Impacts of Organic Ligands on Forsterite Reactivity in Supercritical CO2 Fluids
Open accessAbstract
Subsurface injection of CO2 for enhanced hydrocarbon recovery, hydraulic fracturing of unconventional reservoirs, and geologic carbon sequestration produces a complex geochemical setting in which CO2-dominated fluids containing dissolved water and organic compounds interact with rocks and minerals. The details of these reactions are relatively unknown and benefit from additional experimentally derived data. In this study, we utilized an in situ X-ray diffraction technique to examine the carbonation reactions of forsterite (Mg2SiO4) during exposure to supercritical CO2 (scCO2) that had been equilibrated with aqueous solutions of acetate, oxalate, malonate, or citrate at 50 °C and 90 bar. The organics affected the relative abundances of the crystalline reaction products, nesquehonite (MgCO3 · 3H2O) and magnesite (MgCO3), likely due to enhanced dehydration of the Mg(2+) cations by the organic ligands. These results also indicate that the scCO2 solvated and transported the organic ligands to the forsterite surface. This phenomenon has profound implications for mineral transformations and mass transfer in the upper crust.
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Self-citationSeparation Process Of Citric Acid with Tertiary Amines/Diluents in Supercritical CO2
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Cited by
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Oxide– and Silicate–Water Interfaces and Their Roles in Technology and the Environment
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Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films
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Self-citationRoom Temperature Magnesite Precipitation
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Self-citationWollastonite Carbonation in Water-Bearing Supercritical CO<sub>2</sub>: Effects of Particle Size
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Review on in-situ CO2 mineralization sequestration: mechanistic understanding and research frontiers
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Reactivation of Serpentine Fracture Networks in Ultramafic Reservoirs
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Self-citation
- Authors
- Miller, Q. R. S., Kaszuba, J. P., Schaef, H. T., Bowden, M. E., & McGrail, B. P.
- Affiliations
- University of Wyoming (US)
- Pacific Northwest National Laboratory (US)
- Corresponding author
- Miller, Quin R. S.
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-03-25
- Volume
- 49
- Issue
- 7
- Pages
- 4724-4734
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W2034630914
- Semantic Scholar
- c68be907cfe147400a6c86384c490e3166da26c4
- Cited by
- 44
- References
- 111
- Citations by year
- 2026: 3 · 2025: 11 · 2024: 4 · 2023: 3 · 2022: 4 · 2021: 1 · 2020: 3 · 2019: 5 · 2018: 6 · 2017: 2 · 2016: 1 · 2014: 1
- FWCI
- 2.16
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- School of Energy Resources, University of Wyoming
- American Chemical Society Petroleum Research Fund
- University of Wyoming
- Office of Fossil Energy
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Engineering › Biomedical Engineering › Subcritical and Supercritical Water Processes
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Keywords
- forsterite, supercritical carbon dioxide, organic ligands, CO2 mineralization, nesquehonite, magnesite, acetate, oxalate, malonate, citrate, CO2 sequestration, enhanced hydrocarbon recovery, hydraulic fracturing, mineral dehydration, ligand solvation, mineral transformation, mass transfer
- MeSH terms
- Carbon Dioxide, Carbonates, Ligands, Magnesium, Minerals, Water, X-Ray Diffraction, Silicon Compounds, Carbon Sequestration
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