The DOI matches its Crossref record.
Electrocatalytic reduction of carbon dioxide by using macrocycles of nickel and cobalt
Abstract
Carbon dioxide has been activated towards reduction by electrochemically primed transition metal complexes. This indirect reduction allows more favorable electrode potentials than those required when CO2 is reduced directly. The metal complexes employed were Curtis type tetraazamacrocyclic complexes of nickel and cobalt. The electrode potentials ranged from -1.3v to -1.6v vs SCE. Evidence for CO2 reduction was obtained from controlled potential coulometry experiments performed in a gas tight electrolysis cell followed by g.c. analysis. The solvents used were either CH3CN-H2O or water only. Carbon monoxide was found to comprise at least 50% of the total reduced products in all cases; H2 was also produced in most cases. While a protic source was found to be necessary for CO2 reduction to occur, the results show that CO2 competes effectively with H+ for the electrons available from the electrochemically reduced metal complexes. In addition, the reduction was found to be electrocatalytic, with current efficiencies for total reduced products as high as 98%. (Author)
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
Qiao, J., Liu, Y., Hong, F., & Zhang, J. (2014) · Chem. Soc. Rev. · doi:10.1039/c3cs60323g · Cited by 2,990
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Chatenet, M., Pollet, B. G., Dekel, D. R., Dionigi, F., Deseure, J., Millet, P., Braatz, R. D., Bazant, M. Z., Eikerling, M., Staffell, I., et al. (2022) · Chemical Society Reviews · doi:10.1039/d0cs01079k · Cited by 2,025
Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
A Molecular MoS 2 Edge Site Mimic for Catalytic Hydrogen Generation
Karunadasa, H. I., Montalvo, E., Sun, Y., Majda, M., Long, J. R., & Chang, C. J. (2012) · Science · doi:10.1126/science.1215868 · Cited by 1,215
Hawecker, J., Lehn, J., & Ziessel, R. (1986) · Helvetica Chimica Acta · doi:10.1002/hlca.19860690824 · Cited by 688
Thoi, V. S., Sun, Y., Long, J. R., & Chang, C. J. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35272a · Cited by 668
Sun, Y., Liu, C., Grauer, D. C., Yano, J., Long, J. R., Yang, P., & Chang, C. J. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4094764 · Cited by 556
Electrochemical CO2 Reduction: Recent Advances and Current Trends
Jones, J., Prakash, G. K. S., & Olah, G. A. (2014) · Israel Journal of Chemistry · doi:10.1002/ijch.201400081 · Cited by 425
Chen, L., Guo, Z., Wei, X.-G., Gallenkamp, C., Bonin, J., Anxolabéhère-Mallart, E., Lau, K.-C., Lau, T.-C., & Robert, M. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06535 · Cited by 359
Electrocatalytic Hydrogen Evolution in Acidic Water with Molecular Cobalt Tetraazamacrocycles
McCrory, C. C. L., Uyeda, C., & Peters, J. C. (2012) · Journal of the American Chemical Society · doi:10.1021/ja210661k · Cited by 351
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Kuramochi, Y., Ishitani, O., & Ishida, H. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.023 · Cited by 325
Metal centers in the anaerobic microbial metabolism of CO and CO2
Bender, G., Pierce, E., Hill, J. A., Darty, J. E., & Ragsdale, S. W. (2011) · Metallomics · doi:10.1039/c1mt00042j · Cited by 68
Metadata
- Authors
- Fisher, B. J., & Eisenberg, R.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 1980-11
- Volume
- 102
- Issue
- 24
- Pages
- 7361-7363
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2010252868
- Cited by
- 559
- References
- 0
- FWCI
- 2.88
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
