The DOI matches its Crossref record; 78 of the 78 references it cites were found in a registry or an index.
Kinetics of Monodisperse Iron Oxide Nanocrystal Formation by “Heating-Up” Process
Abstract
We studied the kinetics of the formation of iron oxide nanocrystals obtained from the solution-phase thermal decomposition of iron-oleate complex via the "heating-up" process. To obtain detailed information on the thermal decomposition process and the formation of iron oxide nanocrystals in the solution, we performed a thermogravimetric-mass spectrometric analysis (TG-MS) and in-situ magnetic measurements using SQUID. The TG-MS results showed that iron-oleate complex was decomposed at around 320 degrees C. The in-situ SQUID data revealed that the thermal decomposition of iron-oleate complex generates intermediate species, which seem to act as monomers for the iron oxide nanocrystals. Extensive studies on the nucleation and growth process using size exclusion chromatography, the crystallization yield data, and TEM showed that the sudden increase in the number concentration of the nanocrystals (burst of nucleation) is followed by the rapid narrowing of the size distribution (size focusing). We constructed a theoretical model to describe the "heating-up" process and performed a numerical simulation. The simulation results matched well with the experimental data, and furthermore they are well fitted to the well-known LaMer model that is characterized by the burst of nucleation and the separation of nucleation and growth under continuous monomer supply condition. Through this theoretical work, we showed that the "heating-up" and "hot injection" processes could be understood within the same theoretical framework in which they share the characteristics of nucleation and growth stages.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Semiconductor Clusters, Nanocrystals, and Quantum Dots
Alivisatos, A. P. (1996) · Science · doi:10.1126/science.271.5251.933 · Cited by 11,528
Murray, C. B., Norris, D. J., & Bawendi, M. G. (1993) · Journal of the American Chemical Society · doi:10.1021/ja00072a025 · Cited by 9,282
Semiconductor Nanocrystals as Fluorescent Biological Labels
Bruchez, M., Moronne, M., Gin, P., Weiss, S., & Alivisatos, A. P. (1998) · Science · doi:10.1126/science.281.5385.2013 · Cited by 8,613
Quantum Dots for Live Cells, in Vivo Imaging, and Diagnostics
Michalet, X., Pinaud, F. F., Bentolila, L. A., Tsay, J. M., Doose, S., Li, J. J., Sundaresan, G., Wu, A. M., Gambhir, S. S., & Weiss, S. (2005) · Science · doi:10.1126/science.1104274 · Cited by 7,790
Quantum Dot Bioconjugates for Ultrasensitive Nonisotopic Detection
Chan, W. C. W., & Nie, S. (1998) · Science · doi:10.1126/science.281.5385.2016 · Cited by 7,278
Quantum dot bioconjugates for imaging, labelling and sensing
Medintz, I. L., Uyeda, H. T., Goldman, E. R., & Mattoussi, H. (2005) · Nature Materials · doi:10.1038/nmat1390 · Cited by 6,229
Monodisperse FePt Nanoparticles and Ferromagnetic FePt Nanocrystal Superlattices
Sun, S., Murray, C. B., Weller, D., Folks, L., & Moser, A. (2000) · Science · doi:10.1126/science.287.5460.1989 · Cited by 6,137
Experimental Determination of the Extinction Coefficient of CdTe, CdSe, and CdS Nanocrystals
Yu, W. W., Qu, L., Guo, W., & Peng, X. (2003) · Chemistry of Materials · doi:10.1021/cm034081k · Cited by 4,997
Shape control of CdSe nanocrystals
Peng, X., Manna, L., Yang, W., Wickham, J., Scher, E., Kadavanich, A., & Alivisatos, A. P. (2000) · Nature · doi:10.1038/35003535 · Cited by 4,487
Ultra-large-scale syntheses of monodisperse nanocrystals
Park, J., An, K., Hwang, Y., Park, J.-G., Noh, H.-J., Kim, J.-Y., Park, J.-H., Hwang, N.-M., & Hyeon, T. (2004) · Nature Materials · doi:10.1038/nmat1251 · Cited by 4,076
Self-citationTheory, Production and Mechanism of Formation of Monodispersed Hydrosols
LaMer, V. K., & Dinegar, R. H. (1950) · Journal of the American Chemical Society · doi:10.1021/ja01167a001 · Cited by 3,894
Perspectives on the Physical Chemistry of Semiconductor Nanocrystals
Alivisatos, A. P. (1996) · The Journal of Physical Chemistry · doi:10.1021/jp9535506 · Cited by 3,595
Size-Controlled Synthesis of Magnetite Nanoparticles
Sun, S., & Zeng, H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja026501x · Cited by 2,829
Some Interesting Properties of Metals Confined in Time and Nanometer Space of Different Shapes
El-Sayed, M. A. (2001) · Accounts of Chemical Research · doi:10.1021/ar960016n · Cited by 2,773
Formation of High-Quality CdTe, CdSe, and CdS Nanocrystals Using CdO as Precursor
Peng, Z. A., & Peng, X. (2001) · Journal of the American Chemical Society · doi:10.1021/ja003633m · Cited by 2,741
Hyeon, T., Lee, S. S., Park, J., Chung, Y., & Na, H. B. (2001) · Journal of the American Chemical Society · doi:10.1021/ja016812s · Cited by 2,040
Self-citationPeng, X., Wickham, J., & Alivisatos, A. P. (1998) · Journal of the American Chemical Society · doi:10.1021/ja9805425 · Cited by 1,895
Chemical synthesis of magnetic nanoparticles
Hyeon, T. (2003) · Chemical Communications · doi:10.1039/b207789b · Cited by 1,576
Self-citationPeng, Z. A., & Peng, X. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0173167 · Cited by 1,524
Talapin, D. V., Rogach, A. L., Kornowski, A., Haase, M., & Weller, H. (2001) · Nano Letters · doi:10.1021/nl0155126 · Cited by 1,506
Nanoscale Materials in Chemistry
(2001) · Wiley eBooks · doi:10.1002/0471220620 · Cited by 1,397
Yu, W. W., & Peng, X. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020703)41:13<2368::aid-anie2368>3.0.co;2-g · Cited by 1,294
Spanhel, L., Haase, M., Weller, H., & Henglein, A. (1987) · Journal of the American Chemical Society · doi:10.1021/ja00253a015 · Cited by 1,250
Finite-size effects in fine particles: magnetic and transport properties
Batlle, X., & Labarta, A. (2002) · Journal of Physics D: Applied Physics · doi:10.1088/0022-3727/35/6/201 · Cited by 1,173
The Quantum Mechanics of Larger Semiconductor Clusters ("Quantum Dots")
Bawendi, M. G., Steigerwald, M. L., & Brus, L. E. (1990) · Annual Review of Physical Chemistry · doi:10.1146/annurev.pc.41.100190.002401 · Cited by 1,158
Katari, J. E. B., Colvin, V. L., & Alivisatos, A. P. (1994) · The Journal of Physical Chemistry · doi:10.1021/j100066a034 · Cited by 1,103
Melting in Semiconductor Nanocrystals
Goldstein, A. N., Echer, C. M., & Alivisatos, A. P. (1992) · Science · doi:10.1126/science.256.5062.1425 · Cited by 1,059
Colloidal synthesis of nanocrystals and nanocrystal superlattices
Murray, C. B., Sun, S., Gaschler, W., Doyle, H., Betley, T. A., & Kagan, C. R. (2001) · IBM Journal of Research and Development · doi:10.1147/rd.451.0047 · Cited by 1,048
Sun, S., & Murray, C. B. (1999) · Journal of Applied Physics · doi:10.1063/1.370357 · Cited by 1,018
Semiconductor crystallites: a class of large molecules
Steigerwald, M. L., & Brus, L. E. (1990) · Accounts of Chemical Research · doi:10.1021/ar00174a003 · Cited by 992
Alternative Routes toward High Quality CdSe Nanocrystals
Qu, L., Peng, Z. A., & Peng, X. (2001) · Nano Letters · doi:10.1021/nl0155532 · Cited by 959
Preparation of monodispersed colloidal particles
Sugimoto, T. (1987) · Advances in Colloid and Interface Science · doi:10.1016/0001-8686(87)80009-x · Cited by 937
Shape Control and Associated Magnetic Properties of Spinel Cobalt Ferrite Nanocrystals
Song, Q., & Zhang, Z. J. (2004) · Journal of the American Chemical Society · doi:10.1021/ja049931r · Cited by 845
Large Clusters of Metal Ions: The Transition from Molecular to Bulk Magnets
Gatteschi, D., Caneschi, A., Pardi, L., & Sessoli, R. (1994) · Science · doi:10.1126/science.265.5175.1054 · Cited by 844
One‐Nanometer‐Scale Size‐Controlled Synthesis of Monodisperse Magnetic Iron Oxide Nanoparticles
Park, J., Lee, E., Hwang, N., Kang, M., Kim, S. C., Hwang, Y., Park, J., Noh, H., Kim, J., Park, J., et al. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200461665 · Cited by 652
Self-citationMagnetic recording: advancing into the future
Moser, A., Takano, K., Margulies, D. T., Albrecht, M., Sonobe, Y., Ikeda, Y., Sun, S., & Fullerton, E. E. (2002) · Journal of Physics D Applied Physics · doi:10.1088/0022-3727/35/19/201 · Cited by 650
Nanoparticles and Nanostructured Films: Preparation, Characterization and Applications
(1998) · Wiley eBooks · doi:10.1002/9783527612079 · Cited by 634
Quantum Dots in Biological and Biomedical Research: Recent Progress and Present Challenges
Klostranec, J. M., & Chan, W. C. W. (2006) · Advanced Materials · doi:10.1002/adma.200500786 · Cited by 630
Park, J., Kang, E., Son, S. U., Park, H. M., Lee, M. K., Kim, J., Kim, K. W., Noh, H. ‐., Park, J. ‐., Bae, C. J., et al. (2005) · Advanced Materials · doi:10.1002/adma.200400611 · Cited by 592
Self-citationFormation of High Quality InP and InAs Nanocrystals in a Noncoordinating Solvent
Battaglia, D., & Peng, X. (2002) · Nano Letters · doi:10.1021/nl025687v · Cited by 576
Influence of Iron Oleate Complex Structure on Iron Oxide Nanoparticle Formation
Bronstein, L. M., Huang, X., Retrum, J., Schmucker, A., Pink, M., Stein, B. D., & Dragnea, B. (2007) · Chemistry of Materials · doi:10.1021/cm062948j · Cited by 576
Bright UV-Blue Luminescent Colloidal ZnSe Nanocrystals
Hines, M. A., & Guyot-Sionnest, P. (1998) · The Journal of Physical Chemistry B · doi:10.1021/jp9810217 · Cited by 554
Colloidal Synthesis and Self-Assembly of CoPt3 Nanocrystals
Shevchenko, E. V., Talapin, D. V., Rogach, A. L., Kornowski, A., Haase, M., & Weller, H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja025976l · Cited by 544
Murray, C. B., Sun, S., Doyle, H., & Betley, T. (2001) · MRS Bulletin · doi:10.1557/mrs2001.254 · Cited by 533
Evolution of an Ensemble of Nanoparticles in a Colloidal Solution: Theoretical Study
Talapin, D. V., Rogach, A. L., Haase, M., & Weller, H. (2001) · The Journal of Physical Chemistry B · doi:10.1021/jp012229m · Cited by 524
Colloidal chemical synthesis and characterization of InAs nanocrystal quantum dots
Guzelian, A. A., Banin, U., Kadavanich, A. V., Peng, X., & Alivisatos, A. P. (1996) · Applied Physics Letters · doi:10.1063/1.117605 · Cited by 515
Talapin, D. V., Rogach, A. L., Shevchenko, E. V., Kornowski, A., Haase, M., & Weller, H. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0123599 · Cited by 480
Organometallic Synthesis and Spectroscopic Characterization of Manganese-Doped CdSe Nanocrystals
Mikulec, F. V., Kuno, M., Bennati, M., Hall, D. A., Griffin, R. G., & Bawendi, M. G. (2000) · Journal of the American Chemical Society · doi:10.1021/ja991249n · Cited by 479
Growth and Properties of Semiconductor Core/Shell Nanocrystals with InAs Cores
Cao, & Banin, U. (2000) · Journal of the American Chemical Society · doi:10.1021/ja001386g · Cited by 460
Yu, W. W., Falkner, J. C., Shih, B. S., & Colvin, V. L. (2004) · Chemistry of Materials · doi:10.1021/cm049476y · Cited by 426
Synthesis of Monodisperse Palladium Nanoparticles
Kim, S.-W., Park, J., Jang, Y., Chung, Y., Hwang, S., Hyeon, T., & Kim, Y. W. (2003) · Nano Letters · doi:10.1021/nl0343405 · Cited by 421
Self-citationNucleation and Growth Kinetics of CdSe Nanocrystals in Octadecene
Bullen, C. R., & Mulvaney, P. A. (2004) · Nano Letters · doi:10.1021/nl0496724 · Cited by 393
Yu, W. W., Falkner, J. C., Shih, B. S., & Colvin, V. L. (2004) · ChemInform · doi:10.1002/chin.200443230 · Cited by 375
High Quality ZnSe and ZnS Nanocrystals Formed by Activating Zinc Carboxylate Precursors
Li, L. S., Pradhan, N., Wang, Y., & Peng, X. (2004) · Nano Letters · doi:10.1021/nl048650e · Cited by 373
Size-dependent catalytic activity of supported metal clusters
Xu, Z., Xiao, F.-S., Purnell, S. K., Alexeev, O., Kawi, S., Deutsch, S. E., & Gates, B. C. (1994) · Nature · doi:10.1038/372346a0 · Cited by 372
One-Step Synthesis of FePt Nanoparticles with Tunable Size
Chen, M., Liu, J. P., & Sun, S. (2004) · Journal of the American Chemical Society · doi:10.1021/ja047648m · Cited by 368
The Growth of Uniform Colloidal Dispersions
Reiss, H. (1951) · The Journal of Chemical Physics · doi:10.1063/1.1748251 · Cited by 336
Synthesis, Stabilization, and Electronic Structure of Quantum Semiconductor Nanoclusters
Steigerwald, M. L., & Brus, L. E. (1989) · Annual Review of Materials Science · doi:10.1146/annurev.ms.19.080189.002351 · Cited by 310
Puntes, V. F., Krishnan, K. M., & Alivisatos, P. (2001) · Applied Physics Letters · doi:10.1063/1.1362333 · Cited by 306
Preparation and Characterization of Monodisperse Fe Nanoparticles
Farrell, D. F., Majetich, S. A., & Wilcoxon, J. P. (2003) · The Journal of Physical Chemistry B · doi:10.1021/jp0351831 · Cited by 303
De Jesus, J. C., González, I., Quevedo, A., & Puerta, T. (2005) · Journal of Molecular Catalysis A: Chemical · doi:10.1016/j.molcata.2004.09.065 · Cited by 257
Supramolecular Complexes from CdSe Nanocrystals and Organic Fluorophors
Schmelz, O., Mews, A., Basché, T., Herrmann, A., & Müllen, K. (2001) · Langmuir · doi:10.1021/la0016367 · Cited by 236
Uk Son, S., Kyu Park, I., Park, J., & Hyeon, T. (2004) · Chemical Communications · doi:10.1039/b316147a · Cited by 223
Self-citationNucleation and Growth of CdSe Nanocrystals in a Binary Ligand System
van Embden, J., & Mulvaney, P. (2005) · Langmuir · doi:10.1021/la051081l · Cited by 219
(2001) · Elsevier eBooks · doi:10.1016/b978-0-444-89569-1.x5016-7 · Cited by 218
Magnetic recording beyond the first 100 Years
Speliotis, D. (1999) · Journal of Magnetism and Magnetic Materials · doi:10.1016/s0304-8853(98)00399-0 · Cited by 212
Direct Synthesis of Narrowly Dispersed Silver Nanoparticles Using a Single-Source Precursor
Lin, X. Z., Teng, X., & Yang, H. (2003) · Langmuir · doi:10.1021/la035185c · Cited by 196
Shape Evolution and Self Assembly of Monodisperse PbTe Nanocrystals
Lu, W., Fang, J., Stokes, K. L., & Lin, J. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0469131 · Cited by 177
Size Distributions of Gold Nanoclusters Studied by Liquid Chromatography
Wilcoxon, J. P., Martin, J. E., & Provencio, P. (2000) · Langmuir · doi:10.1021/la000669j · Cited by 168
Polyol Process Synthesis of Monodispersed FePt Nanoparticles
Liu, C., Wu, X., Klemmer, T. J., Shukla, N., Yang, X., Weller, D., Roy, A. G., Tanase, M., & Laughlin, D. E. (2004) · The Journal of Physical Chemistry B · doi:10.1021/jp0312971 · Cited by 154
Synthesis of spherical FePd and CoPt nanoparticles
Chen, M., & Nikles, D. E. (2002) · Journal of Applied Physics · doi:10.1063/1.1456406 · Cited by 152
Heterogeneous Growth of Metal Clusters from Solutions of Seed Nanoparticles
Wilcoxon, J. P., & Provencio, P. P. (2004) · Journal of the American Chemical Society · doi:10.1021/ja031622y · Cited by 136
Synthesis, Self-Assembly, and Magnetic Properties of FexCoyPt100-x-y Nanoparticles
Chen, M., & Nikles, D. E. (2002) · Nano Letters · doi:10.1021/nl015649w · Cited by 133
Impact of Ripening on Manganese-Doped ZnSe Nanocrystals
Zu, L., Norris, D. J., Kennedy, T. A., Erwin, S. C., & Efros, A. L. (2005) · Nano Letters · doi:10.1021/nl051732y · Cited by 111
Roto, R., & Villemure, G. (2002) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(02)00834-3 · Cited by 69
Davis, R. A., & Schultz, H. P. (1962) · The Journal of Organic Chemistry · doi:10.1021/jo01050a039 · Cited by 43
Murugan, A. V., Reddy, M. V., Campet, G., & Vijayamohanan, K. (2007) · Journal of Electroanalytical Chemistry · doi:10.1016/j.jelechem.2007.02.013 · Cited by 37
(2002) · doi:10.1002/1616-3028(20021016)12:10<653::aid-adfm653>3.0.co;2-v
Cited by
Mechanisms of Nucleation and Growth of Nanoparticles in Solution
Thanh, N. T. K., Maclean, N., & Mahiddine, S. (2014) · Chemical Reviews · doi:10.1021/cr400544s · Cited by 3,399
Synthesis, Functionalization, and Biomedical Applications of Multifunctional Magnetic Nanoparticles
Hao, R., Xing, R., Xu, Z., Hou, Y., Gao, S., & Sun, S. (2010) · Advanced Materials · doi:10.1002/adma.201000260 · Cited by 1,372
Magnetic nanoparticles: preparation, physical properties, and applications in biomedicine
Akbarzadeh, A., Samiei, M., & Davaran, S. (2012) · Nanoscale Research Letters · doi:10.1186/1556-276x-7-144 · Cited by 1,241
Localized Surface Plasmon Resonance in Semiconductor Nanocrystals
Agrawal, A., Cho, S. H., Zandi, O., Ghosh, S., Johns, R. W., & Milliron, D. J. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.7b00613 · Cited by 1,014
Compound Copper Chalcogenide Nanocrystals
Coughlan, C., Ibáñez, M., Dobrozhan, O., Singh, A., Cabot, A., & Ryan, K. M. (2017) · Chemical Reviews · doi:10.1021/acs.chemrev.6b00376 · Cited by 930
Metadata
- Authors
- Kwon, S. G., Piao, Y., Park, J., Angappane, S., Jo, Y., Hwang, N.-M., Park, J.-G., & Hyeon, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2007-09-22
- Volume
- 129
- Issue
- 41
- Pages
- 12571-12584
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2016265500
- Cited by
- 473
- References
- 78
- FWCI
- 13.81
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
