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Exfoliation of Graphite into Graphene in Aqueous Solutions of Inorganic Salts
Open accessAbstract
Mass production of high-quality graphene sheets is essential for their practical application in electronics, optoelectronics, composite materials, and energy-storage devices. Here we report a prompt electrochemical exfoliation of graphene sheets into aqueous solutions of different inorganic salts ((NH4)2SO4, Na2SO4, K2SO4, etc.). Exfoliation in these electrolytes leads to graphene with a high yield (>85%, ≤3 layers), large lateral size (up to 44 μm), low oxidation degree (a C/O ratio of 17.2), and a remarkable hole mobility of 310 cm(2) V(-1) s(-1). Further, highly conductive graphene films (11 Ω sq(-1)) are readily fabricated on an A4-size paper by applying brush painting of a concentrated graphene ink (10 mg mL(-1), in N,N'-dimethylformamide). All-solid-state flexible supercapacitors manufactured on the basis of such graphene films deliver a high area capacitance of 11.3 mF cm(-2) and an excellent rate capability of 5000 mV s(-1). The described electrochemical exfoliation shows great promise for the industrial-scale synthesis of high-quality graphene for numerous advanced applications.
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Cites
Electric Field Effect in Atomically Thin Carbon Films
Novoselov, K. S., Geim, A. K., Morozov, S. V., Jiang, D., Zhang, Y., Dubonos, S. V., Grigorieva, I. V., & Firsov, A. A. (2004) · Science · doi:10.1126/science.1102896 · Cited by 66,834
Geim, A. K., & Novoselov, K. S. (2007) · Nature Materials · doi:10.1038/nmat1849 · Cited by 39,979
Raman Spectrum of Graphene and Graphene Layers
Ferrari, A. C., Meyer, J. C., Scardaci, V., Casiraghi, C., Lazzeri, M., Mauri, F., Piscanec, S., Jiang, D., Novoselov, K. S., Roth, S., et al. (2006) · Physical Review Letters · doi:10.1103/physrevlett.97.187401 · Cited by 15,047
Roll-to-roll production of 30-inch graphene films for transparent electrodes
Bae, S., Kim, H., Lee, Y., Xu, X., Park, J.-S., Zheng, Y., Balakrishnan, J., Lei, T., Ri Kim, H., Song, Y. I., et al. (2010) · Nature Nanotechnology · doi:10.1038/nnano.2010.132 · Cited by 8,136
Chemical methods for the production of graphenes
Park, S., & Ruoff, R. S. (2009) · Nature Nanotechnology · doi:10.1038/nnano.2009.58 · Cited by 6,663
High-yield production of graphene by liquid-phase exfoliation of graphite
Hernandez, Y., Nicolosi, V., Lotya, M., Blighe, F. M., Sun, Z., De, S., McGovern, I. T., Holland, B., Byrne, M., Gun'Ko, Y. K., et al. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.215 · Cited by 6,285
Raman spectroscopy in graphene
Malard, L. M., Pimenta, M. A., Dresselhaus, G., & Dresselhaus, M. S. (2009) · Physics Reports · doi:10.1016/j.physrep.2009.02.003 · Cited by 6,059
Eda, G., Fanchini, G., & Chhowalla, M. (2008) · Nature Nanotechnology · doi:10.1038/nnano.2008.83 · Cited by 4,379
Epitaxial graphene on ruthenium
Sutter, P. W., Flege, J.-I., & Sutter, E. A. (2008) · Nature Materials · doi:10.1038/nmat2166 · Cited by 2,346
Reduced graphene oxide by chemical graphitization
Moon, I. K., Lee, J., Ruoff, R. S., & Lee, H. (2010) · Nature Communications · doi:10.1038/ncomms1067 · Cited by 2,135
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Flexible and Stretchable Energy Storage: Recent Advances and Future Perspectives
Liu, W., Song, M., Kong, B., & Cui, Y. (2017) · Advanced Materials · doi:10.1002/adma.201603436 · Cited by 1,202
High-quality graphene via microwave reduction of solution-exfoliated graphene oxide
Voiry, D., Yang, J., Kupferberg, J., Fullon, R., Lee, C., Jeong, H. Y., Shin, H. S., & Chhowalla, M. (2016) · Science · doi:10.1126/science.aah3398 · Cited by 872
Hou, Y., Lohe, M. R., Zhang, J., Liu, S., Zhuang, X., & Feng, X. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03440j · Cited by 824
Self-citationInterface-Assisted Synthesis of 2D Materials: Trend and Challenges
Dong, R., Zhang, T., & Feng, X. (2018) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00056 · Cited by 710
Self-citationGraphene based metal and metal oxide nanocomposites: synthesis, properties and their applications
Khan, M., Tahir, M. N., Adil, S. F., Khan, H. U., Siddiqui, M. R. H., Al-warthan, A. A., & Tremel, W. (2015) · Journal of Materials Chemistry A · doi:10.1039/c5ta02240a · Cited by 709
Shen, J., He, Y., Wu, J., Gao, C., Keyshar, K., Zhang, X., Yang, Y., Ye, M., Vajtai, R., Lou, J., et al. (2015) · Nano Letters · doi:10.1021/acs.nanolett.5b01842 · Cited by 578
Kumar, R., Sahoo, S., Joanni, E., Singh, R. K., Tan, W. K., Kar, K. K., & Matsuda, A. (2019) · Progress in Energy and Combustion Science · doi:10.1016/j.pecs.2019.100786 · Cited by 554
3D Graphene Materials: From Understanding to Design and Synthesis Control
Sun, Z., Fang, S., & Hu, Y. H. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.0c00083 · Cited by 543
Li, H., Hou, Y., Wang, F., Lohe, M. R., Zhuang, X., Niu, L., & Feng, X. (2017) · Advanced Energy Materials · doi:10.1002/aenm.201601847 · Cited by 512
Self-citationRecent Progress in Graphene/Polymer Nanocomposites
Sun, X., Huang, C., Wang, L., Liang, L., Cheng, Y., Fei, W., & Li, Y. (2021) · Advanced Materials · doi:10.1002/adma.202001105 · Cited by 490
Graphene and its electrochemistry – an update
Ambrosi, A., Chua, C. K., Latiff, N. M., Loo, A. H., Wong, C. H. A., Eng, A. Y. S., Bonanni, A., & Pumera, M. (2016) · Chemical Society Reviews · doi:10.1039/c6cs00136j · Cited by 469
Khan, A. H., Ghosh, S., Pradhan, B., Dalui, A., Shrestha, L. K., Acharya, S., & Ariga, K. (2017) · Bulletin of the Chemical Society of Japan · doi:10.1246/bcsj.20170043 · Cited by 432
Synthesis of graphene materials by electrochemical exfoliation: Recent progress and future potential
Liu, F., Wang, C., Sui, X., Riaz, M. A., Xu, M., Wei, L., & Chen, Y. (2019) · Carbon Energy · doi:10.1002/cey2.14 · Cited by 407
Electrochemical Method To Prepare Graphene Quantum Dots and Graphene Oxide Quantum Dots
Ahirwar, S., Mallick, S., & Bahadur, D. (2017) · ACS Omega · doi:10.1021/acsomega.7b01539 · Cited by 375
2D Materials in Flexible Electronics: Recent Advances and Future Prospectives
Katiyar, A. K., Hoang, A. T., Xu, D., Hong, J., Kim, B. J., Ji, S., & Ahn, J.-H. (2024) · Chemical Reviews · doi:10.1021/acs.chemrev.3c00302 · Cited by 363
Electrochemical exfoliation of graphite and production of functional graphene
Yu, P., Lowe, S. E., Simon, G. P., & Zhong, Y. L. (2015) · Current Opinion in Colloid & Interface Science · doi:10.1016/j.cocis.2015.10.007 · Cited by 361
Yang, S., Brüller, S., Wu, Z.-S., Liu, Z., Parvez, K., Dong, R., Richard, F., Samorì, P., Feng, X., & Müllen, K. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09000 · Cited by 344
Self-citationTop-down synthesis of graphene: A comprehensive review
Kumar, N., Salehiyan, R., Chauke, V., Joseph Botlhoko, O., Setshedi, K., Scriba, M., Masukume, M., & Sinha Ray, S. (2021) · FlatChem · doi:10.1016/j.flatc.2021.100224 · Cited by 336
Scalable Fabrication and Integration of Graphene Microsupercapacitors through Full Inkjet Printing
Li, J., Sollami Delekta, S., Zhang, P., Yang, S., Lohe, M. R., Zhuang, X., Feng, X., & Östling, M. (2017) · ACS Nano · doi:10.1021/acsnano.7b03354 · Cited by 334
Self-citationWang, G., Zhang, J., Yang, S., Wang, F., Zhuang, X., Müllen, K., & Feng, X. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201702254 · Cited by 334
Self-citationWu, Z., Parvez, K., Li, S., Yang, S., Liu, Z., Liu, S., Feng, X., & Müllen, K. (2015) · Advanced Materials · doi:10.1002/adma.201501643 · Cited by 326
Self-citationScalable exfoliation and dispersion of two-dimensional materials – an update
Tao, H., Zhang, Y., Gao, Y., Sun, Z., Yan, C., & Texter, J. (2017) · Physical Chemistry Chemical Physics · doi:10.1039/c6cp06813h · Cited by 317
New‐Generation Graphene from Electrochemical Approaches: Production and Applications
Yang, S., Lohe, M. R., Müllen, K., & Feng, X. (2016) · Advanced Materials · doi:10.1002/adma.201505326 · Cited by 313
Self-citationHou, Y., Qiu, M., Nam, G., Kim, M. G., Zhang, T., Liu, K., Zhuang, X., Cho, J., Yuan, C., & Feng, X. (2017) · Nano Letters · doi:10.1021/acs.nanolett.7b01030 · Cited by 284
Self-citationRecent advances on graphene: Synthesis, properties and applications
Zhang, F., Yang, K., Liu, G., Chen, Y., Wang, M., Li, S., & Li, R. (2022) · Composites Part A: Applied Science and Manufacturing · doi:10.1016/j.compositesa.2022.107051 · Cited by 283
Self-citationMohanraj, J., Durgalakshmi, D., Rakkesh, R. A., Balakumar, S., Rajendran, S., & Karimi-Maleh, H. (2020) · Journal of Colloid and Interface Science · doi:10.1016/j.jcis.2020.01.089 · Cited by 282
Ultrathin Printable Graphene Supercapacitors with AC Line‐Filtering Performance
Wu, Z., Liu, Z., Parvez, K., Feng, X., & Müllen, K. (2015) · Advanced Materials · doi:10.1002/adma.201501208 · Cited by 276
Self-citationShi, G., Araby, S., Gibson, C. T., Meng, Q., Zhu, S., & Ma, J. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201706705 · Cited by 267
Layered Intercalation Materials
Zhou, J., Lin, Z., Ren, H., Duan, X., Shakir, I., Huang, Y., & Duan, X. (2021) · Advanced Materials · doi:10.1002/adma.202004557 · Cited by 266
Synthesis of atomically thin sheets by the intercalation-based exfoliation of layered materials
Yang, R., Fan, Y., Mei, L., Shin, H. S., Voiry, D., Lu, Q., Li, J., & Zeng, Z. (2023) · Nature Synthesis · doi:10.1038/s44160-022-00232-z · Cited by 253
Tang, J., Chen, S., Yuan, Y., Cai, X., & Zhou, S. (2015) · Biosensors and Bioelectronics · doi:10.1016/j.bios.2015.04.074 · Cited by 110
Yin, P., Liu, Y., Xiao, L., & Zhang, C. (2021) · Polymers · doi:10.3390/polym13162834 · Cited by 42
Metadata
- Authors
- Parvez, K., Wu, Z.-S., Li, R., Liu, X., Graf, R., Feng, X., & Müllen, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2014-04-09
- Volume
- 136
- Issue
- 16
- Pages
- 6083-6091
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2071955897
- Cited by
- 1,440
- References
- 38
- FWCI
- 50.33
- Type
- journal article
- Language
- en
- Open access
- green
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