Cited by 41CO2 Sequestration and Geologic InteractionsCalcium Carbonate Crystallization and InhibitionNanopore and Nanochannel Transport Studies

Emerging investigator series: ion diffusivities in nanoconfined interfacial water films contribute to mineral carbonation thresholds

Open access
Miller, Quin R. S., Kaszuba, John P., Kerisit, Sebastien N., Schaef, H. Todd, Bowden, Mark E., McGrail, B. Peter, Rosso, Kevin M.·2020·Environmental Science: Nano

Abstract

Mineral carbonation reactivity trends and thresholds in nanoconfined water films delineated with in situ X-ray diffraction and molecular simulations.

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Integrity signals

Registry

Crossref · 10.1039/c9en01382b

Cites

144 of 144 references verified0 citation errors · 0 not checkable

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Claims other papers make about this one

Each is checked against this paper’s own text: does it say what the citing paper says it does?

  • The dielectric permittivity of confined water decreases with pore size.

    “Compiled literature results for the dielectric permittivity constants of confined water as a function of pore size136- 140 .”

    From Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films (2022) · cites this paper as [137]

    The Introduction states that interfacial water has a significantly lower dielectric constant than bulk water. It does not establish that permittivity decreases as pore size decreases or compile dielectric-permittivity results by pore size. (LLM, conf=0.83)

    Experimental — accuracy not yet measured
  • Forsterite-to-magnesite carbonation has apparent activation energies of 34±7 kJ/mol at 100% RH and 83±17 kJ/mol at 85% RH.

    “Miller et al. 46,137 measured time-dependent forsterite to magnesite carbonation at different temperatures, and determined apparent activation energies of 34±7 kJ/mol at 100% RH and 83±17 kJ/mol at 85% RH, Figure 7.”

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Cites

1 retracted

Flagged first, then by citations

Research works printed but not linked: 5

  1. [4]4. Y. F. Wang, C. Bryan, H. F. Xu and H. Z. Gao, Nanogeochemistry: Geochemical reactions and mass transfers in nanopores, Geology, 2003, 31, 387-390.
  2. [68]68. J. S. Loring, Q. R. S. Miller, H. T. Schaef and C. J. Thompson, in Science of Carbon Storage in Deep Saline Formations: Process Coupling across Time and Spatial Scales, eds. P. Newell and A. G. Ilgen, Elsevier, 1st edn., 2018.
  3. [69]69. J. P. Kaszuba, L. L. Williams, D. R. Janecky, W. K. Hollis and I. N. Tsimpanogiannis, Immiscible CO 2 -H 2 O fluids in the shallow crust, Geochem. Geophys. Geosyst., 2006, 7(10), Q10003.
  4. [94]94. J. H. Kwak, J. Z. Hu, R. V. F. Turcu, K. M. Rosso, E. S. Ilton, C. Wang, J. A. Sears, M. H. Engelhard, A. R. Felmy and D. W. Hoyt, The role of H 2 O in the carbonation of forsterite in supercritical CO 2 , Int. J. Greenhouse Gas Control, 2011, 5, 1081-1092.
  5. [106]106. T. F. Kazmierczak, M. B. Tomson and G. H. Nancollas, Crystal growth of calcium carbonate. A controlled composition kinetic study, J. Phys. Chem., 1982, 86, 103- 107. 125.

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Authors
Miller, Q. R. S., Kaszuba, J. P., Kerisit, S. N., Schaef, H. T., Bowden, M. E., McGrail, B. P., & Rosso, K. M.
Affiliations
  • University of Wyoming (US)
  • Physical and Computational Sciences Directorate
  • Pacific Northwest National Laboratory (US)
Corresponding author
Miller, Quin R. S.
Venue
Environmental Science: Nano
Published
2020
Volume
7
Issue
4
Pages
1068-1081
ISSN
  • 2051-8153 (ISSN-L)
  • 2051-8161
OpenAlex
W3008671197
Cited by
41
References
144
Citations by year
2026: 11 · 2025: 10 · 2024: 4 · 2023: 3 · 2022: 4 · 2021: 7 · 2020: 2
FWCI
1.44
Type
journal article
Language
en
Open access
Locations
  • Environmental Science Nano (publishedVersion)
  • OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
Funders
  • Chemical Sciences, Geosciences, and Biosciences Division
  • School of Energy Resources, University of Wyoming
  • Office of Fossil Energy
  • University of Wyoming
Topics
  • Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
  • Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
  • Physical Sciences › Engineering › Biomedical Engineering › Nanopore and Nanochannel Transport Studies
Keywords
CO2 mineralization, nanoconfined water, ion diffusivity, carbon sequestration, in situ X-ray diffraction, molecular simulation

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