Emerging investigator series: ion diffusivities in nanoconfined interfacial water films contribute to mineral carbonation thresholds
Open accessAbstract
Mineral carbonation reactivity trends and thresholds in nanoconfined water films delineated with in situ X-ray diffraction and molecular simulations.
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Claims other papers make about this one
Each is checked against this paper’s own text: does it say what the citing paper says it does?
The dielectric permittivity of confined water decreases with pore size.
“Compiled literature results for the dielectric permittivity constants of confined water as a function of pore size136- 140 .”
From Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films (2022) · cites this paper as [137]
The Introduction states that interfacial water has a significantly lower dielectric constant than bulk water. It does not establish that permittivity decreases as pore size decreases or compile dielectric-permittivity results by pore size. (LLM, conf=0.83)
Experimental — accuracy not yet measuredForsterite-to-magnesite carbonation has apparent activation energies of 34±7 kJ/mol at 100% RH and 83±17 kJ/mol at 85% RH.
“Miller et al. 46,137 measured time-dependent forsterite to magnesite carbonation at different temperatures, and determined apparent activation energies of 34±7 kJ/mol at 100% RH and 83±17 kJ/mol at 85% RH, Figure 7.”
From Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films (2022) · cites this paper as [137]
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Cites
1 retracted
Kalinichev, A. G., Wang, J., & Kirkpatrick, R. J. (2006) · Cement and Concrete Research · doi:10.1016/j.cemconres.2006.07.004 · Cited by 294 · see citing works
RetractedThe missing term in effective pair potentials
Berendsen, H. J. C., Grigera, J. R., & Straatsma, T. P. (1987) · The Journal of Physical Chemistry · doi:10.1021/j100308a038 · Cited by 13,313 · see citing works
Cygan, R. T., Liang, J.-J., & Kalinichev, A. G. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0363287 · Cited by 3,244 · see citing works
DL_POLY_2.0: A general-purpose parallel molecular dynamics simulation package
Smith, W. R., & Forester, T. R. (1996) · Journal of Molecular Graphics · doi:10.1016/s0263-7855(96)00043-4 · Cited by 2,231 · see citing works
Harris, J. G., & Yung, K. H. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100031a034 · Cited by 1,573 · see citing works
White, A. F., & Brantley, S. L. (2003) · Chemical Geology · doi:10.1016/j.chemgeo.2003.03.001 · Cited by 1,196 · see citing works
Anomalously low dielectric constant of confined water
Fumagalli, L., Esfandiar, A., Fabregas, R., Hu, S., Ares, P., Janardanan, A., Yang, Q., Radha, B., Taniguchi, T., Watanabe, K., et al. (2018) · Science · doi:10.1126/science.aat4191 · Cited by 1,067 · see citing works
Usher, C. R., Michel, A. E., & Grassian, V. H. (2003) · Chemical Reviews · doi:10.1021/cr020657y · Cited by 1,022 · see citing works
Chemical Weathering Rates of Silicate Minerals
(1995) · De Gruyter eBooks · doi:10.1515/9781501509650 · Cited by 870 · see citing works
Sedimentary carbonate minerals
(1973) · Earth-Science Reviews · doi:10.1016/0012-8252(73)90031-7 · Cited by 563 · see citing works
Precipitation in the Mg-carbonate system—effects of temperature and CO2 pressure
Hänchen, M., Prigiobbe, V., Baciocchi, R., & Mazzotti, M. (2008) · Chemical Engineering Science · doi:10.1016/j.ces.2007.09.052 · Cited by 545 · see citing works
Sedimentary Carbonate Minerals
Lippmann, F. (1973) · doi:10.1007/978-3-642-65474-9 · Cited by 545 · see citing works
The dolomite problem; control of precipitation kinetics by temperature and saturation state
Arvidson, R. S. (1999) · American Journal of Science · doi:10.2475/ajs.299.4.257 · Cited by 447 · see citing works
Coupled dissolution and precipitation at mineral–fluid interfaces
Ruíz-Agudo, E., Putnis, C. V., & Putnis, A. (2014) · Chemical Geology · doi:10.1016/j.chemgeo.2014.06.007 · Cited by 444 · see citing works
Application of symmetrized harmonics expansion to correction of the preferred orientation effect
Järvinen, M. (1993) · Journal of Applied Crystallography · doi:10.1107/s0021889893001219 · Cited by 427 · see citing works
Origins of hydration lubrication
Ma, L., Gaisinskaya-Kipnis, A., Kampf, N., & Klein, J. (2015) · Nature Communications · doi:10.1038/ncomms7060 · Cited by 390 · see citing works
Transient liquid water and water activity at Gale crater on Mars
Martín-Torres, F. J., Zorzano, M.-P., Valentín-Serrano, P., Harri, A.-M., Genzer, M., Kemppinen, O., Rivera-Valentin, E. G., Jun, I., Wray, J., Bo Madsen, M., et al. (2015) · Nature Geoscience · doi:10.1038/ngeo2412 · Cited by 359 · see citing works
Hellmann, R., Wirth, R., Daval, D., Barnes, J.-P., Penisson, J.-M., Tisserand, D., Epicier, T., Florin, B., & Hervig, R. L. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2011.12.002 · Cited by 327 · see citing works
Acceleration of reaction in charged microdroplets
Lee, J. K., Banerjee, S., Nam, H. G., & Zare, R. N. (2015) · Quarterly Reviews of Biophysics · doi:10.1017/s0033583515000086 · Cited by 320 · see citing works
Osti, N. C., Naguib, M., Ostadhossein, A., et al. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b01490 · Cited by 317 · see citing works
Hellmann, R., Cotte, S., Cadel, E., Malladi, S., Karlsson, L. S., Lozano-Perez, S., Cabié, M., & Seyeux, A. (2015) · Nature Materials · doi:10.1038/nmat4172 · Cited by 315 · see citing works
Daval, D., Martinez, I., Corvisier, J., Findling, N., Goffé, B., & Guyot, F. (2009) · Chemical Geology · doi:10.1016/j.chemgeo.2009.01.022 · Cited by 314 · see citing works
Origin and consequences of silicate glass passivation by surface layers
Gin, S., Jollivet, P., Fournier, M., Angeli, F., Frugier, P., & Charpentier, T. (2015) · Nature Communications · doi:10.1038/ncomms7360 · Cited by 304 · see citing works
Dielectric Constant of Water Confined in a Nanocavity
Senapati, S., & Chandra, A. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp011058i · Cited by 302 · see citing works
Crystallization under nanoscale confinement
Jiang, Q., & Ward, M. D. (2013) · Chemical Society Reviews · doi:10.1039/c3cs60234f · Cited by 297 · see citing works
Magnesite growth rates as a function of temperature and saturation state
Saldi, G. D., Jordan, G., Schott, J., & Oelkers, E. H. (2009) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2009.06.035 · Cited by 289 · see citing works
Molecular Dynamics Simulations of Water Structure and Diffusion in Silica Nanopores
Bourg, I. C., & Steefel, C. I. (2012) · The Journal of Physical Chemistry C · doi:10.1021/jp301299a · Cited by 286 · see citing works
Low-temperature thermodynamic model for the system Na2CO3–MgCO3–CaCO3–H2O
Königsberger, E., Königsberger, L.-C., & Gamsjäger, H. (1999) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00238-0 · Cited by 275 · see citing works
Molecular Structure and Dynamics in Thin Water Films at the Silica and Graphite Surfaces
Argyris, D., Tummala, N. R., Striolo, A., & Cole, D. R. (2008) · The Journal of Physical Chemistry C · doi:10.1021/jp803234a · Cited by 263 · see citing works
Role(s) of adsorbed water in the surface chemistry of environmental interfaces
Rubasinghege, G., & Grassian, V. H. (2013) · Chemical Communications · doi:10.1039/c3cc38872g · Cited by 247 · see citing works
Surface chemistry allows for abiotic precipitation of dolomite at low temperature
Roberts, J. A., Kenward, P. A., Fowle, D. A., Goldstein, R. H., González, L. A., & Moore, D. S. (2013) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1305403110 · Cited by 246 · see citing works
Jin, L., Ravella, R., Ketchum, B., Bierman, P. R., Heaney, P. J., White, T. S., & Brantley, S. L. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.03.036 · Cited by 243 · see citing works
Water properties under nano-scale confinement
Knight, A. W., Kalugin, N. G., Coker, E. N., & Ilgen, A. (2019) · Scientific Reports · doi:10.1038/s41598-019-44651-z · Cited by 219 · see citing works
Interfacial water dielectric-permittivity-profile measurements using atomic force microscopy
Teschke, O., Ceotto, G., & de Souza, E. F. (2001) · Physical Review E · doi:10.1103/physreve.64.011605 · Cited by 209 · see citing works
Water reactivity in the liquid and supercritical CO2 phase: Has half the story been neglected?
McGrail, B. P., Schaef, H. T., Glezakou, V., Dang, L. X., & Owen, A. T. (2009) · Energy Procedia · doi:10.1016/j.egypro.2009.02.131 · Cited by 200 · see citing works
Self-citationIn Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO <sub>2</sub>
Loring, J. S., Thompson, C. J., Wang, Z., Joly, A. G., Sklarew, D. S., Schaef, H. T., Ilton, E. S., Rosso, K. M., & Felmy, A. R. (2011) · Environmental Science & Technology · doi:10.1021/es201284e · Cited by 197 · see citing works
Self-citationAmorphous Calcium Carbonate is Stabilized in Confinement
Stephens, C. J., Ladden, S. F., Meldrum, F. C., & Christenson, H. K. (2010) · Advanced Functional Materials · doi:10.1002/adfm.201000248 · Cited by 190 · see citing works
Shales at all scales: Exploring coupled processes in mudrocks
Ilgen, A., Heath, J. E., Akkutlu, I. Y., et al. (2017) · Earth-Science Reviews · doi:10.1016/j.earscirev.2016.12.013 · Cited by 173 · see citing works
Hongfei, L. I. N., Fujii, T., Takisawa, R., Takahashi, T., & Hashida, T. (2007) · Journal of Materials Science · doi:10.1007/s10853-007-2029-4 · Cited by 165 · see citing works
Mechanism of leached layer formation during chemical weathering of silicate minerals
Ruíz-Agudo, E., Putnis, C. V., Rodriguez-Navarro, C. M., & Putnis, A. (2012) · Geology · doi:10.1130/g33339.1 · Cited by 160 · see citing works
Molecular Simulations of Water and Ion Diffusion in Nanosized Mineral Fractures
Kerisit, S., & Liu, C. (2009) · Environmental Science & Technology · doi:10.1021/es8016045 · Cited by 157 · see citing works
Self-citationChemistry in nanoconfined water
Muñoz‐Santiburcio, D., & Marx, D. (2017) · Chemical Science · doi:10.1039/c6sc04989c · Cited by 151 · see citing works
Tracer Diffusion in Compacted, Water-Saturated Bentonite
Bourg, I. C., Sposito, G., & Bourg, A. C. M. (2006) · Clays and Clay Minerals · doi:10.1346/ccmn.2006.0540307 · Cited by 150 · see citing works
Wang, Y. (2014) · Chemical Geology · doi:10.1016/j.chemgeo.2014.04.007 · Cited by 149 · see citing works
Physicochemical controls on adsorbed water film thickness in unsaturated geological media
Tokunaga, T. K. (2011) · Water Resources Research · doi:10.1029/2011wr010676 · Cited by 144 · see citing works
Kim, D., Lee, B., Thomopoulos, S., & Jun, Y. (2018) · Nature Communications · doi:10.1038/s41467-018-03041-1 · Cited by 142 · see citing works
Saldi, G. D., Schott, J., Pokrovsky, O. S., Gautier, Q., & Oelkers, E. H. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.12.005 · Cited by 141 · see citing works
Chemistry Inside Carbon Nanotubes: the Menshutkin SN2 Reaction
Halls, M. D., & Schlegel, H. B. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0137165 · Cited by 141 · see citing works
Liu, D., Xu, Y., Papineau, D., Yu, N., Fan, Q., Qiu, X., & Wang, H. (2019) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.12.036 · Cited by 141 · see citing works
Tommaso, D. D., & de Leeuw, N. H. (2010) · Phys. Chem. Chem. Phys. · doi:10.1039/b915329b · Cited by 139 · see citing works
The role of H2O in the carbonation of forsterite in supercritical CO2
Kwak, J. H., Hu, J. Z., Turcu, R. V. F., Rosso, K. M., Ilton, E. S., Wang, C., Sears, J. A., Engelhard, M. H., Felmy, A. R., & Hoyt, D. W. (2011) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2011.05.013 · Cited by 136 · see citing works
Self-citationFelmy, A. R., Qafoku, O., Arey, B. W., Hu, J. Z., Hu, M., Todd Schaef, H., Ilton, E. S., Hess, N. J., Pearce, C. I., Feng, J., et al. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.05.026 · Cited by 130 · see citing works
Self-citationSchaef, H. T., Windisch, C. F., McGrail, B. P., Martin, P. F., & Rosso, K. M. (2011) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2011.09.029 · Cited by 129 · see citing works
Self-citationFluid-driven metamorphism of the continental crust governed by nanoscale fluid flow
Plümper, O., Boţan, A., Los, C., Liu, Y., Malthe‐Sørenssen, A., & Jamtveit, B. (2017) · Nature Geoscience · doi:10.1038/ngeo3009 · Cited by 124 · see citing works
A novel method to low temperature synthesis of nanocrystalline forsterite
Saberi, A., Alinejad, B., Negahdari, Z., Kazemi, F., & Almasi, A. (2006) · Materials Research Bulletin · doi:10.1016/j.materresbull.2006.07.020 · Cited by 121 · see citing works
Greathouse, J. A., Cygan, R. T., Fredrich, J. T., & Jerauld, G. R. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.5b10851 · Cited by 115 · see citing works
Emmanuel, S., Ague, J. J., & Walderhaug, O. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.03.019 · Cited by 113 · see citing works
Springer, R., Wang, Z.-M., Anderko, A., Wang, P., & Felmy, A. R. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2012.07.008 · Cited by 111 · see citing works
Early Stages of Crystallization of Calcium Carbonate Revealed in Picoliter Droplets
Stephens, C. J., Kim, Y., Evans, S. D., Meldrum, F. C., & Christenson, H. K. (2011) · Journal of the American Chemical Society · doi:10.1021/ja200309m · Cited by 111 · see citing works
Insights into silicate carbonation processes in water-bearing supercritical CO2 fluids
Miller, Q. R. S., Thompson, C. J., Loring, J. S., Windisch, C. F., Bowden, M. E., Hoyt, D. W., Hu, J. Z., Arey, B. W., Rosso, K. M., & Schaef, H. T. (2013) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2013.02.005 · Cited by 109 · see citing works
Self-citationTodd Schaef, H., McGrail, B. P., Loring, J. L., Bowden, M. E., Arey, B. W., & Rosso, K. M. (2013) · Environmental Science & Technology · doi:10.1021/es301126f · Cited by 108 · see citing works
Self-citationStudies in the system MgO-SiO 2 -CO 2 -H 2 O (II); the activity-product constant of magnesite
Christ, C. L., & Hostetler, P. B. (1970) · American Journal of Science · doi:10.2475/ajs.268.5.439 · Cited by 108 · see citing works
Kwak, J. H., Hu, J. Z., Hoyt, D. W., Sears, J. A., Wang, C., Rosso, K. M., & Felmy, A. R. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1001308 · Cited by 105 · see citing works
Self-citationKalluri, R. K., Konatham, D., & Striolo, A. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp203086x · Cited by 100 · see citing works
Nanoconfinement in Slit Pores Enhances Water Self-Dissociation
Muñoz‐Santiburcio, D., & Marx, D. (2017) · Physical Review Letters · doi:10.1103/physrevlett.119.056002 · Cited by 100 · see citing works
Room Temperature Magnesite Precipitation
Power, I. M., Kenward, P. A., Dipple, G. M., & Raudsepp, M. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b00311 · Cited by 99 · see citing works
Forsteritic olivine: effect of crystallographic direction on dissolution kinetics
Awad, A., Koster van Groos, A. F., & Guggenheim, S. (2000) · Geochimica et Cosmochimica Acta · doi:10.1016/s0016-7037(99)00442-1 · Cited by 98 · see citing works
Zachara, J. M., Brantley, S., Chorover, J., Ewing, R., Kerisit, S., Liu, C., Perfect, E., Rother, G., & Stack, A. G. (2016) · Environmental Science & Technology · doi:10.1021/acs.est.5b05015 · Cited by 98 · see citing works
Self-citationMiller, Q. R. S., Schaef, H. T., Kaszuba, J. P., Gadikota, G., McGrail, B. P., & Rosso, K. M. (2019) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.9b00301 · Cited by 98 · see citing works
Self-citationWater and carbon dioxide adsorption at olivine surfaces
Kerisit, S., Bylaska, E. J., & Felmy, A. R. (2013) · Chemical Geology · doi:10.1016/j.chemgeo.2013.10.004 · Cited by 89 · see citing works
Self-citationWang, X., Alvarado, V., Swoboda-Colberg, N., & Kaszuba, J. P. (2013) · Energy Conversion and Management · doi:10.1016/j.enconman.2012.07.024 · Cited by 86 · see citing works
Self-citationFrustrated Solvation Structures Can Enhance Electron Transfer Rates
Remsing, R. C., McKendry, I. G., Strongin, D. R., et al. (2015) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.5b02277 · Cited by 85 · see citing works
Galvez, M. E., Manning, C. E., Connolly, J. A. D., et al. (2015) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2015.06.019 · Cited by 84 · see citing works
Structure and dynamics of forsterite–scCO2/H2O interfaces as a function of water content
Kerisit, S., Weare, J. H., & Felmy, A. R. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.01.038 · Cited by 84 · see citing works
Self-citationNanoconfinement effects on hydrated excess protons in layered materials
Muñoz‐Santiburcio, D., Wittekindt, C., & Marx, D. (2013) · Nature Communications · doi:10.1038/ncomms3349 · Cited by 83 · see citing works
Kirfel, Α., Lippmann, T., Blaha, P., et al. (2005) · Physics and Chemistry of Minerals · doi:10.1007/s00269-005-0468-5 · Cited by 79 · see citing works
The role of water in fault lubrication
Diao, Y., & Espinosa-Marzal, R. M. (2018) · Nature Communications · doi:10.1038/s41467-018-04782-9 · Cited by 78 · see citing works
Wollastonite Carbonation in Water-Bearing Supercritical CO<sub>2</sub>: Effects of Particle Size
Min, Y., Li, Q., Voltolini, M., Kneafsey, T., & Jun, Y.-S. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b04475 · Cited by 74 · see citing works
Particle Size Controls on Water Adsorption and Condensation Regimes at Mineral Surfaces
Yeşilbaş, M., & Boily, J.-F. (2016) · Scientific Reports · doi:10.1038/srep32136 · Cited by 73 · see citing works
Dynamic Stabilization of Metal Oxide–Water Interfaces
McBriarty, M. E., von Rudorff, G. F., Stubbs, J. E., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13096 · Cited by 73 · see citing works
King, H., Stimpfl, M., Deymier, P., Drake, M., Catlow, C. A., Putnis, A., & de Leeuw, N. D. (2010) · Earth and Planetary Science Letters · doi:10.1016/j.epsl.2010.10.019 · Cited by 72 · see citing works
Polar Ozone Depletion (Nobel Lecture)
Molina, M. J. (1996) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199617781 · Cited by 71 · see citing works
Thickness and structure of the water film deposited from vapour on calcite surfaces
Bohr, J., Wogelius, R. A., Morris, P. M., & Stipp, S. L. S. (2010) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2010.08.003 · Cited by 70 · see citing works
Diffusion and Adsorption of Uranyl Carbonate Species in Nanosized Mineral Fractures
Kerisit, S., & Liu, C. (2011) · Environmental Science & Technology · doi:10.1021/es2027696 · Cited by 69 · see citing works
Self-citationFayalite dissolution and siderite formation in water-saturated supercritical CO2
Qafoku, O., Kovarik, L., Kukkadapu, R. K., Ilton, E. S., Arey, B. W., Tucek, J., & Felmy, A. R. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2012.09.028 · Cited by 69 · see citing works
Loring, J. S., Chen, J., Bénézeth, P., Qafoku, O., Ilton, E. S., Washton, N. M., Thompson, C. J., Martin, P. F., McGrail, B. P., Rosso, K. M., et al. (2015) · Langmuir · doi:10.1021/acs.langmuir.5b01052 · Cited by 65 · see citing works
Self-citationAdsorption of copper (II) on mesoporous silica: the effect of nano-scale confinement
Knight, A. W., Tigges, A., & Ilgen, A. (2018) · Geochemical Transactions · doi:10.1186/s12932-018-0057-4 · Cited by 61 · see citing works
Mobility of Cesium through the Callovo-Oxfordian Claystones under Partially Saturated Conditions
Savoye, S., Beaucaire, C., Fayette, A., et al. (2012) · Environmental Science & Technology · doi:10.1021/es2037433 · Cited by 59 · see citing works
Pilati, T., Demartin, F., & Gramaccioli, C. M. (1998) · Acta Crystallographica Section B Structural Science · doi:10.1107/s0108768197018181 · Cited by 58 · see citing works
The crystal structure of nesquehonite, MgCO3.3H2O
Stephan, G. W., & MacGillavry, C. H. (1972) · Acta Crystallographica Section B · doi:10.1107/s0567740872003668 · Cited by 56 · see citing works
Pore Size Effects on the Sorption of Supercritical CO2 in Mesoporous CPG-10 Silica
Rother, G., Krukowski, E. G., Wallacher, D., Grimm, N., Bodnar, R. J., & Cole, D. R. (2011) · The Journal of Physical Chemistry C · doi:10.1021/jp209341q · Cited by 55 · see citing works
Thompson, C. J., Loring, J. S., Rosso, K. M., & Wang, Z.-M. (2013) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2013.07.007 · Cited by 54 · see citing works
Self-citationRelaxations and Interfacial Water Ordering at the Corundum (110) Surface
Catalano, J. G. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp100455s · Cited by 53 · see citing works
Effects of Confinement on the Dielectric Response of Water Extends up to Mesoscale Dimensions
Luca, S. D., Kannam, S. K., Todd, B. D., Frascoli, F., Hansen, J. S., & Daivis, P. J. (2016) · Langmuir · doi:10.1021/acs.langmuir.6b00791 · Cited by 52 · see citing works
Tunable Manipulation of Mineral Carbonation Kinetics in Nanoscale Water Films via Citrate Additives
Miller, Q. R. S., Schaef, H. T., Kaszuba, J. P., Qiu, L., Bowden, M. E., & McGrail, B. P. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b00438 · Cited by 50 · see citing works
Self-citationAnomalously low activation energy of nanoconfined MgCO <sub>3</sub> precipitation
Miller, Q. R. S., Kaszuba, J. P., Schaef, H. T., Bowden, M. E., McGrail, B. P., & Rosso, K. M. (2019) · Chemical Communications · doi:10.1039/c9cc01337g · Cited by 49 · see citing works
Self-citationFracking: What Can Physical Chemistry Offer?
Yethiraj, A., & Striolo, A. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz400141e · Cited by 47 · see citing works
Confinement effects on chemical reactions—Toward an integrated rational catalyst design
Santiso, E. E., Kostov, M. K., George, A. M., et al. (2007) · Applied Surface Science · doi:10.1016/j.apsusc.2006.12.121 · Cited by 46 · see citing works
Formation of drug nanocrystals under nanoconfinement afforded by liposomes
Cipolla, D. C., Wu, H., Salentinig, S., Boyd, B. J., Rades, T., Vanhecke, D., Petri‐Fink, A., Rothen‐Rutishauser, B., Eastman, S. J., Redelmeier, T. E., et al. (2016) · RSC Advances · doi:10.1039/c5ra25898g · Cited by 46 · see citing works
Ion Diffusion Within Water Films in Unsaturated Porous Media
Tokunaga, T. K., Finsterle, S., Kim, Y., Wan, J., Lanzirotti, A., & Newville, M. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b05891 · Cited by 46 · see citing works
Automated high-pressure titration system with in situ infrared spectroscopic detection
Thompson, C. J., Martin, P. F. C., Chen, J., Bénézeth, P., Schaef, H. T., Rosso, K. M., Felmy, A. R., & Loring, J. S. (2014) · Review of Scientific Instruments · doi:10.1063/1.4870411 · Cited by 45 · see citing works
Self-citationImpacts of Organic Ligands on Forsterite Reactivity in Supercritical CO<sub>2</sub> Fluids
Miller, Q. R. S., Kaszuba, J. P., Schaef, H. T., Bowden, M. E., & McGrail, B. P. (2015) · Environmental Science & Technology · doi:10.1021/es506065d · Cited by 44 · see citing works
Self-citationImmiscible CO2‐H2O fluids in the shallow crust
Kaszuba, J., Williams, L. L., Janecky, D. R., Hollis, W. K., & Tsimpanogiannis, I. N. (2006) · Geochemistry Geophysics Geosystems · doi:10.1029/2005gc001107 · Cited by 44 · see citing works
Self-citationSurface-Catalyzed Oxygen Exchange during Mineral Carbonation in Nanoscale Water Films
Miller, Q. R. S., Dixon, D. A., Burton, S. D., Walter, E. D., Hoyt, D. W., McNeill, A. S., Moon, J. D., Thanthiriwatte, K. S., Ilton, E. S., Qafoku, O., et al. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b02215 · Cited by 42 · see citing works
Self-citationTemperature-Dependent Dynamics of Water Confined in Nafion Membranes
Paciaroni, A., Casciola, M., Cornicchi, E., Marconi, M., Onori, G., Pica, M., & Narducci, R. (2006) · The Journal of Physical Chemistry B · doi:10.1021/jp0572176 · Cited by 40 · see citing works
Role of Fe(II) Content in Olivine Carbonation in Wet Supercritical CO<sub>2</sub>
Wood, C. E., Qafoku, O., Loring, J. S., & Chaka, A. M. (2019) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.9b00496 · Cited by 39 · see citing works
Interfacial reactions of Cu( ii ) adsorption and hydrolysis driven by nano-scale confinement
Knight, A. W., Ilani‐Kashkouli, P., Harvey, J., Greathouse, J. A., Ho, T. A., Kabengi, N. J., & Ilgen, A. (2019) · Environmental Science Nano · doi:10.1039/c9en00855a · Cited by 38 · see citing works
Effects of nano-confinement on Zn(II) adsorption to nanoporous silica
Nelson, J., Bargar, J., Wasylenki, L. E., Brown, G. E., & Maher, K. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.08.017 · Cited by 35 · see citing works
Li, Q., & Jun, Y. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b00378 · Cited by 35 · see citing works
Calorimetric study of the surface energy of forsterite
Chen, S., & Navrotsky, A. (2009) · American Mineralogist · doi:10.2138/am.2010.3339 · Cited by 34 · see citing works
Thin Water Films at Multifaceted Hematite Particle Surfaces
Boily, J.-F., Yeşilbaş, M., Md. Musleh Uddin, M., Baiqing, L., Trushkina, Y., & Salazar-Alvarez, G. (2015) · Langmuir · doi:10.1021/acs.langmuir.5b03167 · Cited by 34 · see citing works
Confinement Effects on an Electron Transfer Reaction in Nanoporous Carbon Electrodes
Li, Z., Jeanmairet, G., Méndez‐Morales, T., Burbano, M., Haefelé, M., & Salanne, M. (2017) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.7b00458 · Cited by 34 · see citing works
One-Dimensional Confinement Inhibits Water Dissociation in Carbon Nanotubes
Sirkin, Y. A. P., Hassanali, A. A., & Scherlis, D. A. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02183 · Cited by 34 · see citing works
Confinement Effects on Carbon Dioxide Methanation: A Novel Mechanism for Abiotic Methane Formation
Le, T., Striolo, A., Turner, C. H., & Cole, D. R. (2017) · Scientific Reports · doi:10.1038/s41598-017-09445-1 · Cited by 33 · see citing works
Wonderful nanoconfinement effect on redox reaction equilibrium
Patra, S., Pandey, A. K., Sarkar, S. K., et al. (2014) · RSC Advances · doi:10.1039/c4ra05104a · Cited by 32 · see citing works
Adsorbed water and thin liquid films on Mars
Boxe, C. S., Hand, K. P., Nealson, K. H., Yung, Y. L., Yen, A. S., & Saiz‐Lopez, A. (2012) · International Journal of Astrobiology · doi:10.1017/s1473550412000080 · Cited by 30 · see citing works
Effect of Nanoscale Confinement on the Crystallization of Potassium Ferrocyanide
Anduix-Canto, C., Kim, Y.-Y., Wang, Y.-W., Kulak, A., Meldrum, F. C., & Christenson, H. K. (2016) · Crystal Growth & Design · doi:10.1021/acs.cgd.6b00894 · Cited by 30 · see citing works
Using Confinement To Study the Crystallization Pathway of Calcium Carbonate
Wang, Y., Zeng, M., Meldrum, F. C., & Christenson, H. K. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b01359 · Cited by 30 · see citing works
Humidity-induced restructuring of the calcite surface and the effect of divalent heavy metals
Hausner, D. B., Reeder, R. J., & Strongin, D. R. (2006) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2006.09.069 · Cited by 29 · see citing works
Di Lorenzo, F., Rodríguez-Galán, R. M., & Prieto, M. (2014) · Mineralogical Magazine · doi:10.1180/minmag.2014.078.6.02 · Cited by 28 · see citing works
Heath, J. E., Bryan, C. R., Matteo, E., Dewers, T. A., Wang, Y., & Sallaberry, C. J.-M. (2014) · Water Resources Research · doi:10.1002/2013wr013728 · Cited by 28 · see citing works
The Nanopore Inner Sphere Enhancement Effect on Cation Adsorption: Sodium and Nickel
Schulthess, C. P., Taylor, R. W., & Ferreira, D. R. (2011) · Soil Science Society of America Journal · doi:10.2136/sssaj2010.0129nps · Cited by 28 · see citing works
On the growth of anhydrous Mg-bearing carbonates – Implications from norsethite growth kinetics
Lindner, M., Saldi, G. D., Carrocci, S., Bénézeth, P., Jacques Schott, A., & Jordan, G. (2018) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2018.07.013 · Cited by 27 · see citing works
Galib, M., & Hanna, G. (2014) · Physical Chemistry Chemical Physics · doi:10.1039/c4cp03302g · Cited by 26 · see citing works
Kołodziejczyk, K., Tarnacka, M., Kamińska, E., Dulski, M., Kamiński, K., & Paluch, M. (2016) · Crystal Growth & Design · doi:10.1021/acs.cgd.5b01181 · Cited by 26 · see citing works
Magnesite growth inhibition by organic ligands: An experimental study at 100, 120 and 146 °C
Gautier, Q., Bénézeth, P., & Schott, J. (2016) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2016.02.028 · Cited by 26 · see citing works
Frontiers in geochemistry: contribution of geochemistry to the study of the Earth
(2011) · Choice Reviews Online · doi:10.5860/choice.49-1476 · Cited by 24 · see citing works
Hydration of ions under confinement
(2010) · doi:10.1080/08927021003752895 · Cited by 21 · see citing works
Structural Characterization and Thermal Decomposition Behavior of Microsized and Nanosized CaCO3
Yan-jun, T., 华南理工大学制浆造纸工程国家重点实验室, 广. 5. 华., Li, Y., et al. (2007) · Acta Physico-Chimica Sinica · doi:10.3866/pku.whxb20070518 · Cited by 21 · see citing works
Continuous time-resolved X-ray diffraction of the biocatalyzed reduction of Mn oxide
Fischer, T. B., Heaney, P. J., Jang, J. H., Ross, D. E., Brantley, S. L., Post, J. E., & Tien, M. (2008) · American Mineralogist · doi:10.2138/am.2008.3038 · Cited by 20 · see citing works
Zhu, Y., Ruan, Y., Zhang, Y., Lu, L., & Lü, X. (2016) · Molecular Simulation · doi:10.1080/08927022.2016.1161189 · Cited by 20 · see citing works
Nanoconfinement’s Dramatic Impact on Proton Exchange between Glucose and Water
Wiebenga-Sanford, B. P., DiVerdi, J. A., Rithner, C. D., et al. (2016) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.6b01651 · Cited by 20 · see citing works
Water Structure Controls Carbonic Acid Formation in Adsorbed Water Films
Miller, Q. R. S., Ilton, E. S., Qafoku, O., Dixon, D. A., Vasiliu, M., Thompson, C. J., Schaef, H. T., Rosso, K. M., & Loring, J. S. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02162 · Cited by 19 · see citing works
Self-citationInteratomic potentials of Mg ions in aqueous solutions: structure and dehydration kinetics
Zhang, X., Álvarez‐Lloret, P., Chass, G. A., & Tommaso, D. D. (2018) · European Journal of Mineralogy · doi:10.1127/ejm/2019/0031-2815 · Cited by 17 · see citing works
Kocharyan, G. G., & Lyakhov, A. (2019) · Springer proceedings in earth and environmental sciences · doi:10.1007/978-3-030-31970-0 · Cited by 17 · see citing works
Possibility of H2O2 decomposition in thin liquid films on Mars
Keresztúri, Á., & Góbi, S. (2014) · Planetary and Space Science · doi:10.1016/j.pss.2014.07.017 · Cited by 15 · see citing works
Uncertainties in the Capillary Filling of Heterogeneous Water Nanochannels
Ramazani, F., & Ebrahimi, F. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b03182 · Cited by 15 · see citing works
Birth of Biomolecules from the Warm Wet Sheets of Clays Near Spreading Centers
Williams, L. B., Holloway, J., Canfield, B., Glein, C. R., Dick, J. M., Hartnett, H. E., & Shock, E. L. (2010) · Springer eBooks · doi:10.1007/978-90-481-8794-2_4 · Cited by 13 · see citing works
Interfacial water studies and their relevance for the energy sector
Striolo, A. (2016) · Molecular Physics · doi:10.1080/00268976.2016.1237685 · Cited by 10 · see citing works
Bryan, C. R., Dewers, T. A., Heath, J. E., Wang, Y., Matteo, E., Meserole, S. P., & TALLANT, D. R. (2013) · doi:10.2172/1096255 · Cited by 8 · see citing works
Mobility of chloride through cement-based materials under partially saturated conditions
Savoye, S., Macé, N., Lefevre, S., et al. (2018) · Applied Geochemistry · doi:10.1016/j.apgeochem.2018.06.011 · Cited by 6 · see citing works
Clays and clay minerals : proceedings of the Ninth National Conference on Clays and Clay Minerals
Swineford, A. (1962) · Pergamon Press eBooks · Cited by 4 · see citing works
Comparing the activation energy of diffusion in bulk and ultrathin fluid films
Grabowski, C. A., & Mukhopadhyay, A. (2007) · The Journal of Chemical Physics · doi:10.1063/1.2802198 · Cited by 3 · see citing works
Flagged first, then by citations
Research works printed but not linked: 5
- [4]4. Y. F. Wang, C. Bryan, H. F. Xu and H. Z. Gao, Nanogeochemistry: Geochemical reactions and mass transfers in nanopores, Geology, 2003, 31, 387-390.
- [68]68. J. S. Loring, Q. R. S. Miller, H. T. Schaef and C. J. Thompson, in Science of Carbon Storage in Deep Saline Formations: Process Coupling across Time and Spatial Scales, eds. P. Newell and A. G. Ilgen, Elsevier, 1st edn., 2018.
- [69]69. J. P. Kaszuba, L. L. Williams, D. R. Janecky, W. K. Hollis and I. N. Tsimpanogiannis, Immiscible CO 2 -H 2 O fluids in the shallow crust, Geochem. Geophys. Geosyst., 2006, 7(10), Q10003.
- [94]94. J. H. Kwak, J. Z. Hu, R. V. F. Turcu, K. M. Rosso, E. S. Ilton, C. Wang, J. A. Sears, M. H. Engelhard, A. R. Felmy and D. W. Hoyt, The role of H 2 O in the carbonation of forsterite in supercritical CO 2 , Int. J. Greenhouse Gas Control, 2011, 5, 1081-1092.
- [106]106. T. F. Kazmierczak, M. B. Tomson and G. H. Nancollas, Crystal growth of calcium carbonate. A controlled composition kinetic study, J. Phys. Chem., 1982, 86, 103- 107. 125.
Cited by
Sorted by citations
Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films
Abdolhosseini Qomi, M. J., Miller, Q. R. S., Zare, S., Schaef, H. T., Kaszuba, J. P., & Rosso, K. M. (2022) · Nature Reviews Chemistry · doi:10.1038/s41570-022-00418-1 · Cited by 147 · see citing works
Self-citationPlacencia-Gómez, E., Kerisit, S. N., Mehta, H. S., Qafoku, O., Thompson, C. J., Graham, T. R., Ilton, E. S., & Loring, J. S. (2020) · Environmental Science & Technology · doi:10.1021/acs.est.0c00897 · Cited by 57 · see citing works
Self-citationSaeki, N., Kurihara, R., Ohkubo, T., Teramoto, A., Suda, Y., Kitagaki, R., & Maruyama, I. (2025) · Cement and Concrete Research · doi:10.1016/j.cemconres.2024.107777 · Cited by 48 · see citing works
Kerisit, S. N., Mergelsberg, S. T., Thompson, C. J., White, S. K., & Loring, J. S. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.1c03370 · Cited by 42 · see citing works
Self-citationChai, Y. E., Miller, Q. R. S., Schaef, H. T., Barpaga, D., Bakhshoodeh, R., Bodor, M., Van Gerven, T., & Santos, R. M. (2021) · The Journal of Supercritical Fluids · doi:10.1016/j.supflu.2021.105191 · Cited by 29 · see citing works
Self-citationMolecular Intermediate in the Directed Formation of a Zeolitic Metal–Organic Framework
Sinnwell, M. A., Miller, Q. R. S., Palys, L., Barpaga, D., Liu, L., Bowden, M. E., Han, Y., Ghose, S., Sushko, M. L., Schaef, H. T., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c07862 · Cited by 21 · see citing works
Self-citation
- Authors
- Miller, Q. R. S., Kaszuba, J. P., Kerisit, S. N., Schaef, H. T., Bowden, M. E., McGrail, B. P., & Rosso, K. M.
- Affiliations
- University of Wyoming (US)
- Physical and Computational Sciences Directorate
- Pacific Northwest National Laboratory (US)
- Corresponding author
- Miller, Quin R. S.
- ORCID
- Venue
- Environmental Science: Nano
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2020
- Volume
- 7
- Issue
- 4
- Pages
- 1068-1081
- ISSN
- 2051-8153 (ISSN-L)
- 2051-8161
- OpenAlex
- W3008671197
- Semantic Scholar
- 6bf512b96fad8254528c11e7d0b8e21c912ade15
- Cited by
- 41
- References
- 144
- Citations by year
- 2026: 11 · 2025: 10 · 2024: 4 · 2023: 3 · 2022: 4 · 2021: 7 · 2020: 2
- FWCI
- 1.44
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Locations
- Environmental Science Nano (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Chemical Sciences, Geosciences, and Biosciences Division
- School of Energy Resources, University of Wyoming
- Office of Fossil Energy
- University of Wyoming
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Materials Science › Biomaterials › Calcium Carbonate Crystallization and Inhibition
- Physical Sciences › Engineering › Biomedical Engineering › Nanopore and Nanochannel Transport Studies
- Keywords
- CO2 mineralization, nanoconfined water, ion diffusivity, carbon sequestration, in situ X-ray diffraction, molecular simulation
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review