther, A., Matussek, K., & Müller, A. H. E. (2008) · ACS Nano · doi:10.1021/nn800108y · Cited by 310

Janus Discs

Walther, A., André, X., Drechsler, M., Abetz, V., & Müller, A. H. E. (2007) · Journal of the American Chemical Society · doi:10.1021/ja068153v · Cited by 309

Spotted vesicles, striped micelles and Janus assemblies induced by ligand binding

Christian, D. A., Tian, A., Ellenbroek, W. G., Levental, I., Rajagopal, K., Janmey, P. A., Liu, A. J., Baumgart, T., & Discher, D. E. (2009) · Nature Materials · doi:10.1038/nmat2512 · Cited by 306

Dielectrophoretic Assembly of Metallodielectric Janus Particles in AC Electric Fields

Gangwal, S., Cayre, O. J., & Velev, O. D. (2008) · Langmuir · doi:10.1021/la8015222 · Cited by 298

Nanocomposites with Spatially Separated Functionalities for Combined Imaging and Magnetolytic Therapy

Hu, S.-H., & Gao, X. (2010) · Journal of the American Chemical Society · doi:10.1021/ja102489q · Cited by 292

Synthesis of Polystyrene−Polylactide Bottlebrush Block Copolymers and Their Melt Self-Assembly into Large Domain Nanostructures

Rzayev, J. (2009) · Macromolecules · doi:10.1021/ma802304y · Cited by 288

Clusters of Amphiphilic Colloidal Spheres

Hong, L., Cacciuto, A., Luijten, E., & Granick, S. (2008) · Langmuir · doi:10.1021/la7030818 · Cited by 283

High-Purity Separation of Gold Nanoparticle Dimers and Trimers

Chen, G., Wang, Y., Tan, L. H., Yang, M., Tan, L. S., Chen, Y., & Chen, H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja900809z · Cited by 282

Microfluidic Assembly of Homogeneous and Janus Colloid-Filled Hydrogel Granules

Shepherd, R. F., Conrad, J. C., Rhodes, S. K., Link, D. R., Marquez, M., Weitz, D. A., & Lewis, J. A. (2006) · Langmuir · doi:10.1021/la060759+ · Cited by 273

Stepwise surface encoding for high-throughput assembly of nanoclusters

Maye, M. M., Nykypanchuk, D., Cuisinier, M., van der Lelie, D., & Gang, O. (2009) · Nature Materials · doi:10.1038/nmat2421 · Cited by 266

Supraparticles and “Janus” Particles Fabricated by Replication of Particle Monolayers at Liquid Surfaces Using a Gel Trapping Technique

Paunov, V. N., & Cayre, O. J. (2004) · Advanced Materials · doi:10.1002/adma.200306476 · Cited by 266

Entropy-Mediated Patterning of Surfactant-Coated Nanoparticles and Surfaces

Singh, C., Ghorai, P. K., Horsch, M. A., Jackson, A. M., Larson, R. G., Stellacci, F., & Glotzer, S. C. (2007) · Physical Review Letters · doi:10.1103/physrevlett.99.226106 · Cited by 265

Catalytic Nanomotors: Self‐Propelled Sphere Dimers

Valadares, L. F., Tao, Y., Zacharia, N. S., Kitaev, V., Galembeck, F., Kapral, R., & Ozin, G. A. (2010) · Small · doi:10.1002/smll.200901976 · Cited by 261

Soft Matter

de Gennes, P. G. (1992) · Science · doi:10.1126/science.256.5056.495 · Cited by 253

Gradient Sensitive Microscopic Probes Prepared by Gold Evaporation and Chemisorption on Latex Spheres

Takei, H., & Shimizu, N. (1997) · Langmuir · doi:10.1021/la9621067 · Cited by 252

Structural basis for rodlet assembly in fungal hydrophobins

Kwan, A. H. Y., Winefield, R. D., Sunde, M., Matthews, J. M., Haverkamp, R. G., Templeton, M. D., & Mackay, J. P. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0505704103 · Cited by 249

Reconfigurable responsive structures assembled from magnetic Janus particles

Smoukov, S. K., Gangwal, S., Márquez, M., et al. (2009) · Soft Matter · doi:10.1039/b814304h · Cited by 242

Optofluidic Synthesis of Electroresponsive Photonic Janus Balls with Isotropic Structural Colors

Kim, S., Jeon, S., Jeong, W. C., Park, H. S., & Yang, S. (2008) · Advanced Materials · doi:10.1002/adma.200801167 · Cited by 230

Controlled Assembly of Eccentrically Encapsulated Gold Nanoparticles

Chen, T., Yang, M., Wang, X., Tan, L. H., & Chen, H. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8040288 · Cited by 218

Microfluidic‐Assisted Synthesis of Polymer Particles

Serra, C. A., & Chang, Z. (2008) · Chemical Engineering & Technology · doi:10.1002/ceat.200800219 · Cited by 215

Preparation and Controlled Self-Assembly of Janus Magnetic Nanoparticles

Lattuada, M., & Hatton, T. A. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0740521 · Cited by 213

Large Pore Size Nanoporous Materials from the Self-Assembly of Asymmetric Bottlebrush Block Copolymers

Bolton, J., Bailey, T. S., & Rzayev, J. (2011) · Nano Letters · doi:10.1021/nl103747m · Cited by 206

Stimuli-Responsive Bicomponent Polymer Janus Particles by “Grafting from”/“Grafting to” Approaches

Berger, S., Synytska, A., Ionov, L., Eichhorn, K., & Stamm, M. (2008) · Macromolecules · doi:10.1021/ma802089h · Cited by 204

Surface Functionalization of Living Cells with Multilayer Patches

Swiston, A. J., Cheng, C., Um, S. H., Irvine, D. J., Cohen, R. E., & Rubner, M. F. (2008) · Nano Letters · doi:10.1021/nl802404h · Cited by 204

Double‐Faced Micelles from Water‐Soluble Polymers

Voets, I. K., de Keizer, A., de Waard, P., Frederik, P. M., Bomans, P. H. H., Schmalz, H., Walther, A., King, S. M., Leermakers, F. A. M., & Stuart, M. A. C. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200601000 · Cited by 201

Harnessing Janus Nanoparticles to Create Controllable Pores in Membranes

Alexeev, A., Uspal, W. E., & Balazs, A. C. (2008) · ACS Nano · doi:10.1021/nn8000998 · Cited by 198

Creating Surfactant Nanoparticles for Block Copolymer Composites through Surface Chemistry

Kim, B. J., Bang, J., Hawker, C. J., Chiu, J. J., Pine, D. J., Jang, S. G., Yang, S.-M., & Kramer, E. J. (2007) · Langmuir · doi:10.1021/la701906n · Cited by 195

Versatile Solid Phase Synthesis of Gold Nanoparticle Dimers Using an Asymmetric Functionalization Approach

Sardar, R., Heap, T. B., & Shumaker-Parry, J. S. (2007) · Journal of the American Chemical Society · doi:10.1021/ja070933w · Cited by 189

Creating electrical contacts between metal particles using directed electrochemical growth

Bradley, J., Chen, H.-M., Crawford, J., Eckert, J., Ernazarova, K., Kurzeja, T., Lin, M., McGee, M., Nadler, W., & Stephens, S. G. (1997) · Nature · doi:10.1038/38464 · Cited by 186

Hydrophobins: proteins with potential

Hektor, H. J., & Scholtmeijer, K. (2005) · Current Opinion in Biotechnology · doi:10.1016/j.copbio.2005.05.004 · Cited by 179

Amphiphilicity-Driven Organization of Nanoparticles into Discrete Assemblies

Zubarev, E. R., Xu, J., Sayyad, A. S., & Gibson, J. D. (2006) · Journal of the American Chemical Society · doi:10.1021/ja066708g · Cited by 179

Self-Assembly of Janus Cylinders into Hierarchical Superstructures

Walther, A., Drechsler, M., Rosenfeldt, S., Harnau, L., Ballauff, M., Abetz, V., & Müller, A. H. E. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808614q · Cited by 178

Interfacial Engineering by Proteins: Exfoliation and Functionalization of Graphene by Hydrophobins

Laaksonen, P. H., Kainlauri, M., Laaksonen, T., Shchepetov, A., Jiang, H., Ahopelto, J., & Linder, M. B. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201001806 · Cited by 177

Scalable Routes to Janus Au−SiO 2 and Ternary Ag−Au−SiO 2 Nanoparticles

Chen, T., Chen, G., Xing, S., Wu, T., & Chen, H. (2010) · Chemistry of Materials · doi:10.1021/cm101155v · Cited by 176

Multifunctional Patchy Particles by Glancing Angle Deposition

Pawar, A. B., & Kretzschmar, I. (2009) · Langmuir · doi:10.1021/la900809b · Cited by 176

One-Step Fabrication of Polymeric Janus Nanoparticles for Drug Delivery

Xie, H. M., She, Z., Wang, S., Sharma, G., & Smith, J. W. (2012) · Langmuir · doi:10.1021/la2042185 · Cited by 166

Genetic Engineering of Biomimetic Nanocomposites: Diblock Proteins, Graphene, and Nanofibrillated Cellulose

Laaksonen, P. H., Walther, A., Malho, J., Kainlauri, M., Ikkala, O. T., & Linder, M. B. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201102973 · Cited by 165

Synthesis and Self-Assembly of Amphiphilic Polymeric Microparticles

Dendukuri, D., Hatton, T. A., & Doyle, P. S. (2007) · Langmuir · doi:10.1021/la062512i · Cited by 162

Janus Microspheres for a Highly Flexible and Impregnable Water‐Repelling Interface

Kim, S., Lee, S. Y., & Yang, S. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000108 · Cited by 162

Towards Designer Microparticles: Simultaneous Control of Anisotropy, Shape, and Size

Bhaskar, S., Pollock, K. M., Yoshida, M., & Lahann, J. (2010) · Small · doi:10.1002/smll.200901306 · Cited by 162

Synthesis of Hetero-Grafted Amphiphilic Diblock Molecular Brushes and Their Self-Assembly in Aqueous Medium

Zhou, L., Ma, J., Cheng, C., Zhang, K., & Wooley, K. L. (2010) · Macromolecules · doi:10.1021/ma902513n · Cited by 160

Thermo-Reversible Formation of Wormlike Micelles with a Microphase-Separated Corona from a Semicrystalline Triblock Terpolymer

Schmalz, H., Schmelz, J., Drechsler, M., Yuan, J., Walther, A., Schweimer, K., & Mihut, A. M. (2008) · Macromolecules · doi:10.1021/ma702417y · Cited by 159

Janus Nanoparticles by Interfacial Engineering

Pradhan, S., Xu, L., & Chen, S. (2007) · Advanced Functional Materials · doi:10.1002/adfm.200601034 · Cited by 153

Triphasic Nanocolloids

Roh, K., Martin, D. C., & Lahann, J. (2006) · Journal of the American Chemical Society · doi:10.1021/ja060836n · Cited by 146

Molecular Mimetic Self‐Assembly of Colloidal Particles

Mao, Z., Xu, H., & Wang, D. (2010) · Advanced Functional Materials · doi:10.1002/adfm.200902076 · Cited by 145

Programmed assembly of metallodielectric patchy particles in external AC electric fields

Gangwal, S., Pawar, A. B., Kretzschmar, I., & Velev, O. D. (2010) · Soft Matter · doi:10.1039/b925713f · Cited by 143

Generation of Monodisperse Inorganic–Organic Janus Microspheres in a Microfluidic Device

Prasad, B. S. N., Perumal, J., Choi, C., Lee, C., & Kim, D. (2009) · Advanced Functional Materials · doi:10.1002/adfm.200801181 · Cited by 139

Janus balance of amphiphilic colloidal particles

Jiang, S., & Granick, S. (2007) · The Journal of Chemical Physics · doi:10.1063/1.2803420 · Cited by 138

Asymmetrically Functionalized Gold Nanoparticles Organized in One-Dimensional Chains

Sardar, R., & Shumaker‐Parry, J. S. (2008) · Nano Letters · doi:10.1021/nl073154m · Cited by 138

Fabrication of dipolar colloid particles by microcontact printing

Cayre, O. J., Paunov, V. N., & Velev, O. D. (2003) · Chemical Communications · doi:10.1039/b307296g · Cited by 138

Self-Assembly of Janus Nanoparticles in Diblock Copolymers

Yan, L., Popp, N. R. H., Ghosh, S.-K., & Böker, A. (2010) · ACS Nano · doi:10.1021/nn901739v · Cited by 137

Water-Repellent Textile via Decorating Fibers with Amphiphilic Janus Particles

Synytska, A., Khanum, R., Ionov, L., Cherif, C., & Bellmann, C. (2011) · ACS Applied Materials & Interfaces · doi:10.1021/am200033u · Cited by 132

Rapid Fabrication of Bimetallic Spherical Motors

Wheat, P. M., Marine, N. A., Moran, J. L., & Posner, J. D. (2010) · Langmuir · doi:10.1021/la102218w · Cited by 128

Adsorption of Disk-Shaped Janus Beads at Liquid−Liquid Interfaces

Nonomura, Y., Komura, S., & Tsujii, K. (2004) · Langmuir · doi:10.1021/la0480540 · Cited by 127

Accurate Determination of Elastic Parameters for Multicomponent Membranes

Semrau, S., Idema, T., Holtzer, L., Schmidt, T., & Storm, C. (2008) · Physical Review Letters · doi:10.1103/physrevlett.100.088101 · Cited by 126

The Mason-Pfizer Monkey Virus PPPY and PSAP Motifs Both Contribute to Virus Release

Gottwein, E., Bodem, J., Müller, B., Schmechel, A., Zentgraf, H., & Kräusslich, H. (2003) · Journal of Virology · doi:10.1128/jvi.77.17.9474-9485.2003 · Cited by 124

Janus Droplets: Liquid Marbles Coated with Dielectric/Semiconductor Particles

Bormashenko, E. Y., Bormashenko, Y., Pogreb, R., et al. (2010) · Langmuir · doi:10.1021/la103653p · Cited by 124

Undulated Multicompartment Cylinders by the Controlled and Directed Stacking of Polymer Micelles with a Compartmentalized Corona

Fang, B., Walther, A., Wolf, A. M., Xu, Y., Yuan, J., & Müller, A. H. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806051 · Cited by 123

Mixed Micelle Formation through Stereocomplexation between Enantiomeric Poly(lactide) Block Copolymers

Kim, S. H., Tan, J. P. K., Nederberg, F., Fukushima, K., Yang, Y. Y., Waymouth, R. M., & Hedrick, J. L. (2008) · Macromolecules · doi:10.1021/ma801739x · Cited by 121

Multicompartmental Microcylinders

Bhaskar, S., Hitt, J., Chang, S. L., & Lahann, J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200806241 · Cited by 119

Patterned Fluorescent Particles as Nanoprobes for the Investigation of Molecular Interactions

Choi, J., Zhao, Y., Zhang, D., Chien, S., & Lo, Y.-H. (2003) · Nano Letters · doi:10.1021/nl034106e · Cited by 118

Asymmetric Functionalization of Nanoparticles Based on Thermally Addressable DNA Interconnects

Huo, F., Lytton‐Jean, A. K. R., & Mirkin, C. A. (2006) · Advanced Materials · doi:10.1002/adma.200601178 · Cited by 117

Structurally Controlled Bio‐hybrid Materials Based on Unidirectional Association of Anisotropic Microparticles with Human Endothelial Cells

Yoshida, M., Roh, K., Mandal, S., Bhaskar, S., Lim, D., Nandivada, H., Deng, X., & Lahann, J. (2009) · Advanced Materials · doi:10.1002/adma.200901971 · Cited by 116

Well-Defined Brush Copolymers with High Grafting Density of Amphiphilic Side Chains by Combination of ROP, ROMP, and ATRP

Xie, M., Dang, J., Han, H., Wang, W., Liu, J., He, X., & Zhang, Y. (2008) · Macromolecules · doi:10.1021/ma801408s · Cited by 115

Novel Amphiphilic Centipede-Like Copolymer Bearing Polyacrylate Backbone and Poly(ethylene glycol) and Polystyrene Side Chains

Gu, L., Shen, Z., Zhang, S., Lu, G., Zhang, X., & Huang, X. (2007) · Macromolecules · doi:10.1021/ma062083v · Cited by 114

Membrane heterogeneity – from lipid domains to curvature effects

Semrau, S., & Schmidt, T. (2009) · Soft Matter · doi:10.1039/b901587f · Cited by 112

Layer-by-Layer Assembled Janus Microcapsules

Li, Z., Lee, D., Rubner, M. F., & Cohen, R. E. (2005) · Macromolecules · doi:10.1021/ma0513012 · Cited by 110

Staged Self-Assembly of Colloidal Metastructures

Chen, Q., Bae, S. C., & Granick, S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja303434d · Cited by 103

Multiple Morphologies, Phase Transitions, and Cross-Linking of Crew-Cut Aggregates of Polybutadiene-block-poly(2-vinylpyridine) Diblock Copolymers

Walther, A., Goldmann, A. S., Yelamanchili, R. S., Drechsler, M., Schmalz, H., Eisenberg, A., & Müller, A. H. E. (2008) · Macromolecules · doi:10.1021/ma7026148 · Cited by 96

Towards Holonomic Control of Janus Particles in Optomagnetic Traps

Erb, R. M., Jenness, N. J., Clark, R. L., & Yellen, B. B. (2009) · Advanced Materials · doi:10.1002/adma.200900892 · Cited by 96

Hetero-Grafted Block Brushes with PCL and PBA Side Chains

Lee, H., Matyjaszewski, K. A., Yu-Su, S. Y., & Sheiko, S. S. (2008) · Macromolecules · doi:10.1021/ma800412s · Cited by 93

Mixed, Multicompartment, or Janus Micelles? A Systematic Study of Thermoresponsive Bis-Hydrophilic Block Terpolymers

Walther, A., Barner‐Kowollik, C., & Müller, A. H. E. (2010) · Langmuir · doi:10.1021/la101173b · Cited by 92

Janus Colloidal Matchsticks

Chaudhary, K., Chen, Q., Juárez, J. J., et al. (2012) · Journal of the American Chemical Society · doi:10.1021/ja305067g · Cited by 86

Hydrodynamic Focusing Lithography

Bong, K. W., Bong, K. W., Pregibon, D. C., & Doyle, P. S. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200905229 · Cited by 86

Lock release lithography for 3D and composite microparticles

Bong, K. W., Pregibon, D. C., & Doyle, P. S. (2009) · Lab on a Chip · doi:10.1039/b821930c · Cited by 84

ABC triblock copolymer hamburger-like micelles, segmented cylinders, and Janus particles

DuPont, J. G., & Liu, G. (2010) · Soft Matter · doi:10.1039/c0sm00044b · Cited by 82

Spontaneous symmetry breaking: formation of Janus micelles

Voets, I. K., Fokkink, R. G., Hellweg, T., King, S. M., de Waard, P., de Keizer, A., & Stuart, M. A. C. (2008) · Soft Matter · doi:10.1039/b812793j · Cited by 81

Microfluidic Generation and Selective Degradation of Biopolymer-Based Janus Microbeads

Marquis, M., Renard, D., & Cathala, B. (2012) · Biomacromolecules · doi:10.1021/bm300159u · Cited by 80

Self-assembly of cellulose nanofibrils by genetically engineered fusion proteins

Arola, S., Laaksonen, P. H., Paananen, A., Valo, H., Hähl, H., Laaksonen, T., & Linder, M. B. (2011) · Soft Matter · doi:10.1039/c0sm01114b · Cited by 77

Synthesis and Characterization of Janus Gold Nanoparticles

Kim, H., Carney, R. P., Reguera, J., Ong, Q. K., Liu, X., & Stellacci, F. (2012) · Advanced Materials · doi:10.1002/adma.201200926 · Cited by 75

Surface-Anisotropic Polystyrene Spheres by Electroless Deposition

Cui, J., & Kretzschmar, I. (2006) · Langmuir · doi:10.1021/la061742u · Cited by 70

Relation between Molecular Shape and the Morphology of Self-Assembling Aggregates: A Simulation Study

Vácha, R., & Frenkel, D. (2011) · Biophysical Journal · doi:10.1016/j.bpj.2011.07.046 · Cited by 68

Synthesis and supramolecular self-assembly of stimuli-responsive water-soluble Janus-type heteroarm star copolymers

Ge, Z., Xu, J., Hu, J., Zhang, Y., & Liu, S. (2009) · Soft Matter · doi:10.1039/b907906h · Cited by 68

Mixed Molecular Brushes with PLLA and PS Side Chains Prepared by AGET ATRP and Ring-Opening Polymerization

Wu, D., Yang, Y., Cheng, X., Liu, L., Tian, J., & Zhao, H. (2006) · Macromolecules · doi:10.1021/ma061141+ · Cited by 66

One‐Pot Colloidal Synthesis of Plasmonic Patchy Particles

Bao, H., Peukert, W., & Taylor, R. N. K. (2011) · Advanced Materials · doi:10.1002/adma.201100698 · Cited by 66

Fabrication of multiphasic and regio-specifically functionalized PRINT®particles of controlled size and shape

Zhang, H., Nunes, J. K., Gratton, S. E. A., Herlihy, K. P., Pohlhaus, P. D., & DeSimone, J. M. (2009) · New Journal of Physics · doi:10.1088/1367-2630/11/7/075018 · Cited by 66

Monofunctional Group-Modified Gold Nanoparticles from Solid Phase Synthesis Approach: Solid Support and Experimental Condition Effect

Worden, J. G., Dai, Q. L., Shaffer, A. W., & Huo, Q. (2004) · Chemistry of Materials · doi:10.1021/cm048907+ · Cited by 65

“Ball at the wall” — A new lamellar multiphase morphology in a polystyrene‐block‐polybutadiene‐block‐poly(methyl methacrylate) triblock copolymer

Beckmann, J., Auschra, C., & Stadler, R. (1994) · Macromolecular Rapid Communications · doi:10.1002/marc.1994.030150111 · Cited by 64

Thermoresponsive Amphiphilic Janus Silica Nanoparticles via Combining “Polymer Single-Crystal Templating” and “Grafting-from” Methods

Zhou, T., Wang, X., Dong, B., et al. (2012) · Macromolecules · doi:10.1021/ma3019987 · Cited by 64

Spatioselective Modification of Bicompartmental Polymer Particles and Fibers via Huisgen 1,3‐Dipolar Cycloaddition

Bhaskar, S., Roh, K., Jiang, X., Baker, G. L., & Lahann, J. (2008) · Macromolecular Rapid Communications · doi:10.1002/marc.200800459 · Cited by 60

Bisfunctionalized Janus Molecules

Ropponen, J., Nummelin, S., & Rissanen, K. T. (2004) · Organic Letters · doi:10.1021/ol049555f · Cited by 60

Amphiphilic Dual Brush Block Copolymers as “Giant Surfactants” and Their Aqueous Self-Assembly

Zehm, D., Laschewsky, A., Gradzielski, M., Prévost, S. F., Liang, H., Rabe, J. P., Schweins, R., & Gummel, J. (2009) · Langmuir · doi:10.1021/la903087p · Cited by 60

Interplay between Chain Collapse and Microphase Separation in Bottle-Brush Polymers with Two Types of Side Chains

Theodorakis, P. E., Paul, W., & Binder, K. (2010) · Macromolecules · doi:10.1021/ma100414u · Cited by 60

Orthogonally Dual-Clickable Janus Nanoparticles via a Cyclic Templating Strategy

Zhang, S., Li, Z., Samarajeewa, S., Sun, G., Yang, C., & Wooley, K. L. (2011) · Journal of the American Chemical Society · doi:10.1021/ja203133h · Cited by 57

Self-assembled film of hydrophobins on gold surfaces and its application to electrochemical biosensing

Zhao, Z., Wang, H.-C., Qin, X., et al. (2009) · Colloids and Surfaces B Biointerfaces · doi:10.1016/j.colsurfb.2009.01.011 · Cited by 56

Mixed versus Ordinary Micelles in the Dilute Solution of AB and BC Diblock Copolymers

Palyulin, V. V., & Potemkin, I. I. (2008) · Macromolecules · doi:10.1021/ma8003949 · Cited by 50

Smart Organic/Inorganic Hybrid Nanoobjects with Controlled Shapes by Self-Assembly of Gelable Block Copolymers

Zhang, K., Gao, L., & Chen, Y. (2008) · Macromolecules · doi:10.1021/ma7021698 · Cited by 46

Bis-Hydrophilic Block Terpolymers via RAFT Polymerization: Toward Dynamic Micelles with Tunable Corona Properties

Walther, A., Millard, P., Goldmann, A. S., Lovestead, T. M., Schacher, F. H., Barner‐Kowollik, C., & Müller, A. H. E. (2008) · Macromolecules · doi:10.1021/ma801215q · Cited by 46

Synthesis of (Poly(chloroethyl vinyl ether)- g -polystyrene)comb- b -(poly(chloropyran ethoxy vinyl ether)- g -polyisoprene)comb Copolymers and Study of Hyper-Branched Micelle Formation in Dilute Solutions

Lanson, D., Schappacher, M., Borsali, R., & Deffieux, A. (2007) · Macromolecules · doi:10.1021/ma0704414 · Cited by 44

Probing the Self-Assembly and the Accompanying Structural Changes of Hydrophobin SC3 on a Hydrophobic Surface by Mass Spectrometry

Wang, X., Permentier, H. P., Rink, R., et al. (2004) · Biophysical Journal · doi:10.1529/biophysj.104.041616 · Cited by 42

Directed Assembly of Janus Particles under High Frequency ac-Electric Fields: Effects of Medium Conductivity and Colloidal Surface Chemistry

Zhang, L., & Zhu, Y. (2012) · Langmuir · doi:10.1021/la302725v · Cited by 41

Organic/inorganic nanoobjects with controlled shapes from gelable triblock copolymers

Zhang, K., Gao, L., & Chen, Y. (2010) · Polymer · doi:10.1016/j.polymer.2010.04.042 · Cited by 40

Polystyrene−Polylactide Bottlebrush Block Copolymer at the Air/Water Interface

Zhao, L., Byun, M., Rzayev, J., & Lin, Z. (2009) · Macromolecules · doi:10.1021/ma9016345 · Cited by 39

Directed self-assembly of Janus nanorods in binary polymer mixture: towards precise control of nanorod orientation relative to interface

Xu, K., Guo, R., Dong, B., & Yan, L. (2012) · Soft Matter · doi:10.1039/c2sm26193f · Cited by 37

Conformational Aspects and Intramolecular Phase Separation of Alternating Copolymacromonomers: A Computer Simulation Study

de Jong, J., & ten Brinke, G. (2004) · Macromolecular Theory and Simulations · doi:10.1002/mats.200300052 · Cited by 28

Sequential functionalization of janus‐type dendrimer‐like poly(ethylene oxide)s with camptothecin and folic acid

Feng, X., Pinaud, J., Chaikof, E. L., Taton, D., & Gnanou, Y. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24718 · Cited by 26

Self-Assembly of the AB/BC Diblock Copolymer Mixture Based on Hydrogen Bonding in a Selective Solvent: A Monte Carlo Study

Han, Y., & Jiang, W. J. (2011) · The Journal of Physical Chemistry B · doi:10.1021/jp1106313 · Cited by 26

Thermodynamics versus Kinetics in Nanosynthesis

Wang, Y., He, J., Liu, C., Chong, W. H., & Chen, H. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201402986 · Cited by 497

Surface-Initiated Polymerization as an Enabling Tool for Multifunctional (Nano-)Engineered Hybrid Materials

Hui, C. M., Pietrasik, J., Schmitt, M., Mahoney, C., Choi, J., Bockstaller, M. R., & Matyjaszewski, K. (2014) · Chemistry of Materials · doi:10.1021/cm4023634 · Cited by 367

Electrospun amorphous solid dispersions of poorly water-soluble drugs: A review

Yu, D.-G., Li, J.-J., Williams, G. R., & Zhao, M. (2018) · Journal of Controlled Release · doi:10.1016/j.jconrel.2018.08.016 · Cited by 341

pH-Responsive PDMS- b -PDMAEMA Micelles for Intracellular Anticancer Drug Delivery

Car, A., Baumann, P., Duskey, J. T., Chami, M., Bruns, N., & Meier, W. (2014) · Biomacromolecules · doi:10.1021/bm500919z · Cited by 113

Compatibilization of Immiscible Polymer Blends Using in Situ Formed Janus Nanomicelles by Reactive Blending

Wang, H., Dong, W., & Li, Y. (2015) · ACS Macro Letters · doi:10.1021/acsmacrolett.5b00763 · Cited by 107