The DOI matches its Crossref record; 2 of the 2 references it cites were found in a registry or an index.
Electrochemical Water Oxidation with Cobalt-Based Electrocatalysts from pH 0–14: The Thermodynamic Basis for Catalyst Structure, Stability, and Activity
Open accessAbstract
Building upon recent study of cobalt-oxide electrocatalysts in fluoride-buffered electrolyte at pH 3.4, we have undertaken a mechanistic investigation of cobalt-catalyzed water oxidation in aqueous buffering electrolytes from pH 0-14. This work includes electrokinetic studies, cyclic voltammetric analysis, and electron paramagnetic resonance (EPR) spectroscopic studies. The results illuminate a set of interrelated mechanisms for electrochemical water oxidation in alkaline, neutral, and acidic media with electrodeposited Co-oxide catalyst films (CoO(x)(cf)s) as well as for a homogeneous Co-catalyzed electrochemical water oxidation reaction. Analysis of the pH dependence of quasi-reversible features in cyclic voltammograms of the CoO(x)(cf)s provides the basis for a Pourbaix diagram that closely resembles a Pourbaix diagram derived from thermodynamic free energies of formation for a family of Co-based layered materials. Below pH 3, a shift from heterogeneous catalysis producing O(2) to homogeneous catalysis yielding H(2)O(2) is observed. Collectively, the results reported here provide a foundation for understanding the structure, stability, and catalytic activity of aqueous cobalt electrocatalysts for water oxidation.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
The Mechanism of Water Oxidation: From Electrolysis via Homogeneous to Biological Catalysis
Dau, H., Limberg, C., Reier, T., Risch, M., Roggan, S., & Strasser, P. (2010) · ChemCatChem · doi:10.1002/cctc.201000126 · Cited by 1,783
Proton-coupled electron transfer
Huynh, M. H. V., & Meyer, T. J. (2007) · Chemical Reviews · doi:10.1021/cr0500030 · Cited by 1,659
Cited by
Earth-abundant catalysts for electrochemical and photoelectrochemical water splitting
Roger, I., Shipman, M. A., & Symes, M. D. (2017) · Nature Reviews Chemistry · doi:10.1038/s41570-016-0003 · Cited by 3,503
Oh, W.-D., Dong, Z., & Lim, T.-T. (2016) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2016.04.003 · Cited by 2,612
Recent Progress in Cobalt‐Based Heterogeneous Catalysts for Electrochemical Water Splitting
Wang, J., Cui, W., Liu, Q., Xing, Z., Asiri, A. M., & Sun, X. (2016) · Advanced Materials · doi:10.1002/adma.201502696 · Cited by 2,446
Visible-light driven heterojunction photocatalysts for water splitting – a critical review
Moniz, S. J. A., Shevlin, S. A., Martin, D. J., Guo, Z.-X., & Tang, J. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03271c · Cited by 2,363
Toward the rational design of non-precious transition metal oxides for oxygen electrocatalysis
Hong, W. T., Risch, M., Stoerzinger, K. A., Grimaud, A., Suntivich, J., & Shao-Horn, Y. (2015) · Energy & Environmental Science · doi:10.1039/c4ee03869j · Cited by 2,089
Research opportunities to advance solar energy utilization
Lewis, N. S. (2016) · Science · doi:10.1126/science.aad1920 · Cited by 2,075
Xiao, Z., Huang, Y.-C., Dong, C.-L., Xie, C., Liu, Z., Du, S., Chen, W., Yan, D., Tao, L., Shu, Z., et al. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c00257 · Cited by 1,445
Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201502226 · Cited by 1,428
Artificial Photosynthesis: Molecular Systems for Catalytic Water Oxidation
Kärkäs, M. D., Verho, O., Johnston, E. V., & Åkermark, B. (2014) · Chemical Reviews · doi:10.1021/cr400572f · Cited by 1,376
Meng, Y., Song, W., Huang, H., Ren, Z., Chen, S.-Y., & Suib, S. L. (2014) · Journal of the American Chemical Society · doi:10.1021/ja505186m · Cited by 1,083
Lu, Z., Zhu, W., Yu, X., Zhang, H., Li, Y., Sun, X., Wang, X., Wang, H., Wang, J., Luo, J., et al. (2014) · Advanced Materials · doi:10.1002/adma.201304759 · Cited by 1,025
Moysiadou, A., Lee, S., Hsu, C.-S., Chen, H. M., & Hu, X. (2020) · Journal of the American Chemical Society · doi:10.1021/jacs.0c04867 · Cited by 987
Time-resolved observations of water oxidation intermediates on a cobalt oxide nanoparticle catalyst
Zhang, M., de Respinis, M., & Frei, H. (2014) · Nature Chemistry · doi:10.1038/nchem.1874 · Cited by 855
Zhang, G., Wang, G., Liu, Y., Liu, H., Qu, J., & Li, J. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08491 · Cited by 721
Correlative operando microscopy of oxygen evolution electrocatalysts
Mefford, J. T., Akbashev, A. R., Kang, M., Bentley, C. L., Gent, W. E., Deng, H. D., Alsem, D. H., Yu, Y.-S., Salmon, N. J., Shapiro, D. A., et al. (2021) · Nature · doi:10.1038/s41586-021-03454-x · Cited by 699
Recent development in electrocatalysts for hydrogen production through water electrolysis
Anwar, S., Khan, F., Zhang, Y., & Djire, A. (2021) · International Journal of Hydrogen Energy · doi:10.1016/j.ijhydene.2021.06.191 · Cited by 652
Solar‐to‐Hydrogen Energy Conversion Based on Water Splitting
Qi, J., Zhang, W., & Cao, R. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701620 · Cited by 649
Selenide‐Based Electrocatalysts and Scaffolds for Water Oxidation Applications
Xia, C., Jiang, Q., Zhao, C., Hedhili, M. N., & Alshareef, H. N. (2016) · Advanced Materials · doi:10.1002/adma.201503906 · Cited by 614
Jiang, J., Zhang, A., Li, L., & Ai, L. (2015) · Journal of Power Sources · doi:10.1016/j.jpowsour.2014.12.085 · Cited by 572
Indra, A., Song, T., & Paik, U. (2018) · Advanced Materials · doi:10.1002/adma.201705146 · Cited by 507
Water-hydroxide trapping in cobalt tungstate for proton exchange membrane water electrolysis
Ram, R., Xia, L., Benzidi, H., Guha, A., Golovanova, V., Garzón Manjón, A., Llorens Rauret, D., Sanz Berman, P., Dimitropoulos, M., Mundet, B., et al. (2024) · Science · doi:10.1126/science.adk9849 · Cited by 489
Kwak, I. H., Im, H. S., Jang, D. M., Kim, Y. W., Park, K., Lim, Y. R., Cha, E. H., & Park, J. (2016) · ACS Applied Materials & Interfaces · doi:10.1021/acsami.5b12093 · Cited by 486
Bao, J., Zhang, X., Fan, B., Zhang, J., Zhou, M., Yang, W., Hu, X., Wang, H., Pan, B., & Xie, Y. (2015) · Angewandte Chemie · doi:10.1002/ange.201502226 · Cited by 485
Ryu, J., Jung, N., Jang, J. H., Kim, H.-J., & Yoo, S. J. (2015) · ACS Catalysis · doi:10.1021/acscatal.5b00349 · Cited by 455
Kuznetsov, D. A., Han, B., Yu, Y., Rao, R. R., Hwang, J., Román-Leshkov, Y., & Shao-Horn, Y. (2018) · Joule · doi:10.1016/j.joule.2017.11.014 · Cited by 452
Liu, X., Meng, J., Zhu, J., Huang, M., Wen, B., Guo, R., & Mai, L. (2021) · Advanced Materials · doi:10.1002/adma.202007344 · Cited by 438
Electrodeposition of Crystalline Co3O4—A Catalyst for the Oxygen Evolution Reaction
Koza, J. A., He, Z., Miller, A. S., & Switzer, J. A. (2012) · Chemistry of Materials · doi:10.1021/cm3012205 · Cited by 428
Zou, X., Goswami, A., & Asefa, T. (2013) · Journal of the American Chemical Society · doi:10.1021/ja407174u · Cited by 425
Ďurovič, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.229708 · Cited by 436
Duan, P., Qi, Y., Feng, S., Peng, X., Wang, W., Yue, Y., Shang, Y., Li, Y., Gao, B., & Xu, X. (2020) · Applied Catalysis B: Environmental · doi:10.1016/j.apcatb.2020.118717 · Cited by 417
Water oxidation catalysts based on abundant 1st row transition metals
Singh, A., & Spiccia, L. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2013.02.027 · Cited by 405
Structural Changes of Cobalt-Based Perovskites upon Water Oxidation Investigated by EXAFS
Risch, M., Grimaud, A., May, K. J., Stoerzinger, K. A., Chen, T. J., Mansour, A. N., & Shao-Horn, Y. (2013) · The Journal of Physical Chemistry C · doi:10.1021/jp3126768 · Cited by 353
Recent Progress in Electrocatalysts for Acidic Water Oxidation
Lei, Z., Wang, T., Zhao, B., Cai, W., Liu, Y., Jiao, S., Li, Q., Cao, R., & Liu, M. (2020) · Advanced Energy Materials · doi:10.1002/aenm.202000478 · Cited by 336
Feng, J., Ding, L., Ye, S., He, X., Xu, H., Tong, Y., & Li, G. (2015) · Advanced Materials · doi:10.1002/adma.201503187 · Cited by 332
Tetrametallic molecular catalysts for photochemical water oxidation
Sartorel, A., Bonchio, M., Campagna, S., & Scandola, F. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35287g · Cited by 329
Recent advances in cobalt-based electrocatalysts for hydrogen and oxygen evolution reactions
Zhang, W., Cui, L., & Liu, J. (2020) · Journal of Alloys and Compounds · doi:10.1016/j.jallcom.2019.153542 · Cited by 328
Favaro, M., Yang, J., Nappini, S., Magnano, E., Toma, F. M., Crumlin, E. J., Yano, J., & Sharp, I. D. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b03211 · Cited by 323
Singh, T. I., Rajeshkhanna, G., Pan, U. N., Kshetri, T., Lin, H., Kim, N. H., & Lee, J. H. (2021) · Small · doi:10.1002/smll.202101312 · Cited by 312
Wan, S., Qi, J., Zhang, W., Wang, W., Zhang, S., Liu, K., Zheng, H., Sun, J., Wang, S., & Cao, R. (2017) · Advanced Materials · doi:10.1002/adma.201700286 · Cited by 304
ZnO As an Active and Selective Catalyst for Electrochemical Water Oxidation to Hydrogen Peroxide
Kelly, S. R., Shi, X., Back, S., Vallez, L., Park, S. Y., Siahrostami, S., Zheng, X., & Nørskov, J. K. (2019) · ACS Catalysis · doi:10.1021/acscatal.8b04873 · Cited by 298
Yang, H., Li, F., Zhan, S., Liu, Y., Li, W., Meng, Q., Kravchenko, A., Liu, T., Yang, Y., Fang, Y., et al. (2022) · Nature Catalysis · doi:10.1038/s41929-022-00783-6 · Cited by 282
Plevová, M., Hnát, J., & Bouzek, K. (2021) · Journal of Power Sources · doi:10.1016/j.jpowsour.2021.230072 · Cited by 278
Menezes, P. W., Indra, A., Sahraie, N. R., Bergmann, A., Strasser, P., & Driess, M. (2015) · ChemSusChem · doi:10.1002/cssc.201402699 · Cited by 267
Dong, C., Yuan, X., Wang, X., Liu, X., Dong, W., Wang, R., Duan, Y., & Huang, F. (2016) · Journal of Materials Chemistry A · doi:10.1039/c6ta04052g · Cited by 264
Water oxidation using earth-abundant transition metal catalysts: opportunities and challenges
Kärkäs, M. D., & Åkermark, B. (2016) · Dalton Transactions · doi:10.1039/c6dt00809g · Cited by 257
Mondschein, J. S., Callejas, J. F., Read, C. G., Chen, J. Y. C., Holder, C. F., Badding, C. K., & Schaak, R. E. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02879 · Cited by 257
Self-citationXiong, Q., Zhang, X., Wang, H., Liu, G., Wang, G., Zhang, H., & Zhao, H. (2018) · Chemical Communications · doi:10.1039/c8cc00766g · Cited by 255
Seawater electrocatalysis: activity and selectivity
Khatun, S., Hirani, H., & Roy, P. (2021) · Journal of Materials Chemistry A · doi:10.1039/d0ta08709b · Cited by 236
Zhang, W., Wu, Y., Qi, J., Chen, M., & Cao, R. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201602547 · Cited by 215
Wang, P., Song, F., Amal, R., Ng, Y. H., & Hu, X. (2016) · ChemSusChem · doi:10.1002/cssc.201501599 · Cited by 203
Yu, X., Zhang, S., Li, C., Zhu, C., Chen, Y., Gao, P., Qi, L., & Zhang, X. (2016) · Nanoscale · doi:10.1039/c6nr01867j · Cited by 165
Seo, B., Sa, Y. J., Woo, J., Kwon, K., Park, J., Shin, T. J., Jeong, H. Y., & Joo, S. H. (2016) · ACS Catalysis · doi:10.1021/acscatal.6b00553 · Cited by 153
Yu, M., Waag, F., Chan, C. K., Weidenthaler, C., Barcikowski, S., & Tüysüz, H. (2020) · ChemSusChem · doi:10.1002/cssc.201903186 · Cited by 93
Meng, T., Hao, Y.-N., Zheng, L., & Cao, M. (2018) · Nanoscale · doi:10.1039/c8nr03299h · Cited by 82
CoNiSe2 Nanostructures for Clean Energy Production
Jansi Rani, B., Ravi, G., Yuvakkumar, R., Saravanakumar, B., Thambidurai, M., Dang, C., & Velauthapillai, D. (2020) · ACS Omega · doi:10.1021/acsomega.0c01476 · Cited by 64
Inocêncio, C. V. M., Holade, Y., Morais, C., Kokoh, K. B., & Napporn, T. W. (2023) · Electrochemical Science Advances · doi:10.1002/elsa.202100206 · Cited by 57
Metadata
- Authors
- Gerken, J. B., McAlpin, J. G., Chen, J. Y. C., Rigsby, M. L., Casey, W. H., Britt, R. D., & Stahl, S. S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2011-08-19
- Volume
- 133
- Issue
- 36
- Pages
- 14431-14442
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1985778735
- Cited by
- 814
- References
- 2
- FWCI
- 18.39
- Type
- journal article
- Language
- en
- Open access
- hybrid
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
