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Selective CO2 Conversion to Formate Conjugated with H2O Oxidation Utilizing Semiconductor/Complex Hybrid Photocatalysts
Abstract
Photoelectrochemical reduction of CO(2) to HCOO(-) (formate) over p-type InP/Ru complex polymer hybrid photocatalyst was highly enhanced by introducing an anchoring complex into the polymer. By functionally combining the hybrid photocatalyst with TiO(2) for water oxidation, selective photoreduction of CO(2) to HCOO(-) was achieved in aqueous media, in which H(2)O was used as both an electron donor and a proton source. The so-called Z-scheme (or two-step photoexcitation) system operated with no external electrical bias. The selectivity for HCOO(-) production was >70%, and the conversion efficiency of solar energy to chemical energy was 0.03-0.04%.
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Citations
Cited by
Tu, W., Zhou, Y., & Zou, Z. (2014) · Advanced Materials · doi:10.1002/adma.201400087 · Cited by 1,635
Direct Z-scheme photocatalysts: Principles, synthesis, and applications
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Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Metal‐Free Carbon Materials for CO2 Electrochemical Reduction
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Yaashikaa, P. R., Senthil Kumar, P., Varjani, S. J., & Saravanan, A. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.05.017 · Cited by 508
Kuriki, R., Matsunaga, H., Nakashima, T., Wada, K., Yamakata, A., Ishitani, O., & Maeda, K. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01997 · Cited by 482
Advances in molecular photocatalytic and electrocatalytic CO2 reduction
Windle, C. D., & Perutz, R. N. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.03.010 · Cited by 481
Vu, N., Kaliaguine, S., & Do, T. (2019) · Advanced Functional Materials · doi:10.1002/adfm.201901825 · Cited by 445
Atomic‐Level Reactive Sites for Semiconductor‐Based Photocatalytic CO2 Reduction
Zhang, Y., Xia, B., Ran, J., Davey, K., & Qiao, S. Z. (2020) · Advanced Energy Materials · doi:10.1002/aenm.201903879 · Cited by 423
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Kuramochi, Y., Ishitani, O., & Ishida, H. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.023 · Cited by 325
Kuriki, R., Yamamoto, M., Higuchi, K., Yamamoto, Y., Akatsuka, M., Lu, D., Yagi, S., Yoshida, T., Ishitani, O., & Maeda, K. (2017) · Angewandte Chemie International Edition · doi:10.1002/anie.201701627 · Cited by 258
Nishi, T., Hayasaka, Y., Suzuki, T. M., Sato, S., Isomura, N., Takahashi, N., Kosaka, S., Nakamura, T., Sato, S., & Morikawa, T. (2018) · ChemistrySelect · doi:10.1002/slct.201800943 · Cited by 18
Self-citation
Metadata
- Authors
- Sato, S., Arai, T., Morikawa, T., Uemura, K., Suzuki, T. M., Tanaka, H., & Kajino, T.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-09-07
- Volume
- 133
- Issue
- 39
- Pages
- 15240-15243
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2034924684
- Cited by
- 500
- References
- 0
- FWCI
- 12.48
- Type
- journal article
- Language
- en
- Open access
- closed
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