The DOI matches its Crossref record.
Catalytic Hydrogenation of Carbon Dioxide Using Ir(III)−Pincer Complexes
Abstract
Catalytic hydrogenation of carbon dioxide in aqueous potassium hydroxide was performed using a newly synthesized isopropyl-substituted PNP-pincer iridium trihydride complex as a catalyst. Potassium formate was obtained with turnover numbers up to 3,500,000 and a turnover frequency of 150,000 h(-1), both of which are the highest values reported to date.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cited by
Recent advances in catalytic hydrogenation of carbon dioxide
Wang, W., Wang, S., Ma, X., & Gong, J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15008a · Cited by 3,316
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO 2 Fixation
Appel, A. M., Bercaw, J. E., Bocarsly, A. B., Dobbek, H., DuBois, D. L., Dupuis, M., Ferry, J. G., Fujita, E., Hille, R., Kenis, P. J. A., et al. (2013) · Chemical Reviews · doi:10.1021/cr300463y · Cited by 2,193
Centi, G., Quadrelli, E. A., & Perathoner, S. (2013) · Energy & Environmental Science · doi:10.1039/c3ee00056g · Cited by 1,257
Asay, M., Jones, C., & Driess, M. (2011) · Chemical Reviews · doi:10.1021/cr100216y · Cited by 1,253
Hull, J. F., Himeda, Y., Wang, W.-H., Hashiguchi, B., Periana, R., Szalda, D. J., Muckerman, J. T., & Fujita, E. (2012) · Nature Chemistry · doi:10.1038/nchem.1295 · Cited by 936
Mellmann, D., Sponholz, P., Junge, H., & Beller, M. (2016) · Chemical Society Reviews · doi:10.1039/c5cs00618j · Cited by 872
Klankermayer, J., Wesselbaum, S., Beydoun, K., & Leitner, W. (2016) · Angewandte Chemie International Edition · doi:10.1002/anie.201507458 · Cited by 856
Direct synthesis of formic acid from carbon dioxide by hydrogenation in acidic media
Moret, S., Dyson, P. J., & Laurenczy, G. (2014) · Nature Communications · doi:10.1038/ncomms5017 · Cited by 733
Sustainable conversion of carbon dioxide: the advent of organocatalysis
Fiorani, G., Guo, W., & Kleij, A. W. (2015) · Green Chemistry · doi:10.1039/c4gc01959h · Cited by 658
Single-Atom Catalysis toward Efficient CO2 Conversion to CO and Formate Products
Su, X., Yang, X.-F., Huang, Y., Liu, B., & Zhang, T. (2019) · Accounts of Chemical Research · doi:10.1021/acs.accounts.8b00478 · Cited by 499
Kuriki, R., Matsunaga, H., Nakashima, T., Wada, K., Yamakata, A., Ishitani, O., & Maeda, K. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b01997 · Cited by 482
Schmeier, T. J., Dobereiner, G. E., Crabtree, R. H., & Hazari, N. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2035514 · Cited by 438
Aresta, M., Dibenedetto, A., & Quaranta, E. (2016) · Journal of Catalysis · doi:10.1016/j.jcat.2016.04.003 · Cited by 346
Nielsen, M., Junge, H., Kammer, A., & Beller, M. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201200625 · Cited by 293
Green catalytic process for cyclic carbonate synthesis from carbon dioxide under mild conditions
Lang, X.-D., & He, L.-N. (2016) · The Chemical Record · doi:10.1002/tcr.201500293 · Cited by 122
Bio-inspired mechanistic insights into CO2 reduction
Mondal, B., Song, J., Neese, F., & Ye, S. (2015) · Current Opinion in Chemical Biology · doi:10.1016/j.cbpa.2014.12.022 · Cited by 112
CO2 Fixation through Hydrogenation by Chemical or Enzymatic Methods
Beller, M., & Bornscheuer, U. T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201402963 · Cited by 84
Metadata
- Authors
- Tanaka, R., Yamashita, M., & Nozaki, K.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2009-09-23
- Volume
- 131
- Issue
- 40
- Pages
- 14168-14169
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W1975506590
- Cited by
- 902
- References
- 0
- FWCI
- 25.70
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.