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Mo2C Nanoparticles Decorated Graphitic Carbon Sheets: Biopolymer-Derived Solid-State Synthesis and Application as an Efficient Electrocatalyst for Hydrogen Generation
Abstract
The present work reports on the preparation of Mo 2 C nanoparticles decorated graphitic carbon sheets (Mo 2 C/GCSs) via a biopolymer-derived solid-state reaction between (NH 4 ) 6 Mo 7 O 24 ·4H 2 O and sodium alginate at 900 °C under Ar. As a novel hydrogen evolution reaction electrocatalytst, the Mo 2 C/GCSs hybrids exhibit high activity in acidic solutions with an onset potential of 120 mV, a Tafel slope of 62.6 mV dec –1, and an exchange current density of 12.5 × 10 –3 mA cm –2 . Moreover, such Mo 2 C/GCSs catalysts also show excellent durability during long-term 3000 cycles.
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Metadata
- Authors
- Cui, W., Cheng, N., Liu, Q., Ge, C., Asiri, A. M., & Sun, X.
- Venue
- ACS Catalysis
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-07-11
- Volume
- 4
- Issue
- 8
- Pages
- 2658-2661
- ISSN
- 2155-5435 (ISSN-L)
- OpenAlex
- W2323972847
- Cited by
- 361
- References
- 34
- FWCI
- 13.10
- Type
- journal article
- Language
- en
- Open access
- closed
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