The DOI matches its Crossref record; 43 of the 43 references it cites were found in a registry or an index.
N-Heterocyclic Carbene—Main-Group Chemistry: A Rapidly Evolving Field
Abstract
This Award Article targets the evolving, yet surprisingly fruitful, chemistry of N-heterocyclic carbenes with low-oxidation-state main-group elements. Specifically, the chemistry of carbene-stabilized diatomic allotropes, diborenes, gallium octahedra, beryllium borohydride, and a host of related compounds will be presented. Providing a valuable historical perspective, the foundational work concerning the organometallic chemistry of gallium with sterically demanding m-terphenyl ligands from this laboratory will also be discussed.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
(1999) · Choice Reviews Online · doi:10.5860/choice.37-0940 · Cited by 14,314
Comprehensive Coordination Chemistry
Eaborn, C. (1988) · Journal of Organometallic Chemistry · doi:10.1016/0022-328x(88)83103-6 · Cited by 7,163
Cordero, B., Gómez, V., Platero-Prats, A. E., Revés, M., Echeverría, J., Cremades, E., Barragán, F., & Alvarez, S. (2008) · Dalton Transactions · doi:10.1039/b801115j · Cited by 4,169
Nucleus-Independent Chemical Shifts (NICS) as an Aromaticity Criterion
Chen, Z., Wannere, C. S., Corminboeuf, C., Puchta, R., & Schleyer, P. V. R. (2005) · Chemical Reviews · doi:10.1021/cr030088+ · Cited by 3,847
Bourissou, D., Guerret, O., Gabbaï, F. P., & Bertrand, G. (2000) · Chemical Reviews · doi:10.1021/cr940472u · Cited by 3,633
Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes
Melaimi, M., Soleilhavoup, M., & Bertrand, G. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201000165 · Cited by 1,066
Facile Splitting of Hydrogen and Ammonia by Nucleophilic Activation at a Single Carbon Center
Frey, G. D., Lavallo, V., Donnadieu, B., Schoeller, W. W., & Bertrand, G. (2007) · Science · doi:10.1126/science.1141474 · Cited by 954
Advances in Organometallic Chemistry
Curtis, M. D. (1978) · Journal of Organometallic Chemistry · doi:10.1016/s0022-328x(00)90390-5 · Cited by 718
Stable singlet carbenes as mimics for transition metal centers
Martin, D., Soleilhavoup, M., & Bertrand, G. (2011) · Chem. Sci. · doi:10.1039/c0sc00388c · Cited by 666
Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond
Braunschweig, H., Dewhurst, R. D., Hammond, K., Mies, J., Radacki, K., & Vargas, A. (2012) · Science · doi:10.1126/science.1221138 · Cited by 559
Carbene-stabilized main group radicals and radical ions
Martin, C. D., Soleilhavoup, M., & Bertrand, G. (2013) · Chemical Science · doi:10.1039/c3sc51174j · Cited by 499
Spherical Aromaticity: Recent Work on Fullerenes, Polyhedral Boranes, and Related Structures
Chen, Z., & King, R. B. (2005) · Chemical Reviews · doi:10.1021/cr0300892 · Cited by 482
Early-Transition-Metal-Mediated Activation and Transformation of White Phosphorus
Cossairt, B. M., Piro, N. A., & Cummins, C. C. (2010) · Chemical Reviews · doi:10.1021/cr9003709 · Cited by 463
Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis
FLOCH, P. (2006) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.04.032 · Cited by 452
P4 Activation by Late-Transition Metal Complexes
Caporali, M., Gonsalvi, L., Rossin, A., & Peruzzini, M. (2010) · Chemical Reviews · doi:10.1021/cr900349u · Cited by 448
Pyykkö, P., Riedel, S., & Patzschke, M. (2005) · Chemistry – A European Journal · doi:10.1002/chem.200401299 · Cited by 426
A Brief Survey of Our Contribution to Stable Carbene Chemistry
Martin, D., Melaimi, M., Soleilhavoup, M., & Bertrand, G. (2011) · Organometallics · doi:10.1021/om200650x · Cited by 422
Carbene-Stabilized Diphosphorus
Wang, Y., Xie, Y., Wei, P., King, R. B., Schaefer, H. F., Schleyer, P. V. R., & Robinson, G. H. (2008) · Journal of the American Chemical Society · doi:10.1021/ja807828t · Cited by 388
Self-citationCarbene Stabilization of Highly Reactive Main-Group Molecules
Wang, Y., & Robinson, G. H. (2011) · Inorganic Chemistry · doi:10.1021/ic200675u · Cited by 380
Self-citationOrbital Overlap and Chemical Bonding
Krapp, A., Bickelhaupt, F. M., & Frenking, G. (2006) · Chemistry - A European Journal · doi:10.1002/chem.200600564 · Cited by 352
Isolation of crystalline carbene-stabilized P2-radical cations and P2-dications
Back, O., Donnadieu, B., Parameswaran, P., Frenking, G., & Bertrand, G. (2010) · Nature Chemistry · doi:10.1038/nchem.617 · Cited by 307
Carbene Activation of P4 and Subsequent Derivatization
Masuda, J. D., Schoeller, W. W., Donnadieu, B., & Bertrand, G. (2007) · Angewandte Chemie International Edition · doi:10.1002/anie.200703055 · Cited by 291
Li, X.-W., Pennington, W. T., & Robinson, G. H. (1995) · Journal of the American Chemical Society · doi:10.1021/ja00133a045 · Cited by 254
Self-citationCarbene-stabilized main group diatomic allotropes
Wang, Y., & Robinson, G. H. (2012) · Dalton Trans. · doi:10.1039/c1dt11165e · Cited by 240
Self-citationCopper N-heterocyclic carbene complexes in catalysis
Egbert, J. D., Cazin, C. S. J., & Nolan, S. P. (2013) · Catalysis Science & Technology · doi:10.1039/c2cy20816d · Cited by 228
Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy
Abraham, M. Y., Wang, Y., Xie, Y., Wei, P., Schaefer, H. F., Schleyer, P. V. R., & Robinson, G. H. (2010) · Chemistry – A European Journal · doi:10.1002/chem.200902840 · Cited by 209
Self-citationBorwasserstoffe, IX.: B 3 N 3 H 6
Stock, A., & Pohland, E. (1926) · Berichte der deutschen chemischen Gesellschaft (A and B Series) · doi:10.1002/cber.19260590907 · Cited by 208
Dill, J. D., Schleyer, P. V. R., & Pople, J. A. (1975) · Journal of the American Chemical Society · doi:10.1021/ja00845a021 · Cited by 207
Triple-Bond Reactivity of Diphosphorus Molecules
Piro, N. A., Figueroa, J. S., McKellar, J. T., & Cummins, C. C. (2006) · Science · doi:10.1126/science.1129630 · Cited by 204
DFT study of “all-metal” aromatic compounds
Tsipis, C. A. (2005) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2005.01.031 · Cited by 180
SYNTHESIS OF THE s-TRIPHENYLCYCLOPROPENYL CATION
Breslow, R. (1957) · Journal of the American Chemical Society · doi:10.1021/ja01576a067 · Cited by 173
Grigsby, W. J., & Power, P. P. (1997) · Chemistry - A European Journal · doi:10.1002/chem.19970030308 · Cited by 156
Masters, S. L., Morrison, C. A., Rankin, D. W. H., et al. (2001) · Journal of the American Chemical Society · doi:10.1021/ja010615b · Cited by 135
The Nature of the Gallium−Gallium Triple Bond
Xie, Y., Grev, R. S., Gu, J., Schaefer, H. F., Schleyer, P. V. R., Su, J., Li, X.-W., & Robinson, G. H. (1998) · Journal of the American Chemical Society · doi:10.1021/ja9739300 · Cited by 125
Self-citationReduction of a Boron–Nitrogen 1,3‐Butadiene Analogue: Evidence for a Strong BB π‐Bond
Moezzi, A., Bartlett, R. A., & Power, P. P. (1992) · Angewandte Chemie International Edition in English · doi:10.1002/anie.199210821 · Cited by 124
Twamley, B., & Power, P. P. (2000) · Angewandte Chemie International Edition · Cited by 113
Photochemical Incorporation of Diphosphorus Units into Organic Molecules
Tofan, D. C., & Cummins, C. C. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.201004385 · Cited by 100
Are Cyclogallenes [M2(GaH)3] (M = Li, Na, K) Aromatic?
Xie, Y., Schreiner, P. R., Schaefer, H. F., Li, X.-W., & Robinson, G. H. (1996) · Journal of the American Chemical Society · doi:10.1021/ja9616701 · Cited by 85
Self-citationYoon, C. W., Carroll, P. J., & Sneddon, L. G. (2008) · Journal of the American Chemical Society · doi:10.1021/ja808045p · Cited by 82
Mitoraj, M. P., & Michalak, A. (2011) · Inorganic Chemistry · doi:10.1021/ic101576g · Cited by 78
A Neutral Ga6 Octahedron: Synthesis, Structure, and Aromaticity
Quillian, B., Wei, P., Wannere, C. S., Schleyer, P. V. R., & Robinson, G. H. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809945v · Cited by 66
Self-citationIngleson, M. J., Barrio, J. P., Bacsa, J., Steiner, A., Darling, G. R., Jones, J. T. A., Khimyak, Y. Z., & Rosseinsky, M. J. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200804196 · Cited by 44
Hollow nanoparticles excel in lubrication
DAGANI, R. (1997) · Chemical & Engineering News · doi:10.1021/cen-v075n025.p009a · Cited by 14
Metadata
- Authors
- Wang, Y., & Robinson, G. H.
- Venue
- Inorganic Chemistry
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-10-24
- Volume
- 53
- Issue
- 22
- Pages
- 11815-11832
- ISSN
- 0020-1669 (ISSN-L)
- 1520-510X
- OpenAlex
- W2314303973
- Cited by
- 266
- References
- 43
- FWCI
- 14.67
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.