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Defining Rules for the Shape Evolution of Gold Nanoparticles
Abstract
The roles of silver ions and halides (chloride, bromide, and iodide) in the seed-mediated synthesis of gold nanostructures have been investigated, and their influence on the growth of 10 classes of nanoparticles that differ in shape has been determined. We systematically studied the effects that each chemical component has on the particle shape, on the rate of particle formation, and on the chemical composition of the particle surface. We demonstrate that halides can be used to (1) adjust the reduction potential of the gold ion species in solution and (2) passivate the gold nanoparticle surface, both of which control the reaction kinetics and thus enable the selective synthesis of a series of different particle shapes. We also show that silver ions can be used as an underpotential deposition agent to access a different set of particle shapes by controlling growth of the resulting gold nanoparticles through surface passivation (more so than kinetic effects). Importantly, we show that the density of silver coverage can be controlled by the amount and type of halide present in solution. This behavior arises from the decreasing stability of the underpotentially deposited silver layer in the presence of larger halides due to the relative strengths of the Ag(+)/Ag(0)-halide and Au(+)/Au(0)-halide interactions, as well as the passivation effects of the halides on the gold particle surface. We summarize this work by proposing a set of design considerations for controlling the growth and final shape of gold nanoparticles prepared by seed-mediated syntheses through the judicious use of halides and silver ions.
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Cites
Shape‐Controlled Synthesis of Metal Nanocrystals: Simple Chemistry Meets Complex Physics?
Xia, Y., Xiong, Y., Lim, B., & Skrabalak, S. E. (2009) · Angewandte Chemie International Edition · doi:10.1002/anie.200802248 · Cited by 5,702
Preparation and Growth Mechanism of Gold Nanorods (NRs) Using Seed-Mediated Growth Method
Nikoobakht, B., & El-Sayed, M. A. (2003) · Chemistry of Materials · doi:10.1021/cm020732l · Cited by 5,069
Photoinduced Conversion of Silver Nanospheres to Nanoprisms
Jin, R., Cao, Y., Mirkin, C. A., Kelly, K. L., Schatz, G. C., & Zheng, J. G. (2001) · Science · doi:10.1126/science.1066541 · Cited by 3,384
Self-citationAnisotropic Metal Nanoparticles: Synthesis, Assembly, and Optical Applications
Murphy, C. J., Sau, T. K., Gole, A. M., Orendorff, C. J., Gao, J., Gou, L., Hunyadi, S. E., & Li, T. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp0516846 · Cited by 3,085
Tian, N., Zhou, Z.-Y., Sun, S.-G., Ding, Y., & Wang, Z. L. (2007) · Science · doi:10.1126/science.1140484 · Cited by 3,073
Shape Control of Colloidal Metal Nanocrystals
Tao, A. R., Habas, S., & Yang, P. (2008) · Small · doi:10.1002/smll.200701295 · Cited by 2,408
Gold Nanoparticles for Biology and Medicine
Giljohann, D. A., Seferos, D. S., Daniel, W. L., Massich, M. D., Patel, P. C., & Mirkin, C. A. (2010) · Angewandte Chemie International Edition · doi:10.1002/anie.200904359 · Cited by 2,356
Self-citationStandard Potentials in Aqueous Solution
Bard, A. J., Parsons, R., & Jordan, J. (2017) · Routledge eBooks · doi:10.1201/9780203738764 · Cited by 2,311
Transmission Electron Microscopy of Shape-Controlled Nanocrystals and Their Assemblies
Wang, Z. L. (2000) · The Journal of Physical Chemistry B · doi:10.1021/jp993593c · Cited by 2,137
Shape control in gold nanoparticle synthesis
Grzelczak, M., Pérez-Juste, J., Mulvaney, P., & Liz-Marzán, L. M. (2008) · Chemical Society Reviews · doi:10.1039/b711490g · Cited by 1,911
Jana, N. R., Gearheart, L., & Murphy, C. J. (2001) · Advanced Materials · doi:10.1002/1521-4095(200109)13:18<1389::aid-adma1389>3.0.co;2-f · Cited by 1,784
Controlling anisotropic nanoparticle growth through plasmon excitation
Jin, R., Charles Cao, Y., Hao, E., Métraux, G. S., Schatz, G. C., & Mirkin, C. A. (2003) · Nature · doi:10.1038/nature02020 · Cited by 1,674
Self-citationRoom Temperature, High-Yield Synthesis of Multiple Shapes of Gold Nanoparticles in Aqueous Solution
Sau, T. K., & Murphy, C. J. (2004) · Journal of the American Chemical Society · doi:10.1021/ja047846d · Cited by 1,583
種結晶を媒介とした成長法を用いた金ナノロッド(NR)の調製と成長メカニズム
Nikoobakht, B., & El-Sayed, M. A. (2003) · Chemistry of Materials · Cited by 1,419
Optical Properties of Star-Shaped Gold Nanoparticles
Nehl, C. L., Liao, H., & Hafner, J. H. (2006) · Nano Letters · doi:10.1021/nl052409y · Cited by 1,162
Templated Techniques for the Synthesis and Assembly of Plasmonic Nanostructures
Jones, M. R., Osberg, K. D., Macfarlane, R. J., Langille, M. R., & Mirkin, C. A. (2011) · Chemical Reviews · doi:10.1021/cr1004452 · Cited by 1,159
Self-citationMechanism of Silver(I)-Assisted Growth of Gold Nanorods and Bipyramids
Liu, M., & Guyot-Sionnest, P. (2005) · The Journal of Physical Chemistry B · doi:10.1021/jp054808n · Cited by 1,004
Underpotential Deposition at Single Crystal Surfaces of Au, Pt, Ag and Other Materials
Herrero, E., Buller, L. J., & Abruña, H. D. (2001) · Chemical Reviews · doi:10.1021/cr9600363 · Cited by 934
Colloidal Gold and Silver Triangular Nanoprisms
Millstone, J. E., Hurst, S. J., Métraux, G. S., Cutler, J. I., & Mirkin, C. A. (2009) · Small · doi:10.1002/smll.200801480 · Cited by 895
Self-citationNanomaterials of high surface energy with exceptional properties in catalysis and energy storage
Zhou, Z.-Y., Tian, N., Li, J.-T., Broadwell, I., & Sun, S.-G. (2011) · Chemical Society Reviews · doi:10.1039/c0cs00176g · Cited by 884
Catalysis Based on Nanocrystals with Well‐Defined Facets
Zhou, K., & Li, Y. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201102619 · Cited by 826
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Millstone, J. E., Park, S., Shuford, K. L., Qin, L., Schatz, G. C., & Mirkin, C. A. (2005) · Journal of the American Chemical Society · doi:10.1021/ja043245a · Cited by 756
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Magnussen, O. M. (2002) · Chemical Reviews · doi:10.1021/cr000069p · Cited by 755
High-yield synthesis and optical response of gold nanostars
Senthil Kumar, P., Pastoriza-Santos, I., Rodríguez-González, B., Javier García de Abajo, F., & Liz-Marzán, L. M. (2008) · Nanotechnology · doi:10.1088/0957-4484/19/01/015606 · Cited by 751
Electric‐Field‐Directed Growth of Gold Nanorods in Aqueous Surfactant Solutions
Pérez‐Juste, J., Liz‐Marzán, L. M., Carnie, S., Chan, D. Y. C., & Mulvaney, P. (2004) · Advanced Functional Materials · doi:10.1002/adfm.200305068 · Cited by 575
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Washio, I., Xiong, Y., Yin, Y., & Xia, Y. (2006) · Advanced Materials · doi:10.1002/adma.200600675 · Cited by 520
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Yu, T., Kim, D. Y., Zhang, H., & Xia, Y. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201007859 · Cited by 454
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Niu, W., Zheng, S., Wang, D., Liu, X., Li, H., Han, S., Chen, J., Tang, Z., & Xu, G. (2009) · Journal of the American Chemical Society · doi:10.1021/ja804115r · Cited by 358
Ma, Y., Kuang, Q., Jiang, Z., Xie, Z., Huang, R., & Zheng, L. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200802750 · Cited by 336
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Metadata
- Authors
- Langille, M. R., Personick, M. L., Zhang, J., & Mirkin, C. A.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2012-08-24
- Volume
- 134
- Issue
- 35
- Pages
- 14542-14554
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2145059166
- Cited by
- 707
- References
- 72
- FWCI
- 23.19
- Type
- journal article
- Language
- en
- Open access
- closed
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