The DOI matches its Crossref record; 6 of the 6 references it cites were found in a registry or an index.
Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene–Isoquinoline Complex
Abstract
The solar-driven reduction of carbon dioxide to value-added chemical fuels is a longstanding challenge in the fields of catalysis, energy science, and green chemistry. In order to develop effective CO2 fixation, several key considerations must be balanced, including (1) catalyst selectivity for promoting CO2 reduction over competing hydrogen generation from proton reduction, (2) visible-light harvesting that matches the solar spectrum, and (3) the use of cheap and earth-abundant catalytic components. In this report, we present the synthesis and characterization of a new family of earth-abundant nickel complexes supported by N-heterocyclic carbene-amine ligands that exhibit high selectivity and activity for the electrocatalytic and photocatalytic conversion of CO2 to CO. Systematic changes in the carbene and amine donors of the ligand have been surveyed, and [Ni((Pr)bimiq1)](2+) (1c, where (Pr)bimiq1 = bis(3-(imidazolyl)isoquinolinyl)propane) emerges as a catalyst for electrochemical reduction of CO2 with the lowest cathodic onset potential (E(cat) = -1.2 V vs SCE). Using this earth-abundant catalyst with Ir(ppy)3 (where ppy = 2-phenylpyridine) and an electron donor, we have developed a visible-light photoredox system for the catalytic conversion of CO2 to CO that proceeds with high selectivity and activity and achieves turnover numbers and turnover frequencies reaching 98,000 and 3.9 s(-1), respectively. Further studies reveal that the overall efficiency of this solar-to-fuel cycle may be limited by the formation of the active Ni catalyst and/or the chemical reduction of CO2 to CO at the reduced nickel center and provide a starting point for improved photoredox systems for sustainable carbon-neutral energy conversion.
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Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Li, C. W., & Kanan, M. W. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3010978 · Cited by 2,000
Nitrogen-Based Catalysts for the Electrochemical Reduction of CO 2 to CO
Tornow, C. E., Thorson, M. R., Ma, S., Gewirth, A. A., & Kenis, P. J. A. (2012) · Journal of the American Chemical Society · doi:10.1021/ja308217w · Cited by 190
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Electro- and Solar-Driven Fuel Synthesis with First Row Transition Metal Complexes
Dalle, K. E., Warnan, J., Leung, J. J., Reuillard, B., Karmel, I. S., & Reisner, E. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00392 · Cited by 912
Gao, S., Gu, B., Jiao, X., Sun, Y., Zu, X., Yang, F., Zhu, W., Wang, C., Feng, Z., Ye, B., et al. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11263 · Cited by 641
Sacrificial electron donor reagents for solar fuel production
Pellegrin, Y., & Odobel, F. (2016) · Comptes Rendus. Chimie · doi:10.1016/j.crci.2015.11.026 · Cited by 561
Yaashikaa, P. R., Senthil Kumar, P., Varjani, S. J., & Saravanan, A. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.05.017 · Cited by 508
Li, J., Wu, X., Pan, W., Zhang, G., & Chen, H. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201708709 · Cited by 478
Boutin, E., Merakeb, L., Ma, B., Boudy, B., Wang, M., Bonin, J., Anxolabéhère-Mallart, E., & Robert, M. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00218f · Cited by 423
Chen, L., Guo, Z., Wei, X.-G., Gallenkamp, C., Bonin, J., Anxolabéhère-Mallart, E., Lau, K.-C., Lau, T.-C., & Robert, M. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b06535 · Cited by 359
Current technology development for CO2 utilization into solar fuels and chemicals: A review
Mustafa, A., Lougou, B. G., Shuai, Y., Wang, Z., & Tan, H. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.01.023 · Cited by 336
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Kuramochi, Y., Ishitani, O., & Ishida, H. (2018) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2017.11.023 · Cited by 325
Wang, H., Chen, Y., Hou, X., Ma, C., & Tan, T. (2016) · Green Chemistry · doi:10.1039/c6gc00410e · Cited by 288
Wang, J.-W., Jiang, L., Huang, H.-H., Han, Z., & Ouyang, G. (2021) · Nature Communications · doi:10.1038/s41467-021-24647-y · Cited by 164
Metadata
- Authors
- Thoi, V. S., Kornienko, N., Margarit, C. G., Yang, P., & Chang, C. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2013-09-13
- Volume
- 135
- Issue
- 38
- Pages
- 14413-14424
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2051746169
- Cited by
- 376
- References
- 6
- FWCI
- 8.66
- Type
- journal article
- Language
- en
- Open access
- closed
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