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Enhanced Emission and Its Switching in Fluorescent Organic Nanoparticles
Abstract
A new class of organic nanoparticles (CN-MBE nanoparticles) with a mean diameter of ca. 30-40 nm, which exhibit a strongly enhanced fluorescence emission, were prepared by a simple reprecipitation method. CN-MBE (1-cyano-trans-1,2-bis-(4'-methylbiphenyl)ethylene) is very weakly fluorescent in solution, but the intensity is increased by almost 700 times in the nanoparticles. Enhanced emission in CN-MBE nanoparticles is attributed to the synergetic effect of intramolecular planarization and J-type aggregate formation (restricted excimer formation) in nanopaticles. On/off fluorescence switching for organic vapor was demonstrated with CN-MBE nanoparticles.
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Metadata
- Authors
- An, B.-K., Kwon, S.-K., Jung, S.-D., & Park, S. Y.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2002-11-08
- Volume
- 124
- Issue
- 48
- Pages
- 14410-14415
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2067816052
- Cited by
- 1,952
- References
- 1
- FWCI
- 10.53
- Type
- journal article
- Language
- en
- Open access
- closed
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