Mesoporous Carbon Stabilized MgO Nanoparticles Synthesized by Pyrolysis of MgCl 2 Preloaded Waste Biomass for Highly Efficient CO 2 Capture
Abstract
Anthropogenic CO2 emission makes significant contribution to global climate change and CO2 capture and storage is a currently a preferred technology to change the trajectory toward irreversible global warming. In this work, we reported a new strategy that the inexhaustible MgCl2 in seawater and the abundantly available biomass waste can be utilized to prepare mesoporous carbon stabilized MgO nanoparticles (mPC-MgO) for CO2 capture. The mPC-MgO showed excellent performance in the CO2 capture process with the maximum capacity of 5.45 mol kg(-1), much higher than many other MgO based CO2 trappers. The CO2 capture capacity of the mPC-MgO material kept almost unchanged in 19-run cyclic reuse, and can be regenerated at low temperature. The mechanism for the CO2 capture by the mPC-MgO was investigated by FTIR and XPS, and the results indicated that the high CO2 capture capacity and the favorable selectivity of the as-prepared materials were mainly attributed to their special structure (i.e., surface area, functional groups, and the MgO NPs). This work would open up a new pathway to slow down global warming as well as resolve the pollution of waste biomass.
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CO2 reacts with MgO on the biochar surface to form MgCO3, and interacts with surface hydroxyl via hydrogen bonding apart from physical adsorption.
“This is due to the fact that CO 2 also reacts with MgO on the biochar surface to form MgCO 3 , and interacts with surface hydroxyl via hydrogen bonding apart from physical adsorption (Liu et al. 2013).”
From Role of biochar toward carbon neutrality (2023) · cites this paper as Liu et al. 2013
MgO-modified biochar has a high CO2 adsorption capacity of 5.45 mmol/g.
“For instance, Liu et al. (2013) fabricated MgO-modified biochar with a high adsorption capacity of 5.45 mmol/g.”
From Role of biochar toward carbon neutrality (2023) · cites this paper as Liu et al. (2013)
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Self-citation
- Authors
- Liu, W.-J., Jiang, H., Tian, K., Ding, Y.-W., & Yu, H.-Q.
- Affiliations
- Department of Chemistry, University of Science and Technology of China, Hefei 230026, People’s Republic of China
- University of Science and Technology of China (CN)
- Hefei National Laboratory for Physical Sciences at Microscale, University of Science and Technology of China, Hefei 230026, People’s Republic of China
- Corresponding author
- Jiang, Hong
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-08-12
- Volume
- 47
- Issue
- 16
- Pages
- 9397-9403
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2326008308
- Cited by
- 276
- References
- 45
- Citations by year
- 2026: 25 · 2025: 26 · 2024: 23 · 2023: 23 · 2022: 35 · 2021: 22 · 2020: 21 · 2019: 25 · 2018: 21 · 2017: 19 · 2016: 15 · 2015: 10 · 2014: 11
- FWCI
- 15.91
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- Topics
- Physical Sciences › Engineering › Mechanical Engineering › Carbon Dioxide Capture Technologies
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Materials Science › Materials Chemistry › Magnesium Oxide Properties and Applications
- Keywords
- CO2 capture, magnesium oxide nanoparticles, mesoporous carbon, biomass waste valorization, adsorption capacity, low-temperature regeneration
- MeSH terms
- Carbon Dioxide, Magnesium Oxide, Magnesium Chloride, Biomass, Nanoparticles, Biofuels
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