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Polyelectrolyte Functionalized Carbon Nanotubes as Efficient Metal-free Electrocatalysts for Oxygen Reduction
Abstract
Having a strong electron-withdrawing ability, poly(diallyldimethylammonium chloride) (PDDA) was used to create net positive charge for carbon atoms in the nanotube carbon plane via intermolecular charge transfer. The resultant PDDA functionalized/adsorbed carbon nanotubes (CNTs), either in an aligned or nonaligned form, were demonstrated to act as metal-free catalysts for oxygen reduction reaction (ORR) in fuel cells with similar performance as Pt catalysts. The adsorption-induced intermolecular charge-transfer should provide a general approach to various carbon-based efficient metal-free ORR catalysts for oxygen reduction in fuel cells, and even new catalytic materials for applications beyond fuel cells.
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Metadata
- Authors
- Wang, S., Yu, D., & Dai, L.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-03-17
- Volume
- 133
- Issue
- 14
- Pages
- 5182-5185
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2002634552
- Cited by
- 724
- References
- 3
- FWCI
- 28.50
- Type
- journal article
- Language
- en
- Open access
- closed
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