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Cited by 531

The DOI matches its Crossref record; 34 of the 34 references it cites were found in a registry or an index.

Tunable Rare-Earth fcu-MOFs: A Platform for Systematic Enhancement of CO2 Adsorption Energetics and Uptake

Xue, Dong-Xu, Cairns, Amy J., Belmabkhout, Youssef, Wojtas, Lukasz, Liu, Yunling, Alkordi, Mohamed H., Eddaoudi, Mohamed·2013·Journal of the American Chemical Society

Abstract

A series of fcu-MOFs based on rare-earth (RE) metals and linear fluorinated/nonfluorinated, homo/heterofunctional ligands were targeted and synthesized. This particular fcu-MOF platform was selected because of its unique structural characteristics combined with the ability/potential to dictate and regulate its chemical properties (e.g., tuning of the electron-rich RE metal ions and high localized charge density, a property arising from the proximal positioning of polarizing tetrazolate moieties and fluoro-groups that decorate the exposed inner surfaces of the confined conical cavities). These features permitted a systematic gas sorption study to evaluate/elucidate the effects of distinctive parameters on CO2-MOF sorption energetics. Our study supports the importance of the synergistic effect of exposed open metal sites and proximal highly localized charge density toward materials with enhanced CO2 sorption energetics.

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Crossref · 10.1021/ja401429x

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Metadata

Authors
Xue, D.-X., Cairns, A. J., Belmabkhout, Y., Wojtas, L., Liu, Y., Alkordi, M. H., & Eddaoudi, M.
Venue
Journal of the American Chemical Society
Published
2013-05-07
Volume
135
Issue
20
Pages
7660-7667
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2318655974
Cited by
531
References
34
FWCI
26.24
Type
journal article
Language
en
Open access
closed

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