Critical Water Coverage during Forsterite Carbonation in Thin Water Films: Activating Dissolution and Mass Transport
Open accessAbstract
In geologic carbon sequestration, CO 2 is injected into geologic reservoirs as a supercritical fluid (scCO 2 ). The carbonation of divalent silicates exposed to humidified scCO 2 occurs in angstroms to nanometers thick adsorbed H 2 O films. A threshold H 2 O film thickness is required for carbonate precipitation, but a mechanistic understanding is lacking. In this study, we investigated carbonation of forsterite (Mg 2 SiO 4 ) in humidified scCO 2 (50 °C and 90 bar), which serves as a model system for understanding subsurface divalent silicate carbonation reactivity. Attenuated total reflection infrared spectroscopy pinpointed that magnesium carbonate precipitation begins at 1.5 monolayers of adsorbed H 2 O. At about this same H 2 O coverage, transmission infrared spectroscopy showed that forsterite dissolution begins and electrical impedance spectroscopy demonstrated that diffusive transport accelerates. Molecular dynamics simulations indicated that the onset of diffusion is due to an abrupt decrease in the free-energy barriers for lateral mobility of outer-spherically adsorbed Mg 2+ . The dissolution and mass transport controls on divalent silicate reactivity in wet scCO 2 could be advantageous for maximizing permeability near the wellbore and minimize leakage through the caprock.
Integrity signals
Registry
Cites
Statistics
Claims the paper makes
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The text we found for this paper looks like another document, so the self-check wasn’t run.
Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156 · see citing works
The missing term in effective pair potentials
Berendsen, H. J. C., Grigera, J. R., & Straatsma, T. P. (1987) · The Journal of Physical Chemistry · doi:10.1021/j100308a038 · Cited by 13,313 · see citing works
Cygan, R. T., Liang, J.-J., & Kalinichev, A. G. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0363287 · Cited by 3,244 · see citing works
DL_POLY_2.0: A general-purpose parallel molecular dynamics simulation package
Smith, W. R., & Forester, T. R. (1996) · Journal of Molecular Graphics · doi:10.1016/s0263-7855(96)00043-4 · Cited by 2,231 · see citing works
Soil water repellency: its causes, characteristics and hydro-geomorphological significance
Doerr, S. H., Shakesby, R. A., & Walsh, R. P. D. (2000) · Earth-Science Reviews · doi:10.1016/s0012-8252(00)00011-8 · Cited by 1,670 · see citing works
Harris, J. G., & Yung, K. H. (1995) · The Journal of Physical Chemistry · doi:10.1021/j100031a034 · Cited by 1,573 · see citing works
Humidity Sensors Principle, Mechanism, and Fabrication Technologies: A Comprehensive Review
Farahani, H., Wagiran, R., & Hamidon, M. N. (2014) · Sensors · doi:10.3390/s140507881 · Cited by 1,286 · see citing works
Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions
Matter, J. M., Stute, M., Snæbjörnsdottir, S. Ó., Oelkers, E. H., Gislason, S. R., Aradottir, E. S., Sigfusson, B., Gunnarsson, I., Sigurdardottir, H., Gunnlaugsson, E., et al. (2016) · Science · doi:10.1126/science.aad8132 · Cited by 1,076 · see citing works
Anomalously low dielectric constant of confined water
Fumagalli, L., Esfandiar, A., Fabregas, R., Hu, S., Ares, P., Janardanan, A., Yang, Q., Radha, B., Taniguchi, T., Watanabe, K., et al. (2018) · Science · doi:10.1126/science.aat4191 · Cited by 1,067 · see citing works
Carbon dioxide storage through mineral carbonation
Snæbjörnsdóttir, S. Ó., Sigfússon, B., Marieni, C., Goldberg, D., Gislason, S. R., & Oelkers, E. H. (2020) · Nature Reviews Earth & Environment · doi:10.1038/s43017-019-0011-8 · Cited by 977 · see citing works
Ultrafast Graphene Oxide Humidity Sensors
Borini, S., White, R. W. P., Wei, D., Astley, M., Haque, S., Spigone, E., Harris, N., Kivioja, J. M., & Ryhänen, T. (2013) · ACS Nano · doi:10.1021/nn404889b · Cited by 901 · see citing works
Schoonen, M. A. A., & Barnes, H. L. (1992) · Geochimica et Cosmochimica Acta · doi:10.1016/0016-7037(92)90335-g · Cited by 795 · see citing works
Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks
Gaus, I. (2010) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2009.09.015 · Cited by 693 · see citing works
Oelkers, E. H., Gislason, S. R., & Matter, J. (2008) · Elements · doi:10.2113/gselements.4.5.333 · Cited by 676 · see citing works
Permanent storage of carbon dioxide in geological reservoirs by mineral carbonation
Matter, J. M., & Kelemen, P. B. (2009) · Nature Geoscience · doi:10.1038/ngeo683 · Cited by 662 · see citing works
Electrochemical Impedance Spectroscopy
Orazem, M. E., & Tribollet, B. (2017) · Wiley eBooks · doi:10.1002/9781119363682 · Cited by 593 · see citing works
Facile Fabrication of MoS2-Modified SnO2 Hybrid Nanocomposite for Ultrasensitive Humidity Sensing
Zhang, D., Sun, Y., Li, P., et al. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.6b02206 · Cited by 518 · see citing works
Tang, M., Cziczo, D. J., & Grassian, V. H. (2016) · Chemical Reviews · doi:10.1021/acs.chemrev.5b00529 · Cited by 502 · see citing works
Gaus, I., Azaroual, M., & Czernichowski-Lauriol, I. (2005) · Chemical Geology · doi:10.1016/j.chemgeo.2004.12.016 · Cited by 442 · see citing works
Giammar, D. E., Bruant, R. G., & Peters, C. A. (2005) · Chemical Geology · doi:10.1016/j.chemgeo.2004.12.013 · Cited by 418 · see citing works
Gislason, S. R., & Oelkers, E. H. (2014) · Science · doi:10.1126/science.1250828 · Cited by 358 · see citing works
Dielectric Constant of Water Confined in a Nanocavity
Senapati, S., & Chandra, A. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp011058i · Cited by 302 · see citing works
Adsorption of water vapour on α-Fe 2 O 3
McCafferty, E., & Zettlemoyer, A. C. (1971) · Discussions of the Faraday Society · doi:10.1039/df9715200239 · Cited by 264 · see citing works
The linear and non-linear electrical properties of the electrode-electrolyte interface
McAdams, E. T., Lackermeier, A., McLaughlin, J. A., Macken, D., & JOSSINET, J. (1995) · Biosensors and Bioelectronics · doi:10.1016/0956-5663(95)96795-z · Cited by 243 · see citing works
Li, N., Jiang, Y., Zhou, C., et al. (2019) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.9b12168 · Cited by 241 · see citing works
Field Validation of Supercritical CO<sub>2</sub> Reactivity with Basalts
McGrail, B. P., Schaef, H. T., Spane, F. A., Cliff, J. B., Qafoku, O., Horner, J. A., Thompson, C. J., Owen, A. T., & Sullivan, C. E. (2017) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.6b00387 · Cited by 232 · see citing works
Self-citationWater properties under nano-scale confinement
Knight, A. W., Kalugin, N. G., Coker, E. N., & Ilgen, A. (2019) · Scientific Reports · doi:10.1038/s41598-019-44651-z · Cited by 219 · see citing works
Interfacial water dielectric-permittivity-profile measurements using atomic force microscopy
Teschke, O., Ceotto, G., & de Souza, E. F. (2001) · Physical Review E · doi:10.1103/physreve.64.011605 · Cited by 209 · see citing works
Water reactivity in the liquid and supercritical CO2 phase: Has half the story been neglected?
McGrail, B. P., Schaef, H. T., Glezakou, V., Dang, L. X., & Owen, A. T. (2009) · Energy Procedia · doi:10.1016/j.egypro.2009.02.131 · Cited by 200 · see citing works
In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO <sub>2</sub>
Loring, J. S., Thompson, C. J., Wang, Z., Joly, A. G., Sklarew, D. S., Schaef, H. T., Ilton, E. S., Rosso, K. M., & Felmy, A. R. (2011) · Environmental Science & Technology · doi:10.1021/es201284e · Cited by 197 · see citing works
Self-citationOn sorption and swelling of CO2 in clays
Busch, A., Bertier, P., Gensterblum, Y., Rother, G., Spiers, C. J., Zhang, M., & Wentinck, H. M. (2016) · Geomechanics and Geophysics for Geo-Energy and Geo-Resources · doi:10.1007/s40948-016-0024-4 · Cited by 185 · see citing works
Giesting, P. A., Guggenheim, S., van Groos, A. F. K., & Busch, A. (2012) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2012.01.011 · Cited by 180 · see citing works
Hongfei, L. I. N., Fujii, T., Takisawa, R., Takahashi, T., & Hashida, T. (2007) · Journal of Materials Science · doi:10.1007/s10853-007-2029-4 · Cited by 165 · see citing works
The Wallula basalt sequestration pilot project
McGrail, B. P., Spane, F. A., Sullivan, E. C., Bacon, D. H., & Hund, G. (2011) · Energy Procedia · doi:10.1016/j.egypro.2011.02.557 · Cited by 160 · see citing works
Schaef, H. T., Ilton, E. S., Qafoku, O. S., Martin, P. F. C., Felmy, A. R., & Rosso, K. M. (2012) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2011.11.001 · Cited by 144 · see citing works
Self-citationMechanism of wollastonite carbonation deduced from micro- to nanometer length scale observations
Daval, D., Martinez, I., Guigner, J., Hellmann, R., Corvisier, J., Findling, N., Dominici, C., Goffé, B., & Guyot, F. (2009) · American Mineralogist · doi:10.2138/am.2009.3294 · Cited by 141 · see citing works
Geochemistry of Geologic Carbon Sequestration: An Overview
DePaolo, D. J., & Cole, D. R. (2013) · Reviews in Mineralogy and Geochemistry · doi:10.2138/rmg.2013.77.1 · Cited by 137 · see citing works
The role of H2O in the carbonation of forsterite in supercritical CO2
Kwak, J. H., Hu, J. Z., Turcu, R. V. F., Rosso, K. M., Ilton, E. S., Wang, C., Sears, J. A., Engelhard, M. H., Felmy, A. R., & Hoyt, D. W. (2011) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2011.05.013 · Cited by 136 · see citing works
Self-citationLoring, J. S., Schaef, H. T., Turcu, F., Thompson, C. J., Miller, Q. R. S., Martin, P. F. C., Hu, J. Z., Hoyt, D. W., Qafoku, O. S., Ilton, E. S., et al. (2012) · Langmuir · doi:10.1021/la301136w · Cited by 134 · see citing works
Self-citationA trapped water network in nanoporous material: the role of interfaces
Le Caër, S., Pin, S., Esnouf, S., Raffy, Q., Renault, J. P., Brubach, J.-B., Creff, G., & Roy, P. (2011) · Physical Chemistry Chemical Physics · doi:10.1039/c1cp21980d · Cited by 131 · see citing works
Competitive sorption of CO2 and H2O in 2:1 layer phyllosilicates
Schaef, H. T., Loring, J. S., Glezakou, V., Miller, Q. R. S., Chen, J., Owen, A. T., Lee, M., Ilton, E. S., Felmy, A. R., McGrail, B. P., et al. (2015) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2015.03.027 · Cited by 112 · see citing works
Self-citationCO2 Mineral Sequestration in Naturally Porous Basalt
Xiong, W., Wells, R. K., Horner, J. A., Schaef, H. T., Skemer, P., & Giammar, D. E. (2018) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.8b00047 · Cited by 110 · see citing works
Insights into silicate carbonation processes in water-bearing supercritical CO2 fluids
Miller, Q. R. S., Thompson, C. J., Loring, J. S., Windisch, C. F., Bowden, M. E., Hoyt, D. W., Hu, J. Z., Arey, B. W., Rosso, K. M., & Schaef, H. T. (2013) · International Journal of Greenhouse Gas Control · doi:10.1016/j.ijggc.2013.02.005 · Cited by 109 · see citing works
Self-citationInfrared ansorption frequency trends for anhydrous normal carbonates
Hans, H. A., & Paul, F. (1963) · American Mineralogist · Cited by 109 · see citing works
Infrared spectra, symmentry and structure relations of some carbonate minerals
Adler, H. H., & Kerr, P. F. (1963) · American Mineralogist · Cited by 108 · see citing works
Todd Schaef, H., McGrail, B. P., Loring, J. L., Bowden, M. E., Arey, B. W., & Rosso, K. M. (2013) · Environmental Science & Technology · doi:10.1021/es301126f · Cited by 108 · see citing works
Self-citationCO2 mineral trapping in fractured basalt
Xiong, W., Wells, R. K., Menefee, A. H., Skemer, P., Ellis, B. R., & Giammar, D. E. (2017) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2017.10.003 · Cited by 107 · see citing works
Loring, J. S., Ilton, E. S., Chen, J., Thompson, C. J., Martin, P. F. C., Bénézeth, P., Rosso, K. M., Felmy, A. R., & Schaef, H. T. (2014) · Langmuir · doi:10.1021/la500682t · Cited by 106 · see citing works
Self-citationRother, G., Ilton, E. S., Wallacher, D., Hauß, T., Schaef, H. T., Qafoku, O. S., Rosso, K. M., Felmy, A. R., Krukowski, E. G., Stack, A. G., et al. (2012) · Environmental Science & Technology · doi:10.1021/es301382y · Cited by 106 · see citing works
Self-citationKwak, J. H., Hu, J. Z., Hoyt, D. W., Sears, J. A., Wang, C., Rosso, K. M., & Felmy, A. R. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp1001308 · Cited by 105 · see citing works
Experimental Correlation Between Interfacial Water Structure and Mineral Reactivity
Dewan, S., Yeganeh, M. S., & Borguet, E. (2013) · The Journal of Physical Chemistry Letters · doi:10.1021/jz4007417 · Cited by 105 · see citing works
Sissmann, O. J., Brunet, F., Martinez, I., Guyot, F., Verlaguet, A., Pinquier, Y., & Daval, D. (2014) · Environmental Science & Technology · doi:10.1021/es405508a · Cited by 104 · see citing works
X-ray Diffraction Study of K- and Ca-Exchanged Montmorillonites in CO2 Atmospheres
Giesting, P. A., Guggenheim, S., van Groos, A. F. K., et al. (2012) · Environmental Science & Technology · doi:10.1021/es3005865 · Cited by 99 · see citing works
Miller, Q. R. S., Schaef, H. T., Kaszuba, J. P., Gadikota, G., McGrail, B. P., & Rosso, K. M. (2019) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.9b00301 · Cited by 98 · see citing works
Ilton, E. S., Schaef, H. T., Qafoku, O. S., Rosso, K. M., & Felmy, A. R. (2012) · Environmental Science & Technology · doi:10.1021/es300234v · Cited by 93 · see citing works
Self-citationWater and carbon dioxide adsorption at olivine surfaces
Kerisit, S., Bylaska, E. J., & Felmy, A. R. (2013) · Chemical Geology · doi:10.1016/j.chemgeo.2013.10.004 · Cited by 89 · see citing works
Self-citationLoring, J. S., Thompson, C. J., Zhang, C., Wang, Z., Schaef, H. T., & Rosso, K. M. (2012) · The Journal of Physical Chemistry A · doi:10.1021/jp210020t · Cited by 86 · see citing works
Self-citationFactors affecting wollastonite carbonation under CO2 supercritical conditions
Tai, C. Y.-D., Chen, W. ‐., & Shih, S. (2005) · AIChE Journal · doi:10.1002/aic.10572 · Cited by 84 · see citing works
Structure and dynamics of forsterite–scCO2/H2O interfaces as a function of water content
Kerisit, S., Weare, J. H., & Felmy, A. R. (2012) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2012.01.038 · Cited by 84 · see citing works
Self-citationWollastonite Carbonation in Water-Bearing Supercritical CO<sub>2</sub>: Effects of Particle Size
Min, Y., Li, Q., Voltolini, M., Kneafsey, T., & Jun, Y.-S. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.7b04475 · Cited by 74 · see citing works
Daval, D. (2018) · npj Materials Degradation · doi:10.1038/s41529-018-0035-4 · Cited by 70 · see citing works
Fayalite dissolution and siderite formation in water-saturated supercritical CO2
Qafoku, O., Kovarik, L., Kukkadapu, R. K., Ilton, E. S., Arey, B. W., Tucek, J., & Felmy, A. R. (2012) · Chemical Geology · doi:10.1016/j.chemgeo.2012.09.028 · Cited by 69 · see citing works
Self-citationRegnault, O., Lagneau, V., Catalette, H., & Schneider, H. (2005) · Comptes Rendus Géoscience · doi:10.1016/j.crte.2005.07.012 · Cited by 68 · see citing works
Loring, J. S., Chen, J., Bénézeth, P., Qafoku, O., Ilton, E. S., Washton, N. M., Thompson, C. J., Martin, P. F., McGrail, B. P., Rosso, K. M., et al. (2015) · Langmuir · doi:10.1021/acs.langmuir.5b01052 · Cited by 65 · see citing works
Self-citationSoil wettability can be explained by the chemical composition of particle interfaces - An XPS study
Woche, S. K., Goebel, M., Mikutta, R., et al. (2017) · Scientific Reports · doi:10.1038/srep42877 · Cited by 65 · see citing works
Bowers, G. M., Schaef, H. T., Loring, J. S., Hoyt, D. W., Burton, S., Walter, É., & Kirkpatrick, R. J. (2016) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.6b11542 · Cited by 64 · see citing works
Self-citationThompson, C. J., Loring, J. S., Rosso, K. M., & Wang, Z.-M. (2013) · International journal of greenhouse gas control · doi:10.1016/j.ijggc.2013.07.007 · Cited by 54 · see citing works
Self-citationTang, M., Larish, W. A., Fang, Y., Gankanda, A., & Grassian, V. H. (2016) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.6b05395 · Cited by 53 · see citing works
Min, Y., & Jun, Y.-S. (2018) · Chemical Geology · doi:10.1016/j.chemgeo.2018.01.012 · Cited by 52 · see citing works
Tunable Manipulation of Mineral Carbonation Kinetics in Nanoscale Water Films via Citrate Additives
Miller, Q. R. S., Schaef, H. T., Kaszuba, J. P., Qiu, L., Bowden, M. E., & McGrail, B. P. (2018) · Environmental Science & Technology · doi:10.1021/acs.est.8b00438 · Cited by 50 · see citing works
Qafoku, O., Hu, J., Hess, N. J., Hu, M. Y., Ilton, E. S., Feng, J., Arey, B. W., & Felmy, A. R. (2014) · Geochimica et Cosmochimica Acta · doi:10.1016/j.gca.2013.09.024 · Cited by 49 · see citing works
Self-citationIon Diffusion Within Water Films in Unsaturated Porous Media
Tokunaga, T. K., Finsterle, S., Kim, Y., Wan, J., Lanzirotti, A., & Newville, M. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b05891 · Cited by 46 · see citing works
Tipping Point for Expansion of Layered Aluminosilicates in Weakly Polar Solvents: Supercritical CO2
Schaef, H. T., Loganathan, N., Bowers, G. M., Kirkpatrick, R. J., Yazaydın, A. Ö., Burton, S., Hoyt, D. W., Thanthiriwatte, K. S., Dixon, D. A., McGrail, B. P., et al. (2017) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.7b10590 · Cited by 46 · see citing works
Self-citationAutomated high-pressure titration system with in situ infrared spectroscopic detection
Thompson, C. J., Martin, P. F. C., Chen, J., Bénézeth, P., Schaef, H. T., Rosso, K. M., Felmy, A. R., & Loring, J. S. (2014) · Review of Scientific Instruments · doi:10.1063/1.4870411 · Cited by 45 · see citing works
Self-citationImpacts of Organic Ligands on Forsterite Reactivity in Supercritical CO<sub>2</sub> Fluids
Miller, Q. R. S., Kaszuba, J. P., Schaef, H. T., Bowden, M. E., & McGrail, B. P. (2015) · Environmental Science & Technology · doi:10.1021/es506065d · Cited by 44 · see citing works
Carbon Sequestration in Olivine and Basalt Powder Packed Beds
Xiong, W., Wells, R. K., & Giammar, D. E. (2017) · Environmental Science & Technology · doi:10.1021/acs.est.6b05011 · Cited by 44 · see citing works
Dynamics of Magnesite Formation at Low Temperature and High pCO <sub>2</sub> in Aqueous Solution
Qafoku, O., Dixon, D. A., Rosso, K. M., Schaef, H. T., Bowden, M. E., Arey, B. W., & Felmy, A. R. (2015) · Environmental Science & Technology · doi:10.1021/acs.est.5b02588 · Cited by 42 · see citing works
Self-citationSurface-Catalyzed Oxygen Exchange during Mineral Carbonation in Nanoscale Water Films
Miller, Q. R. S., Dixon, D. A., Burton, S. D., Walter, E. D., Hoyt, D. W., McNeill, A. S., Moon, J. D., Thanthiriwatte, K. S., Ilton, E. S., Qafoku, O., et al. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b02215 · Cited by 42 · see citing works
Self-citationMiller, Q. R. S., Kaszuba, J. P., Kerisit, S. N., Schaef, H. T., Bowden, M. E., McGrail, B. P., & Rosso, K. M. (2020) · Environmental Science: Nano · doi:10.1039/c9en01382b · Cited by 41 · see citing works
Self-citationRole of Fe(II) Content in Olivine Carbonation in Wet Supercritical CO<sub>2</sub>
Wood, C. E., Qafoku, O., Loring, J. S., & Chaka, A. M. (2019) · Environmental Science & Technology Letters · doi:10.1021/acs.estlett.9b00496 · Cited by 39 · see citing works
Self-citationInterfacial reactions of Cu( ii ) adsorption and hydrolysis driven by nano-scale confinement
Knight, A. W., Ilani‐Kashkouli, P., Harvey, J., Greathouse, J. A., Ho, T. A., Kabengi, N. J., & Ilgen, A. (2019) · Environmental Science Nano · doi:10.1039/c9en00855a · Cited by 38 · see citing works
Bowers, G. M., Hoyt, D. W., Burton, S., et al. (2014) · The Journal of Physical Chemistry C · doi:10.1021/jp410535d · Cited by 34 · see citing works
Fang, Y., Tang, M., & Grassian, V. H. (2016) · The Journal of Physical Chemistry A · doi:10.1021/acs.jpca.6b02262 · Cited by 33 · see citing works
Bowers, G. M., Loring, J. S., Schaef, H. T., Walter, É., Burton, S., Hoyt, D. W., Cunniff, S. S., Loganathan, N., & Kirkpatrick, R. J. (2018) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.8b00039 · Cited by 33 · see citing works
Self-citationSynthesis of nanometer-sized fayalite and magnesium-iron(II) mixture olivines
Qafoku, O. S., Ilton, E. S., Bowden, M., Kovařík, L., Zhang, X., Kukkadapu, R., Engelhard, M., Thompson, C. J., Schaef, H. T., McGrail, B. P., et al. (2018) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2018.01.036 · Cited by 28 · see citing works
Self-citationTime-Resolved Studies of Water Dynamics and Proton Transfer at the Alumina−Air Interface
Le Caër, S., Palmer, D. J., Lima, M., Renault, J. P., Vigneron, G., Righini, R., & Pommeret, S. (2007) · Journal of the American Chemical Society · doi:10.1021/ja0691730 · Cited by 25 · see citing works
Water Solubility at Saturation for CO2–CH4 Mixtures at 323.2 K and 9.000 MPa
Loring, J. S., Bacon, D. H., Springer, R., Anderko, A., Gopinath, S., Yonkofski, C. M. R., Thompson, C. J., McGrail, B. P., Rosso, K. M., & Schaef, H. T. (2017) · Journal of Chemical & Engineering Data · doi:10.1021/acs.jced.6b00999 · Cited by 25 · see citing works
Self-citationBowers, G. M., Loring, J. S., Schaef, H. T., Cunniff, S. S., Walter, É., Burton, S., Larsen, R. K., Miller, Q. R. S., Bowden, M., Ilton, E. S., et al. (2019) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.9b00038 · Cited by 24 · see citing works
Self-citation13C Nuclear Magnetic Resonance Spectroscopy of Methane and Carbon Dioxide in a Natural Shale
Bowers, G. M., Schaef, H. T., Miller, Q. R. S., et al. (2019) · ACS Earth and Space Chemistry · doi:10.1021/acsearthspacechem.8b00214 · Cited by 22 · see citing works
Bowers, G. M., Loring, J. S., Walter, É., Burton, S., Bowden, M., Hoyt, D. W., Arey, B. W., Larsen, R. K., & Kirkpatrick, R. J. (2019) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.9b08875 · Cited by 20 · see citing works
Self-citationWater Structure Controls Carbonic Acid Formation in Adsorbed Water Films
Miller, Q. R. S., Ilton, E. S., Qafoku, O., Dixon, D. A., Vasiliu, M., Thompson, C. J., Schaef, H. T., Rosso, K. M., & Loring, J. S. (2018) · The Journal of Physical Chemistry Letters · doi:10.1021/acs.jpclett.8b02162 · Cited by 19 · see citing works
Self-citationSpectral induced polarization of low-pH cement and concrete
Leroy, P., Hördt, A., Gaboreau, S., Zimmermann, E., Claret, F., Bücker, M., Stebner, H., & Huisman, J. A. (2019) · Cement and Concrete Composites · doi:10.1016/j.cemconcomp.2019.103397 · Cited by 16 · see citing works
Finite Size Effects on Hydrogen Bonds in Confined Water
Musat, R. M., Renault, J., Candelaresi, M., Palmer, D. J., Caër, S. L., Righini, R., & Pommeret, S. (2008) · Angewandte Chemie · doi:10.1002/ange.200802630 · Cited by 4 · see citing works
Flagged first, then by citations
Research works printed but not linked: 8
- [4]4. Boulet-Audet, M.; Buffeteau, T.; Boudreault, S.; Daugey, N.; Pézolet, M. Quantitative determination of band distortions in diamond attenuated total reflectance infrared spectra, J. Phys. Chem. B 2010, 114, 8255-8261.
- [5]5. Harrick, N. J. Internal Reflection Spectroscopy; John Wiley & Sons: New York, 1967.
- [6]6. Bertie, J. E.; Eysel, H. H. Infrared intensities of liquids I: Determination of infrared optical and dielectric constants by FT-IR using the CIRCLE ATR cell, Appl. Spectrosc. 1985, 39, 392-401.
- [7]7. Bertie, J. E.; Zhang, S. L.; Manji, R. Infrared intensities of liquids X: Accuracy of current methods of obtaining optical constants from multiple attenuated total reflection measurements using the CIRCLE cell, Appl. Spectrosc. 1992, 46, 1660-1665.
- [8]8. Ohta, K.; Ishida, H. Matrix formalism for calculation of electric field intensity of light in stratified multilayered films, Appl. Opt. 1990, 29, 1952-1959.
- [9]9. Loring, J. S.; Land, D. P. Theoretical determination of parameters for optimum surface specificity in overlayer attenuated-total-reflection infrared spectroscopy, Appl. Opt. 1998, 37, 3515- 3526.
- [11]11. de Juan, A.; Tauler, R. Multivariate curve resolution (MCR) from 2000: Progress in concepts and applications, Crit. Rev. Anal. Chem. 2006, 36, 163-176.
- [12]12. Yeşilbaş, M.; Boily, J.-F. Thin ice films at mineral surfaces, J. Phys. Chem. Lett. 2016, 7, 2849-2855.
Cited by
Sorted by citations
Molecular-scale mechanisms of CO2 mineralization in nanoscale interfacial water films
Abdolhosseini Qomi, M. J., Miller, Q. R. S., Zare, S., Schaef, H. T., Kaszuba, J. P., & Rosso, K. M. (2022) · Nature Reviews Chemistry · doi:10.1038/s41570-022-00418-1 · Cited by 147 · see citing works
Saeki, N., Kurihara, R., Ohkubo, T., Teramoto, A., Suda, Y., Kitagaki, R., & Maruyama, I. (2025) · Cement and Concrete Research · doi:10.1016/j.cemconres.2024.107777 · Cited by 48 · see citing works
Kerisit, S. N., Mergelsberg, S. T., Thompson, C. J., White, S. K., & Loring, J. S. (2021) · Environmental Science & Technology · doi:10.1021/acs.est.1c03370 · Cited by 42 · see citing works
Self-citationMergelsberg, S. T., Kerisit, S. N., Ilton, E. S., Qafoku, O., Thompson, C. J., & Loring, J. S. (2020) · Chemical Communications · doi:10.1039/d0cc04907g · Cited by 35 · see citing works
Self-citationReactive force fields for aqueous and interfacial magnesium carbonate formation
Zare, S., & Qomi, M. J. A. (2021) · Physical Chemistry Chemical Physics · doi:10.1039/d1cp02627e · Cited by 24 · see citing works
- Authors
- Placencia-Gómez, E., Kerisit, S. N., Mehta, H. S., Qafoku, O., Thompson, C. J., Graham, T. R., Ilton, E. S., & Loring, J. S.
- Affiliations
- University of Liège (BE)
- Physical and Computational Sciences Directorate, Pacific Northwest National Laboratory, Richland, Washington 99354, United States
- Pacific Northwest National Laboratory (US)
- Corresponding author
- Loring, John S.
- ORCID
- Venue
- Environmental Science & Technology
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-05-08
- Volume
- 54
- Issue
- 11
- Pages
- 6888-6899
- ISSN
- 0013-936X (ISSN-L)
- 1520-5851
- OpenAlex
- W3022034930
- Semantic Scholar
- d634817e800d2739016ace55edc33b657b7c4961
- Cited by
- 57
- References
- 93
- Citations by year
- 2026: 9 · 2025: 15 · 2024: 15 · 2023: 5 · 2022: 7 · 2021: 5 · 2020: 1
- FWCI
- 1.62
- Type
- journal article
- Language
- en
- Open access
- green
- www.osti.gov
- Licence
- Locations
- Environmental Science & Technology (publishedVersion)
- PubMed (publishedVersion)
- OSTI OAI (U.S. Department of Energy Office of Scientific and Technical Information) (submittedVersion)
- Funders
- Basic Energy Sciences
- Topics
- Physical Sciences › Environmental Science › Environmental Engineering › CO2 Sequestration and Geologic Interactions
- Physical Sciences › Engineering › Biomedical Engineering › Subcritical and Supercritical Water Processes
- Physical Sciences › Chemical Engineering › Process Chemistry and Technology › Carbon dioxide utilization in catalysis
- Keywords
- supercritical carbon dioxide, adsorbed water films, magnesium carbonate precipitation, mass transfer, activation barrier, geologic carbon sequestration, carbonate precipitation
- MeSH terms
- Carbon Dioxide, Carbonates, Solubility, Water, Silicon Compounds
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review