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Synergistic Catalysis of Metal–Organic Framework-Immobilized Au–Pd Nanoparticles in Dehydrogenation of Formic Acid for Chemical Hydrogen Storage
Abstract
Bimetallic Au-Pd nanoparticles (NPs) were successfully immobilized in the metal-organic frameworks (MOFs) MIL-101 and ethylenediamine (ED)-grafted MIL-101 (ED-MIL-101) using a simple liquid impregnation method. The resulting composites, Au-Pd/MIL-101 and Au-Pd/ED-MIL-101, represent the first highly active MOF-immobilized metal catalysts for the complete conversion of formic acid to high-quality hydrogen at a convenient temperature for chemical hydrogen storage. Au-Pd NPs with strong bimetallic synergistic effects have a much higher catalytic activity and a higher tolerance with respect to CO poisoning than monometallic Au and Pd counterparts.
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Metadata
- Authors
- Gu, X., Lu, Z.-H., Jiang, H.-L., Akita, T., & Xu, Q.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-07-19
- Volume
- 133
- Issue
- 31
- Pages
- 11822-11825
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2323003947
- Cited by
- 810
- References
- 1
- FWCI
- 25.87
- Type
- journal article
- Language
- en
- Open access
- closed
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