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Sonochemical Decomposition of Perfluorooctane Sulfonate and Perfluorooctanoic Acid
Abstract
Perfluorooctane sulfonate (PFOS) and perfluorooctanoic acid (PFOA) are shown to be globally distributed, environmentally persistent, and bioaccumulative. Although the toxicities of these compounds were reported, the cleanup procedure from the environment is not developed because of their inertness. In this report the sonochemical degradations of PFOS and PFOA to the products through the fission of the perfluorocarbon chains were observed and the half-life times of the PFOS and PFOA degradations under an argon atmosphere determined to be 43 and 22 min, respectively. The shortening of perfluorocarbon chain of PFOS and PFOA leads to the lowering of the toxicity in view of the decrease of the persistence, and the technique would contribute to the remediation of the environmental pollution by these compounds.
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“various Ar, N2, and O2 concentrations) on the degradation efficiency and reported that degradation efficiency is a function of the polytropic index of the gases (Moriwaki et al., 2005; Phan Thi et al., 2014).”
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Metadata
- Authors
- Moriwaki, H., Takagi, Y., Tanaka, M., Tsuruho, K., Okitsu, K., & Maeda, Y.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2005-03-30
- Volume
- 39
- Issue
- 9
- Pages
- 3388-3392
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2081517506
- Cited by
- 464
- References
- 3
- FWCI
- 10.04
- Type
- journal article
- Language
- en
- Open access
- closed
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