The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Catalysts for Production of Lower Olefins from Synthesis Gas: A Review
Abstract
C 2 to C 4 olefins are traditionally produced from steam cracking of naphtha. The necessity for alternative production routes for these major commodity chemicals via non-oil-based processes has driven research in past times during the oil crises. Currently, there is a renewed interest in producing lower olefins from alternative feedstocks such as coal, natural gas, or biomass, in view of high oil prices, environmental regulations, and strategies to gain independence from oil imports. This review describes the major routes for the production of lower olefins from synthesis gas with an emphasis on a direct or single step process, the so-called FTO or Fischer–Tropsch to olefins process. The different catalysts for FTO are outlined and compared, and the key issues and requirements for future developments are highlighted. Iron-based catalysts are prevailing for FTO, and reproducible lower olefin selectivities of 50 wt % of hydrocarbons produced have been realized at CO conversions higher than 70% for 60 to 1000 h on stream. Remarkably the high selectivity to lower olefins has been achieved over a broad range of process conditions (P, T, H 2 /CO ratio, GHSV). A major challenge for further development and application of FTO catalysts is the suppression of carbon lay-down to enhance catalyst lifetime and to preserve their physical integrity under demanding reaction conditions.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
The Fischer-Tropsch process: 1950-2000
Dry, M. E. (2002) · Catalysis Today · doi:10.1016/s0920-5861(01)00453-9 · Cited by 2,061
Cited by
Selective Hydrogenation over Supported Metal Catalysts: From Nanoparticles to Single Atoms
Zhang, L., Zhou, M., Wang, A., & Zhang, T. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00230 · Cited by 1,611
Selective conversion of syngas to light olefins
Jiao, F., Li, J., Pan, X., Xiao, J., Li, H., Ma, H., Wei, M., Pan, Y., Zhou, Z., Li, M., et al. (2016) · Science · doi:10.1126/science.aaf1835 · Cited by 1,521
Kibria, M. G., Edwards, J. P., Gabardo, C. M., Dinh, C., Seifitokaldani, A., Sinton, D., & Sargent, E. H. (2019) · Advanced Materials · doi:10.1002/adma.201807166 · Cited by 1,331
Cobalt carbide nanoprisms for direct production of lower olefins from syngas
Zhong, L., Yu, F., An, Y., Zhao, Y., Sun, Y., Li, Z., Lin, T., Lin, Y., Qi, X., Dai, Y., et al. (2016) · Nature · doi:10.1038/nature19786 · Cited by 874
New Trends in Olefin Production
Amghizar, I., Vandewalle, L. A., Van Geem, K. M., & Marin, G. B. (2017) · Engineering · doi:10.1016/j.eng.2017.02.006 · Cited by 835
Hierarchically Structured Zeolites: From Design to Application
Chen, L.-H., Sun, M.-H., Wang, Z., Yang, W., Xie, Z., & Su, B.-L. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00016 · Cited by 724
Highly Selective Conversion of Carbon Dioxide to Lower Olefins
Li, Z., Wang, J., Qu, Y., Liu, H., Tang, C., Miao, S., Feng, Z., An, H., & Li, C. (2017) · ACS Catalysis · doi:10.1021/acscatal.7b03251 · Cited by 593
Emerging applications of zeolites in catalysis, separation and host–guest assembly
Li, Y., & Yu, J. (2021) · Nature Reviews Materials · doi:10.1038/s41578-021-00347-3 · Cited by 585
Cheng, K., Zhou, W., Kang, J., He, S., Shi, S., Zhang, Q., Pan, Y., Wen, W., & Wang, Y. (2017) · Chem · doi:10.1016/j.chempr.2017.05.007 · Cited by 533
Direct Production of Lower Olefins from CO2 Conversion via Bifunctional Catalysis
Gao, P., Dang, S., Li, S., Bu, X., Liu, Z., Qiu, M., Yang, C., Wang, H., Zhong, L., Han, Y., et al. (2018) · ACS Catalysis · doi:10.1021/acscatal.7b02649 · Cited by 533
Santos, R. G. D., & Alencar, A. C. (2020) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2019.07.133 · Cited by 459
A hydrophobic FeMn@Si catalyst increases olefins from syngas by suppressing C1 by-products
Xu, Y., Li, X., Gao, J., Wang, J., Ma, G., Wen, X., Yang, Y., Li, Y., & Ding, M. (2021) · Science · doi:10.1126/science.abb3649 · Cited by 444
Pan, X., Jiao, F., Miao, D., & Bao, X. (2021) · Chemical Reviews · doi:10.1021/acs.chemrev.0c01012 · Cited by 423
Cui, W.-G., Zhang, G.-Y., Hu, T.-L., & Bu, X.-H. (2019) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2019.02.001 · Cited by 406
From Solar Energy to Fuels: Recent Advances in Light‐Driven C1 Chemistry
Chen, G., Waterhouse, G. I. N., Shi, R., Zhao, J., Li, Z., Wu, L., Tung, C., & Zhang, T. (2019) · Angewandte Chemie International Edition · doi:10.1002/anie.201814313 · Cited by 396
Significant Advances in C1 Catalysis: Highly Efficient Catalysts and Catalytic Reactions
Bao, J., Yang, G., Yoneyama, Y., & Tsubaki, N. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b03924 · Cited by 367
Development of Tandem Catalysts for CO2 Hydrogenation to Olefins
Ma, Z., & Porosoff, M. D. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b05060 · Cited by 323
Applications of Zeolites to C1 Chemistry: Recent Advances, Challenges, and Opportunities
Zhang, Q., Yu, J., & Corma, A. (2020) · Advanced Materials · doi:10.1002/adma.202002927 · Cited by 316
Oxidative dehydrogenation of ethane: catalytic and mechanistic aspects and future trends
Najari, S., Saeidi, S., Concepcion, P., Dionysiou, D. D., Bhargava, S. K., Lee, A. F., & Wilson, K. (2021) · Chemical Society Reviews · doi:10.1039/d0cs01518k · Cited by 293
Catalysis Chemistry of Dimethyl Ether Synthesis
Sun, J., Yang, G., Yoneyama, Y., & Tsubaki, N. (2014) · ACS Catalysis · doi:10.1021/cs500967j · Cited by 286
Xu, Y., Zhai, P., Deng, Y., Xie, J., Liu, X., Wang, S., & Ma, D. (2020) · Angewandte Chemie International Edition · doi:10.1002/anie.202009620 · Cited by 258
Issues and challenges of Fischer–Tropsch synthesis catalysts
Amin, M., Usman, M., Kella, T., Khan, W. U., Khan, I. A., & Hoon Lee, K. (2024) · Frontiers in Chemistry · doi:10.3389/fchem.2024.1462503 · Cited by 52
Koyunoglu, C., Eksioglu, O., Yıldırım, O., & Karaca, H. (2018) · Energy Sources, Part A: Recovery, Utilization, and Environmental Effects · doi:10.1080/15567036.2018.1469689 · Cited by 5
Metadata
- Authors
- Torres Galvis, H. M., & de Jong, K. P.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-08-19
- Volume
- 3
- Issue
- 9
- Pages
- 2130-2149
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W1967796261
- Cited by
- 1,032
- References
- 2
- FWCI
- 14.25
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
