The DOI matches its Crossref record; 55 of the 55 references it cites were found in a registry or an index.
Manganese Catalysts with Bulky Bipyridine Ligands for the Electrocatalytic Reduction of Carbon Dioxide: Eliminating Dimerization and Altering Catalysis
Abstract
With the goal of improving previously reported Mn bipyridine electrocatalysts in terms of increased activity and reduced overpotential, a bulky bipyridine ligand, 6,6'-dimesityl-2,2'-bipyridine (mesbpy), was utilized to eliminate dimerization in the catalytic cycle. Synthesis, electrocatalytic properties, X-ray diffraction (XRD) studies, and infrared spectroelectrochemistry (IR-SEC) of Mn(mesbpy)(CO)3Br and [Mn(mesbpy)(CO)3(MeCN)](OTf) are reported. Unlike previously reported Mn bipyridine catalysts, these Mn complexes exhibit a single, two-electron reduction wave under nitrogen, with no evidence of dimerization. The anionic complex, [Mn(mesbpy)(CO)3](-), is formed at 300 mV more positive potential than the corresponding state is formed in typical Mn bipyridine catalysts. IR-SEC experiments and chemical reductions with KC8 provide insights into the species leading up to the anionic state, specifically that both the singly reduced and doubly reduced Mn complexes form at the same potential. When formed, the anionic complex binds CO2 with H(+), but catalytic activity does not occur until a ~400 mV more negative potential is present. The Mn complexes show high activity and Faradaic efficiency for CO2 reduction to CO with the addition of weak Brønsted acids. IR-SEC experiments under CO2/H(+) indicate that reduction of a Mn(I)-CO2H catalytic intermediate may be the cause of this unusual "over-reduction" required to initiate catalysis.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Sheldrick, G. M. (2008) · Acta Crystallographica Section A Foundations of Crystallography · doi:10.1107/s0108767307043930 · Cited by 87,804
CRC Handbook of Chemistry and Physics
(2014) · doi:10.1201/b17118 · Cited by 57,706
Density-functional exchange-energy approximation with correct asymptotic behavior
Becke, A. D. (1988) · Physical Review A · doi:10.1103/physreva.38.3098 · Cited by 53,711
Vosko, S. H., Wilk, L., & Nusair, M. (1980) · Canadian Journal of Physics · doi:10.1139/p80-159 · Cited by 20,768
Density-functional approximation for the correlation energy of the inhomogeneous electron gas
Perdew, J. P. (1986) · Physical Review B · doi:10.1103/physrevb.33.8822 · Cited by 18,777
CRC Handbook of Chemistry and Physics
(2016) · CRC Press eBooks · doi:10.1201/9781315380476 · Cited by 13,921
te Velde, G., Bickelhaupt, F. M., Baerends, E. J., Fonseca Guerra, C., van Gisbergen, S. J. A., Snijders, J. G., & Ziegler, T. (2001) · Journal of Computational Chemistry · doi:10.1002/jcc.1056 · Cited by 10,152
Addison, A. W., Rao, T. N., Reedijk, J., van Rijn, J., & Verschoor, G. C. (1984) · J. Chem. Soc., Dalton Trans. · doi:10.1039/dt9840001349 · Cited by 9,445
Relativistic regular two-component Hamiltonians
Lenthe, E. V., Baerends, E. J., & Snijders, J. G. (1993) · The Journal of Chemical Physics · doi:10.1063/1.466059 · Cited by 4,385
(1981) · Handbook of Exploration Geochemistry · doi:10.1016/b978-0-444-41930-9.50014-3 · Cited by 2,896
Equilibrium acidities in dimethyl sulfoxide solution
Bordwell, F. G. (1988) · Accounts of Chemical Research · doi:10.1021/ar00156a004 · Cited by 2,874
Perdew, J. P. (1986) · Physical Review B · doi:10.1103/physrevb.34.7406 · Cited by 2,785
Towards an order- N DFT method
Fonseca Guerra, C., Snijders, J. G., te Velde, G., & Baerends, E. J. (1998) · Theoretical Chemistry Accounts: Theory, Computation, and Modeling (Theoretica Chimica Acta) · doi:10.1007/s002140050353 · Cited by 2,742
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Electrocatalytic and homogeneous approaches to conversion of CO2to liquid fuels
Benson, E. E., Kubiak, C. P., Sathrum, A. J., & Smieja, J. M. (2009) · Chem. Soc. Rev. · doi:10.1039/b804323j · Cited by 2,059
Self-citationvan Lenthe, E., Snijders, J. G., & Baerends, E. J. (1996) · The Journal of Chemical Physics · doi:10.1063/1.472460 · Cited by 1,754
Franke, R., Selent, D., & Börner, A. (2012) · Chemical Reviews · doi:10.1021/cr3001803 · Cited by 1,668
Catalysis of the electrochemical reduction of carbon dioxide
Costentin, C., Robert, M., & Savéant, J.-M. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35360a · Cited by 1,658
Short history and present trends of Fischer–Tropsch synthesis
Schulz, H. (1999) · Applied Catalysis A: General · doi:10.1016/s0926-860x(99)00160-x · Cited by 1,389
A Local Proton Source Enhances CO 2 Electroreduction to CO by a Molecular Fe Catalyst
Costentin, C., Drouet, S., Robert, M., & Savéant, J.-M. (2012) · Science · doi:10.1126/science.1224581 · Cited by 1,315
Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar Fuels
Morris, A. J., Meyer, G. J., & Fujita, E. (2009) · Accounts of Chemical Research · doi:10.1021/ar9001679 · Cited by 1,282
Wang, J. (2006) · Wiley eBooks · doi:10.1002/0471790303 · Cited by 847
Hawecker, J., Lehn, J.-M., & Ziessel, R. (1983) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39830000536 · Cited by 710
Hawecker, J., Lehn, J., & Ziessel, R. (1986) · Helvetica Chimica Acta · doi:10.1002/hlca.19860690824 · Cited by 688
Hydroformylation of alkenes by use of rhodium complex catalysts
Evans, D., Osborn, J. A., & Wilkinson, G. (1968) · Journal of the Chemical Society A: Inorganic, Physical, Theoretical · doi:10.1039/j19680003133 · Cited by 683
Electrocatalytic reduction of carbon dioxide mediated by Re(bipy)(CO)3Cl (bipy = 2,2′-bipyridine)
Hawecker, J., Lehn, J.-M., & Ziessel, R. (1984) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39840000328 · Cited by 601
Bourrez, M., Molton, F., Chardon‐Noblat, S., & Deronzier, A. (2011) · Angewandte Chemie International Edition · doi:10.1002/anie.201103616 · Cited by 590
Smieja, J. M., & Kubiak, C. P. (2010) · Inorganic Chemistry · doi:10.1021/ic1008363 · Cited by 535
Self-citationAdvances in molecular photocatalytic and electrocatalytic CO2 reduction
Windle, C. D., & Perutz, R. N. (2012) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2012.03.010 · Cited by 481
Chemical kinetics and reaction mechanisms
Smith, J. (1982) · The Chemical Engineering Journal · doi:10.1016/0300-9467(82)85032-6 · Cited by 429
Acidities of water and simple alcohols in dimethyl sulfoxide solution
Olmstead, W. N., Margolin, Z., & BORDWELL, F. G. (1980) · The Journal of Organic Chemistry · doi:10.1021/jo01304a032 · Cited by 417
Chemical approaches to artificial photosynthesis
Concepcion, J. J., House, R. L., Papanikolas, J. M., & Meyer, T. J. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1212254109 · Cited by 409
Manganese as a Substitute for Rhenium in CO2 Reduction Catalysts: The Importance of Acids
Smieja, J. M., Sampson, M. D., Grice, K. A., Benson, E. E., Froehlich, J. D., & Kubiak, C. P. (2013) · Inorganic Chemistry · doi:10.1021/ic302391u · Cited by 402
Self-citationSullivan, B. P., Bolinger, C. M., Conrad, D., Vining, W. J., & Meyer, T. J. (1985) · J. Chem. Soc., Chem. Commun. · doi:10.1039/c39850001414 · Cited by 397
Methanol synthesis: a short review of technology improvements
Lange, J.-P. (2001) · Catalysis Today · doi:10.1016/s0920-5861(00)00503-4 · Cited by 356
Johnson, F. P. A., George, M. W., Hartl, F., & Turner, J. J. (1996) · Organometallics · doi:10.1021/om960044+ · Cited by 337
Homogeneous CO2 Reduction by Ni(cyclam) at a Glassy Carbon Electrode
Froehlich, J. D., & Kubiak, C. P. (2012) · Inorganic Chemistry · doi:10.1021/ic3001619 · Cited by 310
Self-citationKeith, J. A., Grice, K. A., Kubiak, C. P., & Carter, E. A. (2013) · Journal of the American Chemical Society · doi:10.1021/ja406456g · Cited by 274
Self-citationLigand Variations in [ReX(diimine)(CO)3] Complexes: Effects on Photocatalytic CO2 Reduction
Kurz, P., Probst, B., Spingler, B., & Alberto, R. (2006) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.200600166 · Cited by 258
Smieja, J. M., Benson, E. E., Kumar, B., Grice, K. A., Seu, C. S., Miller, A. J. M., Mayer, J. M., & Kubiak, C. P. (2012) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.1119863109 · Cited by 208
Self-citationSolubility and electrochemical determination of CO2 in some dipolar aprotic solvents
Gennaro, A., Isse, A. A., & Vianello, E. (1990) · Journal of Electroanalytical Chemistry and Interfacial Electrochemistry · doi:10.1016/0022-0728(90)87217-8 · Cited by 200
Kumar, B., Smieja, J. M., & Kubiak, C. P. (2010) · The Journal of Physical Chemistry C · doi:10.1021/jp105171b · Cited by 181
Self-citationNew and revisited insights into the promotion of methanol synthesis catalysts by CO2
Martin, O., & Pérez-Ramírez, J. (2013) · Catalysis Science & Technology · doi:10.1039/c3cy00573a · Cited by 176
Scarborough, C. C., Sproules, S., Weyhermüller, T., DeBeer, S., & Wieghardt, K. (2011) · Inorganic Chemistry · doi:10.1021/ic201123x · Cited by 163
Fujita, E., Creutz, C., Sutin, N., & Szalda, D. J. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00001a048 · Cited by 162
Benson, E. E., & Kubiak, C. P. (2012) · Chemical Communications · doi:10.1039/c2cc32617e · Cited by 162
Self-citationDirect observation of the reduction of carbon dioxide by rhenium bipyridine catalysts
Sampson, M. D., Froehlich, J. D., Smieja, J. M., Benson, E. E., Sharp, I. D., & Kubiak, C. P. (2013) · Energy & Environmental Science · doi:10.1039/c3ee42186d · Cited by 157
Self-citationBourrez, M., Orio, M., Molton, F., Vezin, H., Duboc, C., Deronzier, A., & Chardon‐Noblat, S. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201306750 · Cited by 142
Benson, E. E., Sampson, M. D., Grice, K. A., Smieja, J. M., Froehlich, J. D., Friebel, D., Keith, J. A., Carter, E. A., Nilsson, A., & Kubiak, C. P. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201209911 · Cited by 142
Self-citationWong, K., Chung, W.-H., & Lau, C. P. (1998) · Journal of Electroanalytical Chemistry · doi:10.1016/s0022-0728(98)00116-8 · Cited by 114
Kumar, B., Smieja, J. M., Sasayama, A. F., & Kubiak, C. P. (2011) · Chemical Communications · doi:10.1039/c1cc16024a · Cited by 108
Self-citationCosnier, S., Deronzier, A., & Moutet, J. (1988) · Journal of Molecular Catalysis · doi:10.1016/0304-5102(88)80070-1 · Cited by 85
Grice, K. A., Gu, N. X., Sampson, M. D., & Kubiak, C. P. (2013) · Dalton Transactions · doi:10.1039/c3dt50612f · Cited by 70
Self-citationMethanol synthesis on ZnO from molecular dynamics
Frenzel, J., Kiss, J. T., Nair, N. N., Meyer, B., & Marx, D. (2013) · physica status solidi (b) · doi:10.1002/pssb.201248446 · Cited by 17
Fischer-Tropsch synthesis catalysts as the core of the strategy for obtaining synthetic liquid fuels
Krylova, A. Y. (2012) · Kinetics and Catalysis · doi:10.1134/s0023158412060067 · Cited by 10
Cited by
A practical beginner’s guide to cyclic voltammetry
Elgrishi, N., Rountree, K. J., McCarthy, B. D., Rountree, E. S., Eisenhart, T. T., & Dempsey, J. L. (2018) · Journal of Chemical Education · doi:10.1021/acs.jchemed.7b00361 · Cited by 4,263
Molecular polypyridine-based metal complexes as catalysts for the reduction of CO2
Elgrishi, N., Chambers, M. B., Wang, X., & Fontecave, M. (2017) · Chemical Society Reviews · doi:10.1039/c5cs00391a · Cited by 555
Selectivity in Electrochemical CO2 Reduction
Saha, P., Amanullah, S., & Dey, A. (2022) · Accounts of Chemical Research · doi:10.1021/acs.accounts.1c00678 · Cited by 528
Yaashikaa, P. R., Senthil Kumar, P., Varjani, S. J., & Saravanan, A. (2019) · Journal of CO2 Utilization · doi:10.1016/j.jcou.2019.05.017 · Cited by 508
Current technology development for CO2 utilization into solar fuels and chemicals: A review
Mustafa, A., Lougou, B. G., Shuai, Y., Wang, Z., & Tan, H. (2020) · Journal of Energy Chemistry · doi:10.1016/j.jechem.2020.01.023 · Cited by 336
Metadata
- Authors
- Sampson, M. D., Nguyen, A. D., Grice, K. A., Moore, C. E., Rheingold, A. L., & Kubiak, C. P.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-03-31
- Volume
- 136
- Issue
- 14
- Pages
- 5460-5471
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2320625878
- Cited by
- 466
- References
- 55
- FWCI
- 13.97
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
