The DOI matches its Crossref record; 12 of the 12 references it cites were found in a registry or an index.
Intermediate Binding Control Using Metal–Organic Frameworks Enhances Electrochemical CO2 Reduction
Abstract
In the electrochemical CO 2 reduction reaction (CO 2 RR), control over the binding of intermediates is key for tuning product selectivity and catalytic activity. Here we report the use of reticular chemistry to control the binding of CO 2 RR intermediates on metal catalysts encapsulated inside metal–organic frameworks (MOFs), thereby allowing us to improve CO 2 RR electrocatalysis. By varying systematically both the organic linker and the metal node in a face-centered cubic ( fcu ) MOF, we tune the adsorption of CO 2, pore openness, and Lewis acidity of the MOFs. Using operando X-ray absorption spectroscopy (XAS) and in situ Raman spectroscopy, we reveal that the MOFs are stable under operating conditions and that this tuning plays the role of optimizing the *CO binding mode on the surface of Ag nanoparticles incorporated inside the MOFs with the increase of local CO 2 concentration. As a result, we improve the CO selectivity from 74% for Ag/Zr- fcu -MOF-1,4-benzenedicarboxylic acid (BDC) to 94% for Ag/Zr- fcu -MOF-1,4-naphthalenedicarboxylic acid (NDC). The work offers a further avenue to utilize MOFs in the pursuit of materials design for CO 2 RR.
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Cites
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
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What would it take for renewably powered electrosynthesis to displace petrochemical processes?
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Advances and challenges in understanding the electrocatalytic conversion of carbon dioxide to fuels
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CO 2 electroreduction to ethylene via hydroxide-mediated copper catalysis at an abrupt interface
Dinh, C.-T., Burdyny, T., Kibria, M. G., Seifitokaldani, A., Gabardo, C. M., García de Arquer, F. P., Kiani, A., Edwards, J. P., De Luna, P., Bushuyev, O. S., et al. (2018) · Science · doi:10.1126/science.aas9100 · Cited by 2,515
Self-citationEnhanced electrocatalytic CO2 reduction via field-induced reagent concentration
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Self-citationElectroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper
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Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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Dopant-induced electron localization drives CO2 reduction to C2 hydrocarbons
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Cited by
Construction and application of base-stable MOFs: a critical review
Wang, K., Li, Y., Xie, L.-H., Li, X., & Li, J.-R. (2022) · Chemical Society Reviews · doi:10.1039/d1cs00891a · Cited by 462
Chang, B., Pang, H., Raziq, F., Wang, S., Huang, K.-W., Ye, J., & Zhang, H. (2023) · Energy & Environmental Science · doi:10.1039/d3ee00964e · Cited by 458
Zhang, L., Li, X.-X., Lang, Z.-L., Liu, Y., Liu, J., Yuan, L., Lu, W.-Y., Xia, Y.-S., Dong, L.-Z., Yuan, D.-Q., et al. (2021) · Journal of the American Chemical Society · doi:10.1021/jacs.0c11450 · Cited by 292
Metadata
- Authors
- Nam, D.-H., Shekhah, O., Lee, G., Mallick, A., Jiang, H., Li, F., Chen, B., Wicks, J., Eddaoudi, M., & Sargent, E. H.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2020-12-15
- Volume
- 142
- Issue
- 51
- Pages
- 21513-21521
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W3113233278
- Cited by
- 246
- References
- 12
- FWCI
- 5.78
- Type
- journal article
- Language
- en
- Open access
- closed
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- Nam, D.-H., Shekhah, O., Lee, G., Mallick, A., Jiang, H., Li, F., Chen, B., Wicks, J., Eddaoudi, M., & Sargent, E. H. (2020). Intermediate Binding Control Using Metal–Organic Frameworks Enhances Electrochemical CO2 Reduction. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.0c10774
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