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Cited by 419

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Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction

Jiang, Yuanyuan, Lu, Yizhong, Lv, Xiangyu, Han, Dongxue, Zhang, Qixian, Niu, Li, Chen, Wei·2013·ACS Catalysis

Abstract

It is commonly accepted that it is almost not possible to realize the large-scale practical application of fuel cells if the expensive noble metal-based electrocatalysts for oxygen reduction reactions (ORR) cannot be replaced by other low-cost, efficient, and stable ones. Herein, our studies demonstrate that iron phthalocyanine (FePc) supported on chemically reduced graphene through π–π interaction can act as a noble metal-free electrocatalyst with a comparable activity, long-term operation stability, and better tolerance to methanol crossover and CO poisoning compared with commercial Pt/C for ORR in alkaline media. The improved electrochemical activity and stability of FePc by graphene is mainly attributed to the inherent properties of graphene and the π-stacking interaction between FePc and planar aromatic structure of graphene. The as-prepared graphene–iron phthalocyanine (g-FePc) composite exhibits an efficient 4-electron pathway and can be used as a promising Pt-free ORR electrocatalyst.

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Metadata

Authors
Jiang, Y., Lu, Y., Lv, X., Han, D., Zhang, Q., Niu, L., & Chen, W.
Venue
ACS Catalysis
Published
2013-05-10
Volume
3
Issue
6
Pages
1263-1271
ISSN
2155-5435 (ISSN-L)
OpenAlex
W2164301661
Cited by
419
References
3
FWCI
13.83
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction. https://app.cochat.ai/papers/10.1021/cs4001927
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Jiang, Y., Lu, Y., Lv, X., Han, D., Zhang, Q., Niu, L., & Chen, W. (2013). Enhanced Catalytic Performance of Pt-Free Iron Phthalocyanine by Graphene Support for Efficient Oxygen Reduction Reaction. ACS Catalysis. https://doi.org/10.1021/cs4001927

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