The DOI matches its Crossref record; 4 of the 4 references it cites were found in a registry or an index.
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
Abstract
High surface area tin oxide nanocrystals prepared by a facile hydrothermal method are evaluated as electrocatalysts toward CO2 reduction to formate. At these novel nanostructured tin catalysts, CO2 reduction occurs selectively to formate at overpotentials as low as ∼340 mV. In aqueous NaHCO3 solutions, maximum Faradaic efficiencies for formate production of >93% have been reached with high stability and current densities of >10 mA/cm(2) on graphene supports. The notable reactivity toward CO2 reduction achieved here may arise from a compromise between the strength of the interaction between CO2(•-) and the nanoscale tin surface and subsequent kinetic activation toward protonation and further reduction.
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Cites
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces
Kuhl, K. P., Cave, E. R., Abram, D. N., & Jaramillo, T. F. (2012) · Energy & Environmental Science · doi:10.1039/c2ee21234j · Cited by 3,160
Hori, Y., Wakebe, H., Tsukamoto, T., & Koga, O. (1994) · Electrochimica Acta · doi:10.1016/0013-4686(94)85172-7 · Cited by 2,140
Ionic Liquid–Mediated Selective Conversion of CO 2 to CO at Low Overpotentials
Rosen, B. A., Salehi-Khojin, A., Thorson, M. R., Zhu, W., Whipple, D. T., Kenis, P. J. A., & Masel, R. I. (2011) · Science · doi:10.1126/science.1209786 · Cited by 1,558
Zhang, J., Vukmirovic, M. B., Xu, Y., Mavrikakis, M., & Adzic, R. R. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200462335 · Cited by 1,106
Cited by
Partially oxidized atomic cobalt layers for carbon dioxide electroreduction to liquid fuel
Gao, S., Lin, Y., Jiao, X., Sun, Y., Luo, Q., Zhang, W., Li, D., Yang, J., & Xie, Y. (2016) · Nature · doi:10.1038/nature16455 · Cited by 1,865
General Techno-Economic Analysis of CO 2 Electrolysis Systems
Jouny, M., Luc, W., & Jiao, F. (2018) · Industrial & Engineering Chemistry Research · doi:10.1021/acs.iecr.7b03514 · Cited by 1,628
Recent Advances in Inorganic Heterogeneous Electrocatalysts for Reduction of Carbon Dioxide
Zhu, D. D., Liu, J. L., & Qiao, S. Z. (2016) · Advanced Materials · doi:10.1002/adma.201504766 · Cited by 1,594
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Fundamentals and challenges of electrochemical CO2 reduction using two-dimensional materials
Sun, Z., Ma, T., Tao, H., Fan, Q., & Han, B. (2017) · Chem · doi:10.1016/j.chempr.2017.09.009 · Cited by 1,224
Metadata
- Authors
- Zhang, S., Kang, P., & Meyer, T. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-21
- Volume
- 136
- Issue
- 5
- Pages
- 1734-1737
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2312983667
- Cited by
- 1,151
- References
- 4
- FWCI
- 26.31
- Type
- journal article
- Language
- en
- Open access
- closed
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