The DOI matches its Crossref record; 36 of the 36 references it cites were found in a registry or an index.
Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory
Abstract
An isoreticular series of metal-organic frameworks (MOFs) with the ftw topology based on zirconium oxoclusters and tetracarboxylate linkers with a planar core (NU-1101 through NU-1104) has been synthesized employing a linker expansion approach. In this series, NU-1103 has a pore volume of 2.91 cc g(-1) and a geometrically calculated surface area of 5646 m(2) g(-1), which is the highest value reported to date for a zirconium-based MOF and among the largest that have been reported for any porous material. Successful activation of the MOFs was proven based on the agreement of pore volumes and BET areas obtained from simulated and experimental isotherms. Critical for practical applications, NU-1103 combines for the first time ultrahigh surface area and water stability, where this material retained complete structural integrity after soaking in water. Pressure range selection for the BET calculations on these materials was guided by the four so-called "consistency criteria". The experimental BET area of NU-1103 was 6550 m(2) g(-1). Insights obtained from molecular simulation suggest that, as a consequence of pore-filling contamination, the BET method overestimates the monolayer loading of NU-1103 by ∼16%.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Reticular synthesis and the design of new materials
Yaghi, O. M., O'Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003) · Nature · doi:10.1038/nature01650 · Cited by 9,101
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Park, K. S., Ni, Z., Côté, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., O’Keeffe, M., & Yaghi, O. M. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602439103 · Cited by 7,563
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Hybrid porous solids: past, present, future
Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822
Ultrahigh Porosity in Metal-Organic Frameworks
Furukawa, H., Ko, N., Go, Y. B., Aratani, N., Choi, S. B., Choi, E., Yazaydin, A. Ö., Snurr, R. Q., O’Keeffe, M., Kim, J., et al. (2010) · Science · doi:10.1126/science.1192160 · Cited by 3,904
Self-citationHydrogen Storage in Metal–Organic Frameworks
Suh, M. P., Park, H. J., Prasad, T. K., & Lim, D.-W. (2012) · Chemical Reviews · doi:10.1021/cr200274s · Cited by 3,689
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W. L., Hudson, M. R., & Yaghi, O. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500330a · Cited by 2,888
Cited by
From fundamentals to applications: a toolbox for robust and multifunctional MOF materials
Kirchon, A., Feng, L., Drake, H. F., Joseph, E. A., & Zhou, H.-C. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00688a · Cited by 1,448
Best Practices for the Synthesis, Activation, and Characterization of Metal–Organic Frameworks
Howarth, A. J., Peters, A. W., Vermeulen, N. A., Wang, T. C., Hupp, J. T., & Farha, O. K. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02626 · Cited by 746
Self-citationMetal-organic frameworks: Challenges and opportunities for ion-exchange/sorption applications
Kumar, P., Pournara, A., Kim, K.-H., Bansal, V., Rapti, S., & Manos, M. J. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.01.002 · Cited by 423
Evaluating topologically diverse metal–organic frameworks for cryo-adsorbed hydrogen storage
Gómez-Gualdrón, D. A., Colón, Y. J., Zhang, X., Wang, T. C., Chen, Y.-S., Hupp, J. T., Yildirim, T., Farha, O. K., Zhang, J., & Snurr, R. Q. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02104b · Cited by 332
Self-citationColón, Y. J., Gómez-Gualdrón, D. A., & Snurr, R. Q. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b00848 · Cited by 321
Self-citationNanosizing a Metal–Organic Framework Enzyme Carrier for Accelerating Nerve Agent Hydrolysis
Li, P., Moon, S.-Y., Guelta, M. A., Lin, L., Gómez-Gualdrón, D. A., Snurr, R. Q., Harvey, S. P., Hupp, J. T., & Farha, O. K. (2016) · ACS Nano · doi:10.1021/acsnano.6b04996 · Cited by 266
Self-citation
Metadata
- Authors
- Wang, T. C., Bury, W., Gómez-Gualdrón, D. A., Vermeulen, N. A., Mondloch, J. E., Deria, P., Zhang, K., Moghadam, P. Z., Sarjeant, A. A., Snurr, R. Q., Stoddart, J. F., Hupp, J. T., & Farha, O. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-03-09
- Volume
- 137
- Issue
- 10
- Pages
- 3585-3591
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2090352689
- Cited by
- 425
- References
- 36
- FWCI
- 20.17
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
