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Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
Abstract
High surface area tin oxide nanocrystals prepared by a facile hydrothermal method are evaluated as electrocatalysts toward CO2 reduction to formate. At these novel nanostructured tin catalysts, CO2 reduction occurs selectively to formate at overpotentials as low as ∼340 mV. In aqueous NaHCO3 solutions, maximum Faradaic efficiencies for formate production of >93% have been reached with high stability and current densities of >10 mA/cm(2) on graphene supports. The notable reactivity toward CO2 reduction achieved here may arise from a compromise between the strength of the interaction between CO2(•-) and the nanoscale tin surface and subsequent kinetic activation toward protonation and further reduction.
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Metadata
- Authors
- Zhang, S., Kang, P., & Meyer, T. J.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-01-21
- Volume
- 136
- Issue
- 5
- Pages
- 1734-1737
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2312983667
- Cited by
- 1,151
- References
- 4
- FWCI
- 26.31
- Type
- journal article
- Language
- en
- Open access
- closed
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