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Ultrahigh Surface Area Zirconium MOFs and Insights into the Applicability of the BET Theory
Abstract
An isoreticular series of metal-organic frameworks (MOFs) with the ftw topology based on zirconium oxoclusters and tetracarboxylate linkers with a planar core (NU-1101 through NU-1104) has been synthesized employing a linker expansion approach. In this series, NU-1103 has a pore volume of 2.91 cc g(-1) and a geometrically calculated surface area of 5646 m(2) g(-1), which is the highest value reported to date for a zirconium-based MOF and among the largest that have been reported for any porous material. Successful activation of the MOFs was proven based on the agreement of pore volumes and BET areas obtained from simulated and experimental isotherms. Critical for practical applications, NU-1103 combines for the first time ultrahigh surface area and water stability, where this material retained complete structural integrity after soaking in water. Pressure range selection for the BET calculations on these materials was guided by the four so-called "consistency criteria". The experimental BET area of NU-1103 was 6550 m(2) g(-1). Insights obtained from molecular simulation suggest that, as a consequence of pore-filling contamination, the BET method overestimates the monolayer loading of NU-1103 by ∼16%.
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Citations
Cites
Adsorption of Gases in Multimolecular Layers
Brunauer, S., Emmett, P. H., & Teller, E. (1938) · Journal of the American Chemical Society · doi:10.1021/ja01269a023 · Cited by 28,156
Sing, K. S. W. (1985) · Pure and Applied Chemistry · doi:10.1351/pac198557040603 · Cited by 24,485
The Chemistry and Applications of Metal-Organic Frameworks
Furukawa, H., Cordova, K. E., O’Keeffe, M., & Yaghi, O. M. (2013) · Science · doi:10.1126/science.1230444 · Cited by 16,945
Reticular synthesis and the design of new materials
Yaghi, O. M., O'Keeffe, M., Ockwig, N. W., Chae, H. K., Eddaoudi, M., & Kim, J. (2003) · Nature · doi:10.1038/nature01650 · Cited by 9,101
Exceptional chemical and thermal stability of zeolitic imidazolate frameworks
Park, K. S., Ni, Z., Côté, A. P., Choi, J. Y., Huang, R., Uribe-Romo, F. J., Chae, H. K., O’Keeffe, M., & Yaghi, O. M. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602439103 · Cited by 7,563
A New Zirconium Inorganic Building Brick Forming Metal Organic Frameworks with Exceptional Stability
Cavka, J. H., Jakobsen, S., Olsbye, U., Guillou, N., Lamberti, C., Bordiga, S., & Lillerud, K. P. (2008) · Journal of the American Chemical Society · doi:10.1021/ja8057953 · Cited by 7,336
Hybrid porous solids: past, present, future
Férey, G. (2008) · Chem. Soc. Rev. · doi:10.1039/b618320b · Cited by 5,822
Ultrahigh Porosity in Metal-Organic Frameworks
Furukawa, H., Ko, N., Go, Y. B., Aratani, N., Choi, S. B., Choi, E., Yazaydin, A. Ö., Snurr, R. Q., O’Keeffe, M., Kim, J., et al. (2010) · Science · doi:10.1126/science.1192160 · Cited by 3,904
Self-citationHydrogen Storage in Metal–Organic Frameworks
Suh, M. P., Park, H. J., Prasad, T. K., & Lim, D.-W. (2012) · Chemical Reviews · doi:10.1021/cr200274s · Cited by 3,689
Water Adsorption in Porous Metal–Organic Frameworks and Related Materials
Furukawa, H., Gándara, F., Zhang, Y.-B., Jiang, J., Queen, W. L., Hudson, M. R., & Yaghi, O. M. (2014) · Journal of the American Chemical Society · doi:10.1021/ja500330a · Cited by 2,888
Horike, S., Shimomura, S., & Kitagawa, S. (2009) · Nature Chemistry · doi:10.1038/nchem.444 · Cited by 2,486
The Reticular Chemistry Structure Resource (RCSR) Database of, and Symbols for, Crystal Nets
O’Keeffe, M., Peskov, M. A., Ramsden, S. J., & Yaghi, O. M. (2008) · Accounts of Chemical Research · doi:10.1021/ar800124u · Cited by 2,313
Metal–Organic Framework Materials with Ultrahigh Surface Areas: Is the Sky the Limit?
Farha, O. K., Eryazici, I., Jeong, N. C., Hauser, B. G., Wilmer, C. E., Sarjeant, A. A., Snurr, R. Q., Nguyen, S. T., Yazaydın, A. Ö., & Hupp, J. T. (2012) · Journal of the American Chemical Society · doi:10.1021/ja3055639 · Cited by 1,958
Self-citationFarha, O. K., Özgür Yazaydın, A., Eryazici, I., Malliakas, C. D., Hauser, B. G., Kanatzidis, M. G., Nguyen, S. T., Snurr, R. Q., & Hupp, J. T. (2010) · Nature Chemistry · doi:10.1038/nchem.834 · Cited by 1,741
Self-citationBanerjee, R., Furukawa, H., Britt, D., Knobler, C., O’Keeffe, M., & Yaghi, O. M. (2009) · Journal of the American Chemical Society · doi:10.1021/ja809459e · Cited by 1,443
Rational Design, Synthesis, Purification, and Activation of Metal−Organic Framework Materials
Farha, O. K., & Hupp, J. T. (2010) · Accounts of Chemical Research · doi:10.1021/ar1000617 · Cited by 1,426
Self-citationMechanochemical Synthesis of Chemically Stable Isoreticular Covalent Organic Frameworks
Biswal, B. P., Chandra, S., Kandambeth, S., Lukose, B., Heine, T., & Banerjee, R. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4017842 · Cited by 1,240
Construction of Ultrastable Porphyrin Zr Metal–Organic Frameworks through Linker Elimination
Feng, D., Chung, W.-C., Wei, Z., Gu, Z.-Y., Jiang, H.-L., Chen, Y.-P., Darensbourg, D. J., & Zhou, H.-C. (2013) · Journal of the American Chemical Society · doi:10.1021/ja408084j · Cited by 1,126
Vapor-Phase Metalation by Atomic Layer Deposition in a Metal–Organic Framework
Mondloch, J. E., Bury, W., Fairen-Jimenez, D., Kwon, S., DeMarco, E. J., Weston, M. H., Sarjeant, A. A., Nguyen, S. T., Stair, P. C., Snurr, R. Q., et al. (2013) · Journal of the American Chemical Society · doi:10.1021/ja4050828 · Cited by 1,008
Self-citationSynthesis, Structure, and Metalation of Two New Highly Porous Zirconium Metal–Organic Frameworks
Morris, W., Volosskiy, B., Demir, S., Gándara, F., McGrier, P. L., Furukawa, H., Cascio, D., Stoddart, J. F., & Yaghi, O. M. (2012) · Inorganic Chemistry · doi:10.1021/ic300825s · Cited by 906
Self-citationAn Exceptionally Stable, Porphyrinic Zr Metal–Organic Framework Exhibiting pH-Dependent Fluorescence
Jiang, H., Feng, D., Wang, K., Gu, Z., Wei, Z., Chen, Y., & Zhou, H.-C. “. (2013) · Journal of the American Chemical Society · doi:10.1021/ja406844r · Cited by 740
Superacidity in Sulfated Metal–Organic Framework-808
Jiang, J., Gándara, F., Zhang, Y.-B., Na, K., Yaghi, O. M., & Klemperer, W. G. (2014) · Journal of the American Chemical Society · doi:10.1021/ja507119n · Cited by 606
Effect of Water Adsorption on Retention of Structure and Surface Area of Metal–Organic Frameworks
Schoenecker, P. M., Carson, C. G., Jasuja, H., Flemming, C. J. J., & Walton, K. S. (2012) · Industrial & Engineering Chemistry Research · doi:10.1021/ie202325p · Cited by 557
Nelson, A. P., Farha, O. K., Mulfort, K. L., & Hupp, J. T. (2009) · Journal of the American Chemical Society · doi:10.1021/ja808853q · Cited by 539
Self-citationAdsorption by Powders and Porous Solids
(2014) · Elsevier eBooks · doi:10.1016/c2010-0-66232-8 · Cited by 411
Liu, T.-F., Feng, D., Chen, Y.-P., Zou, L., Bosch, M., Yuan, S., Wei, Z., Fordham, S., Wang, K., & Zhou, H.-C. (2015) · Journal of the American Chemical Society · doi:10.1021/ja5111317 · Cited by 402
Bae, Y.-S., Yazaydın, A. Ö., & Snurr, R. Q. (2010) · Langmuir · doi:10.1021/la100449z · Cited by 342
Self-citationAre Zr6-based MOFs water stable? Linker hydrolysis vs. capillary-force-driven channel collapse
Mondloch, J. E., Katz, M. J., Planas, N., Semrouni, D., Gagliardi, L., Hupp, J. T., & Farha, O. K. (2014) · Chemical Communications · doi:10.1039/c4cc02401j · Cited by 336
Self-citationActivation of metal–organic framework materials
Mondloch, J. E., Karagiaridi, O., Farha, O. K., & Hupp, J. T. (2013) · CrystEngComm · doi:10.1039/c3ce41232f · Cited by 324
Self-citationMontoro, C., Linares, F., Quartapelle Procopio, E., Senkovska, I., Kaskel, S., Galli, S., Masciocchi, N., Barea, E., & Navarro, J. A. R. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2042113 · Cited by 316
Enhanced Stability of Cu-BTC MOF via Perfluorohexane Plasma-Enhanced Chemical Vapor Deposition
Decoste, J. B., Peterson, G. W., Smith, M. W., Stone, C. A., & Willis, C. R. (2012) · Journal of the American Chemical Society · doi:10.1021/ja211182m · Cited by 273
Gomez-Gualdron, D. A., Gutov, O. V., Krungleviciute, V., Borah, B., Mondloch, J. E., Hupp, J. T., Yildirim, T., Farha, O. K., & Snurr, R. Q. (2014) · Chemistry of Materials · doi:10.1021/cm502304e · Cited by 231
Self-citationGutov, O. V., Bury, W., Gomez‐Gualdron, D. A., Krungleviciute, V., Fairen‐Jimenez, D., Mondloch, J. E., Sarjeant, A. A., Al‐Juaid, S. S., Snurr, R. Q., Hupp, J. T., et al. (2014) · Chemistry – A European Journal · doi:10.1002/chem.201402895 · Cited by 181
Self-citationUltrahigh porosity in mesoporous MOFs: promises and limitations
Senkovska, I., & Kaskel, S. (2014) · Chemical Communications · doi:10.1039/c4cc00524d · Cited by 166
Integration of accessible secondary metal sites into MOFs for H 2 S removal
Nickerl, G., Leistner, M., Helten, S., et al. (2014) · Inorganic Chemistry Frontiers · doi:10.1039/c3qi00093a · Cited by 99
A new metal–organic framework with high stability based on zirconium for sensing small molecules
Zhang, W., Huang, H., Liu, D., Yang, Q., Xiao, Y., Ma, Q., & Zhong, C. (2013) · Microporous and Mesoporous Materials · doi:10.1016/j.micromeso.2013.01.003 · Cited by 87
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Kirchon, A., Feng, L., Drake, H. F., Joseph, E. A., & Zhou, H.-C. (2018) · Chemical Society Reviews · doi:10.1039/c8cs00688a · Cited by 1,448
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Howarth, A. J., Peters, A. W., Vermeulen, N. A., Wang, T. C., Hupp, J. T., & Farha, O. K. (2017) · Chemistry of Materials · doi:10.1021/acs.chemmater.6b02626 · Cited by 746
Self-citationMetal-organic frameworks: Challenges and opportunities for ion-exchange/sorption applications
Kumar, P., Pournara, A., Kim, K.-H., Bansal, V., Rapti, S., & Manos, M. J. (2017) · Progress in Materials Science · doi:10.1016/j.pmatsci.2017.01.002 · Cited by 423
Evaluating topologically diverse metal–organic frameworks for cryo-adsorbed hydrogen storage
Gómez-Gualdrón, D. A., Colón, Y. J., Zhang, X., Wang, T. C., Chen, Y.-S., Hupp, J. T., Yildirim, T., Farha, O. K., Zhang, J., & Snurr, R. Q. (2016) · Energy & Environmental Science · doi:10.1039/c6ee02104b · Cited by 332
Self-citationColón, Y. J., Gómez-Gualdrón, D. A., & Snurr, R. Q. (2017) · Crystal Growth & Design · doi:10.1021/acs.cgd.7b00848 · Cited by 321
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Metadata
- Authors
- Wang, T. C., Bury, W., Gómez-Gualdrón, D. A., Vermeulen, N. A., Mondloch, J. E., Deria, P., Zhang, K., Moghadam, P. Z., Sarjeant, A. A., Snurr, R. Q., Stoddart, J. F., Hupp, J. T., & Farha, O. K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2015-03-09
- Volume
- 137
- Issue
- 10
- Pages
- 3585-3591
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2090352689
- Cited by
- 425
- References
- 36
- FWCI
- 20.17
- Type
- journal article
- Language
- en
- Open access
- closed
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