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Cited by 1,159

The DOI matches its Crossref record; 272 of the 272 references it cites were found in a registry or an index.

Macromolecular Engineering by Atom Transfer Radical Polymerization

Matyjaszewski, Krzysztof, Tsarevsky, Nicolay V.·2014·Journal of the American Chemical Society

Abstract

This Perspective presents recent advances in macromolecular engineering enabled by ATRP. They include the fundamental mechanistic and synthetic features of ATRP with emphasis on various catalytic/initiation systems that use parts-per-million concentrations of Cu catalysts and can be run in environmentally friendly media, e.g., water. The roles of the major components of ATRP--monomers, initiators, catalysts, and various additives--are explained, and their reactivity and structure are correlated. The effects of media and external stimuli on polymerization rates and control are presented. Some examples of precisely controlled elements of macromolecular architecture, such as chain uniformity, composition, topology, and functionality, are discussed. Syntheses of polymers with complex architecture, various hybrids, and bioconjugates are illustrated. Examples of current and forthcoming applications of ATRP are covered. Future challenges and perspectives for macromolecular engineering by ATRP are discussed.

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Metadata

Authors
Matyjaszewski, K., & Tsarevsky, N. V.
Venue
Journal of the American Chemical Society
Published
2014-04-23
Volume
136
Issue
18
Pages
6513-6533
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W1965006117
Cited by
1,159
References
272
FWCI
66.63
Type
journal article
Language
en
Open access
closed

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Bibliographic data: Semantic Scholar, OpenAlex, Crossref.

Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.