The DOI matches its Crossref record; 3 of the 3 references it cites were found in a registry or an index.
Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction
Abstract
It is commonly accepted that it is almost not possible to realize the large-scale practical application of fuel cells if the expensive noble metal-based electrocatalysts for oxygen reduction reactions (ORR) cannot be replaced by other low-cost, efficient, and stable ones. Herein, our studies demonstrate that iron phthalocyanine (FePc) supported on chemically reduced graphene through π–π interaction can act as a noble metal-free electrocatalyst with a comparable activity, long-term operation stability, and better tolerance to methanol crossover and CO poisoning compared with commercial Pt/C for ORR in alkaline media. The improved electrochemical activity and stability of FePc by graphene is mainly attributed to the inherent properties of graphene and the π-stacking interaction between FePc and planar aromatic structure of graphene. The as-prepared graphene–iron phthalocyanine (g-FePc) composite exhibits an efficient 4-electron pathway and can be used as a promising Pt-free ORR electrocatalyst.
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Citations
Cites
Wang, H., Maiyalagan, T., & Wang, X. (2012) · ACS Catalysis · doi:10.1021/cs200652y · Cited by 3,618
High oxygen-reduction activity and durability of nitrogen-doped graphene
Geng, D., Chen, Y., Chen, Y., Li, Y., Li, R., Sun, X., Ye, S., & Knights, S. (2011) · Energy & Environmental Science · doi:10.1039/c0ee00326c · Cited by 1,219
Graphene‐Supported Hemin as a Highly Active Biomimetic Oxidation Catalyst
Xue, T., Jiang, S., Qu, Y., Su, Q., Cheng, R., Dubin, S., Chiu, C., Kaner, R., Huang, Y., & Duan, X. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201108400 · Cited by 365
Cited by
Graphene-Supported Nanoelectrocatalysts for Fuel Cells: Synthesis, Properties, and Applications
Liu, M., Zhang, R., & Chen, W. (2014) · Chemical Reviews · doi:10.1021/cr400523y · Cited by 986
Self-citationChen, K., Liu, K., An, P., Li, H., Lin, Y., Hu, J., Jia, C., Fu, J., Li, H., Liu, H., et al. (2020) · Nature Communications · doi:10.1038/s41467-020-18062-y · Cited by 678
Self-citationHiggins, D., Zamani, P., Yu, A., & Chen, Z. (2016) · Energy & Environmental Science · doi:10.1039/c5ee02474a · Cited by 525
Carbon as catalyst and support for electrochemical energy conversion
Trogadas, P., Fuller, T. F., & Strasser, P. (2014) · Carbon · doi:10.1016/j.carbon.2014.04.005 · Cited by 522
Cui, X., Yang, S., Yan, X., Leng, J., Shuang, S., Ajayan, P. M., & Zhang, Z. (2016) · Advanced Functional Materials · doi:10.1002/adfm.201601492 · Cited by 409
Metadata
- Authors
- Jiang, Y., Lu, Y., Lv, X., Han, D., Zhang, Q., Niu, L., & Chen, W.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-05-10
- Volume
- 3
- Issue
- 6
- Pages
- 1263-1271
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2164301661
- Cited by
- 419
- References
- 3
- FWCI
- 13.83
- Type
- journal article
- Language
- en
- Open access
- closed
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- Jiang, Y., Lu, Y., Lv, X., Han, D., Zhang, Q., Niu, L., & Chen, W. (2013). Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction. ACS Catalysis. https://doi.org/10.1021/cs4001927
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