Random Copolymerization of ε-Caprolactone with Lactide Using a Homosalen−Al Complex

Biodegradable Polymeric Materials

Chiellini, E., & Solaro, R. (1996) · Advanced Materials · doi:10.1002/adma.19960080406 · Cited by 567 · see citing works

Stereoselective Ring-Opening Polymerization of Racemic Lactide Using Aluminum-Achiral Ligand Complexes: Exploration of a Chain-End Control Mechanism

Nomura, N., Ishii, R., Akakura, M., & Aoi, K. (2002) · Journal of the American Chemical Society · doi:10.1021/ja0175789 · Cited by 478 · see citing works

Macromolecular engineering of polylactones and polylactides. 4. Mechanism and kinetics of lactide homopolymerization by aluminum isopropoxide

Dúbois, P., Jacobs, C., Jérôme, R., & Teyssié, P. (1991) · Macromolecules · doi:10.1021/ma00009a022 · Cited by 477 · see citing works

Stereoselective Ring‐Opening Polymerization of a Racemic Lactide by Using Achiral Salen– and Homosalen–Aluminum Complexes

Nomura, N., Ishii, R., Yamamoto, Y., & Kondo, T. (2007) · Chemistry - A European Journal · doi:10.1002/chem.200601308 · Cited by 410 · see citing works

Syntheses and application of polylactides

Kricheldorf, H. R. (2001) · Chemosphere · doi:10.1016/s0045-6535(00)00323-4 · Cited by 343 · see citing works

Study of ligand substituent effects on the rate and stereoselectivity of lactide polymerization using aluminum salen-type initiators

Hormnirun, P., Marshall, E. L., Gibson, V. C., Pugh, R. I., & White, A. J. P. (2006) · Proceedings of the National Academy of Sciences · doi:10.1073/pnas.0602765103 · Cited by 267 · see citing works

Fe(salan)-Catalyzed Asymmetric Oxidation of Sulfides with Hydrogen Peroxide in Water

Egami, H., & Katsuki, T. (2007) · Journal of the American Chemical Society · doi:10.1021/ja071916+ · Cited by 247 · see citing works

Living Ring-Opening Homo- and Copolymerization of ε-Caprolactone and <scp>l</scp> - and <scp>d</scp> , <scp>l</scp> -Lactides by Dimethyl(salicylaldiminato)aluminum Compounds

Pappalardo, D., Annunziata, L., & Pellecchia, C. (2009) · Macromolecules · doi:10.1021/ma9010439 · Cited by 199 · see citing works

Biodegradable Polymers for Sustained Drug Delivery

Schindler, A., Jeffcoat, R. A., Kimmel, G. L., Pitt, C. G., Wall, M. E., & Zweidinger, R. A. (1977) · Springer eBooks · doi:10.1007/978-1-4615-6737-0_12 · Cited by 190 · see citing works

Macromolecular engineering of polylactones and polylactides. 7. Structural analysis of copolyesters of iε-caprolactone and L- or D,L-lactide initiated by triisopropoxyaluminum

Vanhoorne, P., Dúbois, P., Jérôme, R., & Teyssié, P. (1992) · Macromolecules · doi:10.1021/ma00027a008 · Cited by 184 · see citing works

Synthesis, characterization, and miscibility of caprolactone random copolymers

Vion, J. M., Jérôme, R., Teyssié, P., Aubin, M., & Prud'homme, R. E. (1986) · Macromolecules · doi:10.1021/ma00161a009 · Cited by 162 · see citing works

Coordination polymerization of lactides, 4. The role of transesterification in the copolymerization of L , L ‐lactide and ε‐caprolactone

Kasperczyk, J., & Bero, M. (1993) · Die Makromolekulare Chemie · doi:10.1002/macp.1993.021940315 · Cited by 156 · see citing works

α,β-Unsaturated β-Silyl Imide Substrates for Catalytic, Enantioselective Conjugate Additions: A Total Synthesis of (+)-Lactacystin and the Discovery of a New Proteasome Inhibitor

Balskus, E. P., & Jacobsen, E. N. (2006) · Journal of the American Chemical Society · doi:10.1021/ja061970a · Cited by 144 · see citing works

Synthesis of Sulfur-Rich Polymers: Copolymerization of Episulfide with Carbon Disulfide by Using [PPN]Cl/(salph)Cr(III)Cl System

Nakano, K., Tatsumi, G., & Nozaki, K. (2007) · Journal of the American Chemical Society · doi:10.1021/ja076056b · Cited by 144 · see citing works

A Highly Active, Isospecific Cobalt Catalyst for Propylene Oxide Polymerization

Peretti, K. L., Ajiro, H., Cohen, C. T., Lobkovsky, E. B., & Coates, G. W. (2005) · Journal of the American Chemical Society · doi:10.1021/ja053451y · Cited by 139 · see citing works

Coordination polymerization of lactides, 2. Microstructure determination of poly[( L , L ‐lactide)‐ co ‐(ε‐caprolactone)] with 13 C nuclear magnetic resonance spectroscopy

Kasperczyk, J., & Bero, M. (1991) · Die Makromolekulare Chemie · doi:10.1002/macp.1991.021920812 · Cited by 133 · see citing works

Organic and Physical Chemistry of Polymers

Gnanou, Y., & Fontanille, M. (2007) · Wiley eBooks · doi:10.1002/9780470238127 · Cited by 132 · see citing works

Variably Isotactic Poly(hydroxybutyrate) from Racemic β-Butyrolactone: Microstructure Control by Achiral Chromium(III) Salophen Complexes

Zintl, M., Molnar, F., Urban, T., Bernhart, V., Preishuber‐Pflügl, P., & Rieger, B. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200703859 · Cited by 130 · see citing works

Nonlinear least squares fitting applied to copolymerization modeling

van Herk, A. M., & Dröge, T. (1997) · Macromolecular Theory and Simulations · doi:10.1002/mats.1997.040060613 · Cited by 120 · see citing works

Block and random copolymers of ε-caprolactone

Duda, A., Biela, T., Libiszowski, J., Penczek, S., Dúbois, P., Mecerreyes, D., & Jérôme, R. (1998) · Polymer Degradation and Stability · doi:10.1016/s0141-3910(97)00167-5 · Cited by 111 · see citing works

Bismuth(III) n -Hexanoate and Tin(II) 2-Ethylhexanoate Initiated Copolymerizations of ε-Caprolactone and l -Lactide

Kricheldorf, H. R., Bornhorst, K., & Hachmann‐Thießen, H. (2005) · Macromolecules · doi:10.1021/ma047873o · Cited by 105 · see citing works

Ring‐opening oligomerization reactions using aluminium complexes of schiff's bases as initiators

Borgne, A. L., Vincens, V., Jouglard, M., & Spassky, N. (1993) · Makromolekulare Chemie Macromolecular Symposia · doi:10.1002/masy.19930730106 · Cited by 101 · see citing works

Effect of the Configuration of the Active Center on Comonomer Reactivities: The Case of ε‐Caprolactone/ <scp>l,l</scp>‐Lactide Copolymerization

Florczak, M., & Duda, A. (2008) · Angewandte Chemie International Edition · doi:10.1002/anie.200803540 · Cited by 94 · see citing works

Chelation Effect in Polymerization of Cyclic Esters by Metal Alkoxides: Structure Characterization of the Intermediate Formed by Primary Insertion of Lactide into the Al−OR Bond of an Organometallic Initiator

Lewiński, J., Horeglad, P., Wójcik, K., & Justyniak, I. (2005) · Organometallics · doi:10.1021/om050295v · Cited by 93 · see citing works

Polylactones, 39. Zn lactate-catalyzed copolymerization of L-lactide with glycolide or ɛ-caprolactone

Kreiser‐Saunders, I., & Kricheldorf, H. R. (1998) · Macromolecular Chemistry and Physics · doi:10.1002/(sici)1521-3935(19980601)199:6 · Cited by 87 · see citing works

Estimation of copolymer reactivity ratios: An example of nonlinear estimation

Behnken, D. W. (1964) · Journal of Polymer Science Part A General Papers · doi:10.1002/pol.1964.100020207 · Cited by 85 · see citing works

The Total Synthesis of Moenomycin A

Taylor, J. G., Li, X., Oberthür, M., Zhu, W., & Kahne, D. E. (2006) · Journal of the American Chemical Society · doi:10.1021/ja065907x · Cited by 85 · see citing works

Functional amphiphilic and biodegradable copolymers for intravenous vectorisation

Butsele, K. V., Jérôme, R., & Jérôme, C. (2007) · Polymer · doi:10.1016/j.polymer.2007.09.048 · Cited by 70 · see citing works

Highly Enantioselective Carbonyl-ene Reactions Catalyzed by a Hindered Silyl−Salen−Cobalt Complex

Hutson, G. E., Dave, A. H., & Rawal, V. H. (2007) · Organic Letters · doi:10.1021/ol071342d · Cited by 64 · see citing works

Stereoselective Bulk Polymerization of Racemic Lactide for Stereoblock Poly(racemic lactide) Using an Achiral Aluminum Complex

Ishii, R., Nomura, N., & Kondo, T. (2004) · Polymer Journal · doi:10.1295/polymj.36.261 · Cited by 63 · see citing works

Hydrogen-bonding of Esters and Lactones. Site of Bonding and Effect of Ring Size

Searles, S., Tamres, M., & Barrow, G. M. (1953) · Journal of the American Chemical Society · doi:10.1021/ja01097a019 · Cited by 63 · see citing works

Recent research and development in synthetic polymer-based drug delivery systems

Ghosh, S. (2004) · Journal of Chemical Research · doi:10.3184/0308234041209158 · Cited by 63 · see citing works

In Vitro Evaluation of Sustained Drug Release from Biodegradable Elastomer

Wada, R., Hyon, S., Nakamura, T., & Ikada, Y. (1991) · Pharmaceutical Research · doi:10.1023/a:1015860030772 · Cited by 60 · see citing works

Cationic ring‐opening polymerization of lactones in the presence of alcohol

Okamoto, Y. (1991) · Makromolekulare Chemie Macromolecular Symposia · doi:10.1002/masy.19910420109 · Cited by 55 · see citing works

In vitro degradation and biocompatibility of poly( DL ‐lactide‐ϵ‐caprolactone) nerve guides

Meek, M. F., Jansen, K., Steendam, R., van Oeveren, W., van Wachem, P. B., & van Luyn, M. J. A. (2003) · Journal of Biomedical Materials Research Part A · doi:10.1002/jbm.a.10157 · Cited by 55 · see citing works

Effect of polymerization catalysts on the microstructure of P( L LA‐co‐εCL)

Choi, E., Park, J., & Chang, H. (1994) · Journal of Polymer Science Part B Polymer Physics · doi:10.1002/polb.1994.090321505 · Cited by 53 · see citing works

A Direct Function Relationship between Isotacticity and Melting Temperature of Multiblock Stereocopolymer Poly(rac-lactide)

Nomura, N., Hasegawa, J., & Ishii, R. (2009) · Macromolecules · doi:10.1021/ma900760z · Cited by 43 · see citing works

Polymerization of (L,L)‐lactide and copolymerization with ϵ‐caprolactone initiated by dibutyltin dimethoxide in supercritical carbon dioxide

Stassin, F., & Jérôme, R. (2005) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.20735 · Cited by 41 · see citing works

Influence of the nature of the ligand on the microstructure of poly d,l-lactides prepared with organoaluminum initiators

Belleney, J., Wisniewski, M., & Borgne, A. L. (2003) · European Polymer Journal · doi:10.1016/j.eurpolymj.2003.11.001 · Cited by 33 · see citing works

Multiparameter Fluorescence Spectroscopy of Single Quantum Dot−Dye FRET Hybrids

Xu, C. S., Kim, H., Yang, H., & Hayden, C. C. (2007) · Journal of the American Chemical Society · doi:10.1021/ja074279w · Cited by 23 · see citing works

Effect of Lewis Acids on Reactivity Ratios for (Meth)acrylate/Nonpolar Alkene Copolymerizations

Chen, Y., & Sen, A. (2009) · Macromolecules · doi:10.1021/ma900450p · Cited by 23 · see citing works

Basicity and Cationic Copolymerizability of Lactones

鉄雄, 津., Shimizu, T., & YAMASHITA, Y. (1965) · The Journal of the Society of Chemical Industry Japan · doi:10.1246/nikkashi1898.68.12_2473 · Cited by 10 · see citing works

Chain-extended polyurethane anionomers using ionic diols of varying methylene spacers

Ramesh, S., & Radhakrishnan, G. (1996) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/(sici)1099-0518(19960715)34:9 · Cited by 9 · see citing works

Discrete, Solvent-Free Alkaline-Earth Metal Cations: Metal···Fluorine Interactions and ROP Catalytic Activity

Sarazin, Y., Liu, B., Roisnel, T., Maron, L., & Carpentier, J. (2011) · Journal of the American Chemical Society · doi:10.1021/ja2024977 · Cited by 217 · see citing works

Gallium and indium complexes for ring-opening polymerization of cyclic ethers, esters and carbonates

Dagorne, S., Normand, M., Kirillov, E., & Carpentier, J.-F. (2013) · Coordination Chemistry Reviews · doi:10.1016/j.ccr.2013.02.012 · Cited by 215 · see citing works

Ring-Opening Polymerization of <scp>l</scp>-Lactide and ε-Caprolactone Utilizing Biocompatible Zinc Catalysts. Random Copolymerization of <scp>l</scp>-Lactide and ε-Caprolactone

Darensbourg, D. J., & Karroonnirun, O. (2010) · Macromolecules · doi:10.1021/ma101784y · Cited by 178 · see citing works

A highly active and site selective indium catalyst for lactide polymerization

Aluthge, D. C., Patrick, B. O., & Mehrkhodavandi, P. (2012) · Chemical Communications · doi:10.1039/c2cc33519k · Cited by 160 · see citing works

Exploitation of dinuclear salan aluminum complexes for versatile copolymerization of ε-caprolactone and l-lactide

Wang, Y., & Ma, H. (2012) · Chemical Communications · doi:10.1039/c2cc31716h · Cited by 127 · see citing works

Group 4 salalen complexes for the production and degradation of polylactide

Whitelaw, E. L., Davidson, M. G., & Jones, M. D. (2011) · Chemical Communications · doi:10.1039/c1cc13910j · Cited by 125 · see citing works

Kinetic Investigation on the Catalytic Ring-Opening (Co)Polymerization of (Macro)Lactones Using Aluminum Salen Catalysts

Pepels, M. P. F., Bouyahyi, M., Heise, A., & Duchateau, R. (2013) · Macromolecules · doi:10.1021/ma400731c · Cited by 121 · see citing works

Synthesis and Characterization of Amine-Bridged Bis(phenolate)lanthanide Alkoxides and Their Application in the Controlled Polymerization of rac-Lactide and rac-β-Butyrolactone

Nie, K., Fang, L., Yao, Y., Zhang, Y., Shen, Q., & Wang, Y. (2012) · Inorganic Chemistry · doi:10.1021/ic301746c · Cited by 119 · see citing works

Zinc and magnesium complexes supported by bulky multidentate amino-ether phenolate ligands: potent pre-catalysts for the immortalring-opening polymerisation of cyclic esters

Poirier, V., Roisnel, T., Carpentier, J., & Sarazin, Y. (2010) · Dalton Transactions · doi:10.1039/c0dt01219j · Cited by 115 · see citing works

Exploring Closed-Shell Cationic Phenalenyl: From Catalysis to Spin Electronics

Mukherjee, A., Sau, S. C., & Mandal, S. K. (2017) · Accounts of Chemical Research · doi:10.1021/acs.accounts.7b00141 · Cited by 114 · see citing works

Aluminum salen and salan complexes in the ring‐opening polymerization of cyclic esters: Controlled immortal and copolymerization of rac‐β‐butyrolactone and rac‐lactide

Cross, E. D., Allan, L. E. N., Decken, A., & Shaver, M. P. (2012) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.26476 · Cited by 108 · see citing works

Random Copolymerization of ε-Caprolactone and Lactides Promoted by Pyrrolylpyridylamido Aluminum Complexes

Li, G., Lamberti, M., Pappalardo, D., & Pellecchia, C. (2012) · Macromolecules · doi:10.1021/ma3019848 · Cited by 107 · see citing works

Catalytic metal-based systems for controlled statistical copolymerisation of lactide with a lactone

Stirling, E., Champouret, Y., & Visseaux, M. (2018) · Polymer Chemistry · doi:10.1039/c8py00310f · Cited by 101 · see citing works

PLA–PHB–PLA Triblock Copolymers: Synthesis by Sequential Addition and Investigation of Mechanical and Rheological Properties

Aluthge, D. C., Xu, C., Othman, N., Noroozi, N., Hatzikiriakos, S. G., & Mehrkhodavandi, P. (2013) · Macromolecules · doi:10.1021/ma400522n · Cited by 98 · see citing works

Overcoming aggregation in indium salen catalysts for isoselective lactide polymerization

Aluthge, D. C., Ahn, J. M., & Mehrkhodavandi, P. (2015) · Chemical Science · doi:10.1039/c5sc01584g · Cited by 95 · see citing works

Synthesis and Structural Characterization of Various N,O,N-Chelated Aluminum and Gallium Complexes for the Efficient ROP of Cyclic Esters and Carbonates: How Do Aluminum and Gallium Derivatives Compare ?

Hild, F., Neehaul, N., Bier, F., Wirsum, M., Gourlaouen, C., & Dagorne, S. (2013) · Organometallics · doi:10.1021/om3011068 · Cited by 94 · see citing works

Chemistry of magnesium alkyls supported by 1,5,9-trimesityldipyrromethene and 2-[(2,6-diisopropylphenyl)amino]-4-[(2,6-diisopropylphenyl)imino]pent-2-ene. A comparative study

Chisholm, M. H., Choojun, K., Gallucci, J. C., & Wambua, P. M. (2012) · Chemical Science · doi:10.1039/c2sc21017g · Cited by 94 · see citing works

Heteroleptic Silylamido Phenolate Complexes of Calcium and the Larger Alkaline Earth Metals: β‐Agostic Ae⋅⋅⋅SiH Stabilization and Activity in the Ring‐Opening Polymerization of L ‐Lactide

Liu, B., Roisnel, T., Guégan, J., Carpentier, J., & Sarazin, Y. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201103666 · Cited by 88 · see citing works

Self-Switchable Polymerization: A Smart Approach to Sequence-Controlled Degradable Copolymers

Hu, C., Pang, X., & Chen, X. (2022) · Macromolecules · doi:10.1021/acs.macromol.2c00085 · Cited by 87 · see citing works

Group 4 Salalen Complexes and Their Application for the Ring-Opening Polymerization of rac -Lactide

Whitelaw, E. L., Jones, M. D., & Mahon, M. F. (2010) · Inorganic Chemistry · doi:10.1021/ic1010488 · Cited by 84 · see citing works

Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes

Pilone, A., Maio, N. D., Press, K., Venditto, V., Pappalardo, D., Mazzeo, M., Pellecchia, C., Kol, M., & Lamberti, M. (2014) · Dalton Transactions · doi:10.1039/c4dt02616k · Cited by 83 · see citing works

Iso-Selective Ring-Opening Polymerization of rac-Lactide Catalyzed by Crown Ether Complexes of Sodium and Potassium Naphthalenolates

Xiong, J., Zhang, J., Sun, Y., Dai, Z., Pan, X., & Wu, J. (2015) · Inorganic Chemistry · doi:10.1021/ic502685f · Cited by 79 · see citing works

Synthetic and Mechanistic Aspects of the Immortal Ring‐Opening Polymerization of Lactide and Trimethylene Carbonate with New Homo‐ and Heteroleptic Tin(II)‐Phenolate Catalysts

Poirier, V., Roisnel, T., Sinbandhit, S., Bochmann, M., Carpentier, J., & Sarazin, Y. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201102261 · Cited by 78 · see citing works

Potassium, zinc, and magnesium complexes of a bulky OOO-tridentate bis(phenolate) ligand: synthesis, structures, and studies of cyclic ester polymerisation

Huang, Y., Wang, W., Lin, C., Blake, M. P., Clark, L., Schwarz, A. D., & Mountford, P. (2013) · Dalton Transactions · doi:10.1039/c3dt50135c · Cited by 78 · see citing works

Block and random copolymerization of ε‐caprolactone, <i>L</i>‐, and <i>rac</i>‐lactide using titanium complex derived from aminodiol ligand

Dakshinamoorthy, D., & Peruch, F. (2012) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.25983 · Cited by 77 · see citing works

Coordination Chemistry and Reactivity of Zinc Complexes Supported by a Phosphido Pincer Ligand

D’Auria, I., Lamberti, M., Mazzeo, M., Milione, S., Roviello, G., & Pellecchia, C. (2012) · Chemistry - A European Journal · doi:10.1002/chem.201102414 · Cited by 77 · see citing works

Neutral and Cationic N‐Heterocyclic Carbene Zinc Adducts and the BnOH/Zn(C6F5)2 Binary Mixture – Characterization and Use in the Ring‐Opening Polymerization of β‐Butyrolactone, Lactide, and Trimethylene Carbonate

Schnee, G., Fliedel, C., Avilés, T., & Dagorne, S. (2013) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201300292 · Cited by 76 · see citing works

Strategies for the synthesis of block copolymers with biodegradable polyester segments

Diaz, C., & Mehrkhodavandi, P. (2021) · Polymer Chemistry · doi:10.1039/d0py01534b · Cited by 74 · see citing works

Discrete Divalent Rare-Earth Cationic ROP Catalysts: Ligand-Dependent Redox Behavior and Discrepancies with Alkaline-Earth Analogues in a Ligand-Assisted Activated Monomer Mechanism

Liu, B., Roisnel, T., Maron, L., Carpentier, J., & Sarazin, Y. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201204340 · Cited by 74 · see citing works

Alkali aminoether-phenolate complexes: synthesis, structural characterization and evidence for an activated monomer ROP mechanism

Roşca, S., Roşca, D., Dorcet, V., Kozak, C. M., Kerton, F. M., Carpentier, J., & Sarazin, Y. (2012) · Dalton Transactions · doi:10.1039/c2dt32726k · Cited by 73 · see citing works

Group 4 initiators for the stereoselective ROP of rac-β-butyrolactone and its copolymerization with rac-lactide

Jeffery, B. J., Whitelaw, E. L., Garcı́a-Vivó, D., Stewart, J. A., Mahon, M. F., Davidson, M. G., & Jones, M. D. (2011) · Chemical Communications · doi:10.1039/c1cc15265c · Cited by 71 · see citing works

Synthesis and characterization of poly (l-lactide/ε-caprolactone) statistical copolymers with well resolved chain microstructures

Fernández, J., Meaurio, E., Chaos, A., Etxeberria, A., Alonso‐Varona, A., & Sarasua, J.-R. (2013) · Polymer · doi:10.1016/j.polymer.2013.03.009 · Cited by 71 · see citing works

Copolymerization of ε-Caprolactone and <scp>l</scp>-Lactide Catalyzed by Multinuclear Aluminum Complexes: An Immortal Approach

Li, L., Liu, B., Liu, D., Wu, C., Li, S., Liu, B., & Cui, D. (2014) · Organometallics · doi:10.1021/om5008264 · Cited by 70 · see citing works

Salen-type aluminum and zinc complexes as two-faced janus compounds: contribution to molecular sensing and polymerization catalysis

Strianese, M., Pappalardo, D., Mazzeo, M., Lamberti, M., & Pellecchia, C. (2020) · Dalton Transactions · doi:10.1039/d0dt02639e · Cited by 68 · see citing works

Titanium pyridonates and amidates: novel catalysts for the synthesis of random copolymers

Webster, R. L., Noroozi, N., Hatzikiriakos, S. G., Thomson, J. A., & Schafer, L. L. (2012) · Chemical Communications · doi:10.1039/c2cc37201k · Cited by 67 · see citing works

Block–Stereoblock Copolymers of Poly(ϵ‐Caprolactone) and Poly(Lactic Acid)

Rosen, T., Goldberg, I., Navarra, W., Venditto, V., & Kol, M. (2018) · Angewandte Chemie International Edition · doi:10.1002/anie.201803063 · Cited by 66 · see citing works

Heteroleptic Tin(II) Initiators for the Ring-Opening (Co)Polymerization of Lactide and Trimethylene Carbonate: Mechanistic Insights from Experiments and Computations

Wang, L., Kefalidis, C. E., Sinbandhit, S., Dorcet, V., Carpentier, J., Maron, L., & Sarazin, Y. (2013) · Chemistry – A European Journal · doi:10.1002/chem.201301751 · Cited by 65 · see citing works

Methylaluminium 8-quinolinolates: synthesis, characterization and use in ring-opening polymerization (ROP) of ε-caprolactone

Sun, W., Shen, M., Zhang, W., Huang, W., Liu, S., & Redshaw, C. (2011) · Dalton Transactions · doi:10.1039/c0dt01207f · Cited by 65 · see citing works

Polylactic acid (PLA)-based shape-memory materials for biomedical applications

Xu, J., & Song, J. (2015) · Elsevier eBooks · doi:10.1016/b978-0-85709-698-2.00010-6 · Cited by 63 · see citing works

New [ONOO]-Type Amine Bis(phenolate) Ytterbium(II) and -(III) Complexes: Synthesis, Structure, and Catalysis for Highly Heteroselective Polymerization of rac-Lactide

Yang, S., Nie, K., Zhang, Y., Xue, M., Yao, Y., & Shen, Q. (2013) · Inorganic Chemistry · doi:10.1021/ic401747n · Cited by 62 · see citing works

A Novel Regulation Strategy of Solid Electrolyte Interphase Based on Anion‐Solvent Coordination for Magnesium Metal Anode

Tang, K., Du, A., Du, X., Dong, S., Lu, C., Cui, Z., Li, L., Ding, G., Chen, F., Zhou, X., et al. (2020) · Small · doi:10.1002/smll.202005424 · Cited by 62 · see citing works

NHC Bis-Phenolate Aluminum Chelates: Synthesis, Structure, and Use in Lactide and Trimethylene Carbonate Polymerization

Romain, C., Fliedel, C., Bellemin‐Laponnaz, S., & Dagorne, S. (2014) · Organometallics · doi:10.1021/om5004557 · Cited by 61 · see citing works

Synthesis and characterisation of alkylaluminium benzimidazolates and their use in the ring-opening polymerisation of ε-caprolactone

Shen, M., Huang, W., Zhang, W., Hao, X., Sun, W., & Redshaw, C. (2010) · Dalton Transactions · doi:10.1039/c0dt00514b · Cited by 59 · see citing works

Highly Active and Iso‐Selective Catalysts for the Ring‐Opening Polymerization of Cyclic Esters using Group 2 Metal Initiators

Bhattacharjee, J., Harinath, A., Nayek, H. P., Sarkar, A., & Panda, T. K. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201700672 · Cited by 59 · see citing works

Stable divalent germanium, tin and lead amino(ether)-phenolate monomeric complexes: structural features, inclusion heterobimetallic complexes, and ROP catalysis

Wang, L., Roşca, S., Poirier, V., Sinbandhit, S., Dorcet, V., Roisnel, T., Carpentier, J., & Sarazin, Y. (2013) · Dalton Transactions · doi:10.1039/c3dt51681d · Cited by 58 · see citing works

Copolymerization of l -lactide and ε-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6′-dimethylbipheyl-bridge: random and tapered copolymer

Kan, C., & Ma, H. (2016) · RSC Advances · doi:10.1039/c6ra07374c · Cited by 56 · see citing works

Aluminium salalen complexes based on 1,2-diaminocyclohexane and their exploitation for the polymerisation of rac-lactide

Hancock, S. L., Mahon, M. F., & Jones, M. D. (2013) · Dalton Transactions · doi:10.1039/c3dt00021d · Cited by 54 · see citing works

Synthesis, structural characterization and catalytic evaluation of the ring-opening polymerization of discrete five-coordinate alkyl aluminium complexes

Castro‐Osma, J. A., Alonso‐Moreno, C., Márquez‐Segovia, I., Otero, A., Lara‐Sánchez, A., Fernández‐Baeza, J., Rodrı́guez, A. M., Sánchez‐Barba, L. F., & García-Martínez, J. C. (2013) · Dalton Transactions · doi:10.1039/c3dt32657h · Cited by 54 · see citing works

Effects of ligand tuning on dinuclear indium catalysts for lactide polymerization

Osten, K. M., Yu, I., Duffy, I. R., Lagaditis, P. O., Yu, J. C.-C., Wallis, C. J., & Mehrkhodavandi, P. (2012) · Dalton Transactions · doi:10.1039/c2dt30148b · Cited by 53 · see citing works

Kinetic Analysis of the Immortal Ring-Opening Polymerization of Cyclic Esters: A Case Study with Tin(II) Catalysts

Wang, L., Poirier, V., Ghiotto, F., Bochmann, M., Cannon, R. D., Carpentier, J., & Sarazin, Y. (2014) · Macromolecules · doi:10.1021/ma500124k · Cited by 53 · see citing works

Synthesis of biodegradable thermoplastic elastomers from ε‐caprolactone and lactide

Nakayama, Y., Aihara, K., Yamanishi, H., Fukuoka, H., Tanaka, R., Cai, Z., & Shiono, T. (2014) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27463 · Cited by 53 · see citing works

Phenalenyl‐Based Molecules: Tuning the Lowest Unoccupied Molecular Orbital to Design a Catalyst

Sen, T. K., Mukherjee, A., Modak, A., Ghorai, P. K., Kratzert, D., Granitzka, M., Stalke, D., & Mandal, S. K. (2011) · Chemistry - A European Journal · doi:10.1002/chem.201103224 · Cited by 53 · see citing works

Synthesis and structure of a ferric complex of 2,6-di(1H-pyrazol-3-yl)pyridine and its excellent performance in the redox-controlled living ring-opening polymerization of ε-caprolactone

Fang, Y., Gong, W., Shang, X., Li, H., Gao, J., & Lang, J. (2014) · Dalton Transactions · doi:10.1039/c4dt00475b · Cited by 52 · see citing works

Living ring-opening homo- and copolymerisation of ε-caprolactone and l -lactide by cyclic β-ketiminato aluminium complexes

Liu, Y., Dong, W., Liu, J.-Y., & Li, Y. (2013) · Dalton Transactions · doi:10.1039/c3dt52712c · Cited by 51 · see citing works

Copolymerization of Cyclic Esters Controlled by Chiral NNO-Scorpionate Zinc Initiators

Honrado, M., Otero, A., Fernández‐Baeza, J., Sánchez‐Barba, L. F., Garcés, A., Lara‐Sánchez, A., & Rodrı́guez, A. M. (2016) · Organometallics · doi:10.1021/acs.organomet.5b00919 · Cited by 51 · see citing works

Role of Aggregation in the Synthesis and Polymerization Activity of SalBinap Indium Alkoxide Complexes

Aluthge, D. C., Yan, E., Ahn, J. M., & Mehrkhodavandi, P. (2014) · Inorganic Chemistry · doi:10.1021/ic500647j · Cited by 50 · see citing works

Bimetallic aluminum complexes with cyclic β-ketiminato ligands: the cooperative effect improves their capability in polymerization of lactide and ε-caprolactone

Huang, H.-C., Wang, B., Zhang, Y.-P., & Li, Y.-S. (2016) · Polymer Chemistry · doi:10.1039/c6py01092j · Cited by 49 · see citing works

The role of ligand redox non-innocence in ring-opening polymerization reactions catalysed by bis(imino)pyridine iron alkoxide complexes

Delle Chiaie, K. R., Biernesser, A. B., Ortuño, M. A., Dereli, B., Iovan, D. A., Wilding, M. J. T., Li, B., Cramer, C. J., & Byers, J. A. (2017) · Dalton Transactions · doi:10.1039/c7dt03067c · Cited by 48 · see citing works

Controlled ring‐opening polymerization of trimethylene carbonate and access to PTMC‐PLA block copolymers mediated by well‐defined N ‐heterocyclic carbene zinc alkoxides

Fliedel, C., Mameri, S., Dagorne, S., & Avilés, T. (2014) · Applied Organometallic Chemistry · doi:10.1002/aoc.3154 · Cited by 48 · see citing works

A new generation of poly(lactide/ε‐caprolactone) polymeric biomaterials for application in the medical field

Fernández, J., Larrañaga, A., Etxeberria, A., Wang, W., & Sarasua, J. R. (2014) · Journal of Biomedical Materials Research Part A · doi:10.1002/jbm.a.35036 · Cited by 45 · see citing works

Poly(lactide-co-ε-caprolactone) copolymers prepared using bis-thioetherphenolate group 4 metal complexes: synthesis, characterization and morphology

Monica, F. D., Luciano, E., Buonerba, A., Grassi, A., Milione, S., & Capacchione, C. (2014) · RSC Advances · doi:10.1039/c4ra10255j · Cited by 45 · see citing works

Synthesis and Characterization of Dialkylaluminum Amidates and Their Ring-Opening Polymerization of ε-Caprolactone

Zhang, W., Wang, Y., Cao, J., Wang, L., Pan, Y., Redshaw, C., & Sun, W. (2011) · Organometallics · doi:10.1021/om2008343 · Cited by 45 · see citing works

Ring‐opening polymerization of cyclic esters promoted by phosphido‐diphosphine pincer group 3 complexes

D’Auria, I., Mazzeo, M., Pappalardo, D., Lamberti, M., & Pellecchia, C. (2010) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24447 · Cited by 44 · see citing works

Synthesis of repeating sequence copolymers of lactic, glycolic, and caprolactic acids

Weiss, R. M., Jones, E. M., Shafer, D. E., Stayshich, R. M., & Meyer, T. Y. (2011) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.24610 · Cited by 44 · see citing works

Guanidinate Zn(II) Complexes as Efficient Catalysts for Lactide Homo- and Copolymerization under Industrially Relevant Conditions

D’Auria, I., Ferrara, V., Tedesco, C., Kretschmer, W., Kempe, R., & Pellecchia, C. (2021) · ACS Applied Polymer Materials · doi:10.1021/acsapm.1c00552 · Cited by 43 · see citing works

Structural and kinetic studies of the polymerization reactions of ε-caprolactone catalyzed by (pyrazol-1-ylmethyl)pyridine Cu(ii) and Zn(ii) complexes

Ojwach, S. O., Okemwa, T. T., Attandoh, N. W., & Omondi, B. O. (2013) · Dalton Transactions · doi:10.1039/c3dt51338f · Cited by 43 · see citing works

A Discrete Five-Coordinated Cationic Aluminum Complex Supported by a Fluorinated Dialkoxy-Diimino Salen-like Ligand: Synthesis, Structure, and Use in Polymerization Catalysis

Dagorne, S., Bouyahyi, M., Vergnaud, J., & Carpentier, J. (2010) · Organometallics · doi:10.1021/om1000937 · Cited by 43 · see citing works

Ring Opening Polymerization and Copolymerization of Cyclic Esters Catalyzed by Group 2 Metal Complexes Supported by Functionalized P–N Ligands

Harinath, A., Bhattacharjee, J., Sarkar, A., Nayek, H. P., & Panda, T. K. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.7b02847 · Cited by 42 · see citing works

Synthesis, characterization and catalytic activity of magnesium and zinc aminophenoxide complexes: Catalysts for ring-opening polymerization of l-lactide

Chuang, H., Weng, S.-F., Chang, C., Lin, C., & Chen, H. (2011) · Dalton Transactions · doi:10.1039/c1dt11080b · Cited by 41 · see citing works

Controlled ring‐opening homo‐ and copolymerization of ɛ‐caprolactone and d,l ‐lactide by iminophenolate aluminum complexes: An efficient approach toward well‐defined macromonomers

Zaitsev, K. V., Piskun, Y. A., Oprunenko, Y. F., Karlov, S. S., Zaitseva, G. S., Vasilenko, I. V., Churakov, A. V., & Kostjuk, S. V. (2014) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.27110 · Cited by 40 · see citing works

Well-defined, solvent-free cationic barium complexes: Synthetic strategies and catalytic activity in the ring-opening polymerization of lactide

Liu, B., Roisnel, T., & Sarazin, Y. (2011) · Inorganica Chimica Acta · doi:10.1016/j.ica.2011.09.020 · Cited by 40 · see citing works

Aluminum Alkyl Complexes Supported by Bidentate N,N Ligands: Synthesis, Structure, and Catalytic Activity for Guanylation of Amines

Wei, Y., Wang, S., Zhou, S., Feng, Z., Guo, L., Zhu, X., Mu, X., & Yao, F. (2015) · Organometallics · doi:10.1021/acs.organomet.5b00101 · Cited by 40 · see citing works

Controlled random copolymerization of <i>rac</i>‐lactide and <i>ɛ</i>‐caprolactone by well‐designed phenoxyimine Al complexes

Shi, T., Luo, W., Liu, S., & Li, Z. (2018) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.28932 · Cited by 39 · see citing works

β-Pyridylenolate zinc catalysts for the ring-opening homo- and copolymerization of ε-caprolactone and lactides

Bai, J., Xiao, X., Zhang, Y., Chao, J., & Chen, X. (2017) · Dalton Transactions · doi:10.1039/c7dt01877k · Cited by 39 · see citing works

Ring-opening polymerization and copolymerization of cyclic esters catalyzed by amidinate aluminum complexes

Osorio Meléndez, D., Castro‐Osma, J. A., Lara‐Sánchez, A., Rojas, R. S., & Otero, A. (2017) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.28629 · Cited by 38 · see citing works

The effect of steric changes on the isoselectivity of dinuclear indium catalysts for lactide polymerization

Osten, K. M., Aluthge, D. C., & Mehrkhodavandi, P. (2015) · Dalton Transactions · doi:10.1039/c5dt00222b · Cited by 38 · see citing works

Benzoic acid-organocatalyzed ring-opening (co)polymerization (ORO(c)P) of l -lactide and ε-caprolactone under solvent-free conditions: from simplicity to recyclability

Mezzasalma, L., Winter, J. D., Taton, D., & Coulembier, O. (2018) · Green Chemistry · doi:10.1039/c8gc03096k · Cited by 38 · see citing works

Benzoic Acid as an Efficient Organocatalyst for the Statistical Ring-Opening Copolymerization of ε-Caprolactone and L -Lactide: A Computational Investigation

Jehanno, C., Mezzasalma, L., Sardón, H., Ruipérez, F., Coulembier, O., & Taton, D. (2019) · Macromolecules · doi:10.1021/acs.macromol.9b01853 · Cited by 38 · see citing works

Ring-Opening Polymerization (ROP) of cyclic esters by a versatile aluminum Diphenoxyimine Complex: From polylactide to random copolymers

Garcı́a-Valle, F. M., Cuenca, T., Mosquera, M. E. G., Milione, S., & Cano, J. (2020) · European Polymer Journal · doi:10.1016/j.eurpolymj.2020.109527 · Cited by 38 · see citing works

Study on the Origin of Fluorescence by Using Dual-Emission Carbon Dots

Bai, J., Yuan, G., Zhu, Y., Huang, Z., Zhang, L., Wang, X., Wu, S., & Ren, L. (2021) · The Journal of Physical Chemistry C · doi:10.1021/acs.jpcc.1c06137 · Cited by 38 · see citing works

Reinforced Mechanical Properties and Tunable Biodegradability in Nanoporous Cellulose Gels: Poly( l -lactide-co-caprolactone) Nanocomposites

Li, K., Huang, J., Gao, H., Zhong, Y., Cao, X., Chen, Y., Zhang, L., & Cai, J. (2016) · Biomacromolecules · doi:10.1021/acs.biomac.6b00109 · Cited by 37 · see citing works

Bulk Organocatalytic Synthetic Access to Statistical Copolyesters from l -Lactide and ε-Caprolactone Using Benzoic Acid

Mezzasalma, L., Harrisson, S., Saba, S., Loyer, P., Coulembier, O., & Taton, D. (2019) · Biomacromolecules · doi:10.1021/acs.biomac.9b00190 · Cited by 37 · see citing works

Mixed Allyl Rare‐Earth Borohydride Complexes: Synthesis, Structure, and Application in (Co‐)Polymerization Catalysis of Cyclic Esters

Fadlallah, S., Jothieswaran, J., Capet, F., Bonnet, F., & Visseaux, M. (2017) · Chemistry - A European Journal · doi:10.1002/chem.201702902 · Cited by 36 · see citing works

Bimetallic Schiff base complexes for stereoselective polymerisation of racemic-lactide and copolymerisation of racemic-lactide with ε-caprolactone

Sun, Z., Duan, R., Yang, J., Zhang, H., Li, S., Pang, X., Chen, W., & Chen, X. (2016) · RSC Advances · doi:10.1039/c6ra00289g · Cited by 35 · see citing works

Stereoselective Synthesis of Biphenolate/Binaphtolate Titanate and Zirconate Alkoxide Species: Structural Characterization and Use in the Controlled ROP of Lactide

Azor, L., Bailly, C., Karmazin‐Brelot, L., Henry, M., Mobian, P., & Dagorne, S. (2012) · Inorganic Chemistry · doi:10.1021/ic301352t · Cited by 35 · see citing works

Synthesis and Characterization of Dinuclear Salan Rare-Earth Metal Complexes and Their Application in the Homo- and Copolymerization of Cyclic Esters

Ouyang, H., Yuan, D., Nie, K., Zhang, Y., Yao, Y., & Cui, D. (2018) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.8b01046 · Cited by 34 · see citing works

Use of titanocalix[4]arenes in the ring opening polymerization of cyclic esters

Sun, Z., Zhao, Y., Santoro, O., Elsegood, M. R. J., Bedwell, E. V., Zahra, K. M., Walton, A. S., & Redshaw, C. (2020) · Catalysis Science & Technology · doi:10.1039/c9cy02571e · Cited by 34 · see citing works

Homopiperazine and Piperazine Complexes of ZrIV and HfIV and Their Application to the Ring‐Opening Polymerisation of Lactide

Hancock, S. L., Mahon, M. F., Kociok-Köhn, G. I., & Jones, M. D. (2011) · European Journal of Inorganic Chemistry · doi:10.1002/ejic.201100589 · Cited by 34 · see citing works

Lactide, β-butyrolactone, δ-valerolactone, and ε-caprolactone polymerization with copper diketiminate complexes

Whitehorne, T. J. J., & Schaper, F. (2013) · Canadian Journal of Chemistry · doi:10.1139/cjc-2013-0392 · Cited by 33 · see citing works

Ring‐opening polymerization of lactide, ε‐caprolactone and their copolymerization catalyzed by β‐diketiminate zinc complexes

Keram, M., & Ma, H. (2017) · Applied Organometallic Chemistry · doi:10.1002/aoc.3893 · Cited by 33 · see citing works

Monoamidinate titanium complexes: highly active catalysts for the polymerization and copolymerization of l -lactide and ε-caprolactone

Lapenta, R., Mazzeo, M., & Grisi, F. (2015) · RSC Advances · doi:10.1039/c5ra15599a · Cited by 33 · see citing works

Master of Chaos and Order: Opposite Microstructures of PCL‐<i>co</i>‐PGA‐<i>co</i>‐PLA Accessible by a Single Catalyst**

Rittinghaus, R. D., Zenner, J., Pich, A., Kol, M., & Herres‐Pawlis, S. (2022) · Angewandte Chemie International Edition · doi:10.1002/anie.202112853 · Cited by 32 · see citing works

Aluminum, calcium and zinc complexes supported by potentially tridentate iminophenolate ligands: synthesis and use in the ring‐opening polymerization of lactide

Bouyhayi, M., Sarazin, Y., Casagrande, O. L., & Carpentier, J. (2012) · Applied Organometallic Chemistry · doi:10.1002/aoc.2909 · Cited by 32 · see citing works

A DFT study of the ring-opening polymerization mechanism of l-lactide and ε-caprolactone using aluminium salen-type initiators: Towards an understanding of their reactivities in homo- and copolymerization

Chandanabodhi, D., & Nanok, T. (2017) · Molecular Catalysis · doi:10.1016/j.mcat.2017.04.005 · Cited by 31 · see citing works

Enzymatic ring-opening (co)polymerization of lactide stereoisomers catalyzed by lipases. Toward the in situ synthesis of organic/inorganic nanohybrids

Düşkünkorur, H. Ö., Bégué, A., Pollet, É., Phalip, V., Güvenilir, Y., & Avérous, L. (2015) · Journal of Molecular Catalysis B Enzymatic · doi:10.1016/j.molcatb.2015.01.011 · Cited by 30 · see citing works

Synthesis and structural characterization of novel cyclam-based zirconium complexes and their use in the controlled ROP of rac-lactide: access to cyclam-functionalized polylactide materials

Alves, L. G., Hild, F., Munhá, R. F., Veiros, L. F., Dagorne, S., & Martins, A. M. (2012) · Dalton Transactions · doi:10.1039/c2dt31133j · Cited by 29 · see citing works

A Discrete N,O,N-Supported Gallium Amido Complex for the Intermolecular Hydroamination of Terminal Alkynes

Hild, F., & Dagorne, S. (2012) · Organometallics · doi:10.1021/om2012584 · Cited by 28 · see citing works

Synthesis of biodegradable high molecular weight polycarbonates from 1,3‐trimethylene carbonate and 2,2‐dimethyltrimethylene carbonate

Pastusiak, M., Dobrzyński, P., Kasperczyk, J., Smola-Dmochowska, A., & Janeczek, H. (2013) · Journal of Applied Polymer Science · doi:10.1002/app.40037 · Cited by 28 · see citing works

Selective Transesterification to Control Copolymer Microstructure in the Ring-Opening Copolymerization of Lactide and ε-Caprolactone by Lanthanum Complexes

Beament, B., Britton, D., Malcomson, T., Akien, G. R., Halcovitch, N. R., Coogan, M. P., & Platel, R. H. (2024) · Inorganic Chemistry · doi:10.1021/acs.inorgchem.3c03120 · Cited by 27 · see citing works

Ring‐opening polymerization of (Macro)lactones by highly active mononuclear salen–aluminum complexes bearing cyclic β‐ketoiminato ligand

Huang, H., Wang, B., Chen, X., Pan, L., & Li, Y. (2019) · Journal of Polymer Science Part A Polymer Chemistry · doi:10.1002/pola.29350 · Cited by 27 · see citing works

Ring-opening homo- and co-polymerization of lactides and ε-caprolactone by salalen aluminum complexes

Pilone, A., Maio, N. D., Press, K., Venditto, V., Pappalardo, D., Mazzeo, M., Pellecchia, C., Kol, M., & Lamberti, M. (2014) · Dalton Transactions · doi:10.1039/c4dt02616k · Cited by 83 · see citing works

Controlled random copolymerization of <i>rac</i>‐lactide and <i>ɛ</i>‐caprolactone by well‐designed phenoxyimine Al complexes

Shi, T., Luo, W., Liu, S., & Li, Z. (2018) · Journal of Polymer Science Part A: Polymer Chemistry · doi:10.1002/pola.28932 · Cited by 39 · see citing works

Copolymerization of l -lactide and ε-caprolactone catalyzed by mono-and dinuclear salen aluminum complexes bearing bulky 6,6′-dimethylbipheyl-bridge: random and tapered copolymer

Kan, C., & Ma, H. (2016) · RSC Advances · doi:10.1039/c6ra07374c · Cited by 56 · see citing works

Copolymerization of ε-Caprolactone and <scp>l</scp>-Lactide Catalyzed by Multinuclear Aluminum Complexes: An Immortal Approach

Li, L., Liu, B., Liu, D., Wu, C., Li, S., Liu, B., & Cui, D. (2014) · Organometallics · doi:10.1021/om5008264 · Cited by 70 · see citing works

Random Copolymerization of ε-Caprolactone and Lactides Promoted by Pyrrolylpyridylamido Aluminum Complexes

Li, G., Lamberti, M., Pappalardo, D., & Pellecchia, C. (2012) · Macromolecules · doi:10.1021/ma3019848 · Cited by 107 · see citing works