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New Insight into the Synthesis of Large-Pore Ordered Mesoporous Materials
Open accessAbstract
Ordered mesoporous materials (OMMs) have received increasing interest due to their uniform pore size, high surface area, various compositions and wide applications in energy conversion and storage, biomedicine and environmental remediation, etc. The soft templating synthesis using surfactants or amphiphilic block copolymers is the most efficient method to produce OMMs with tailorable pore structure and surface property. However, due to the limited choice of commercially available soft templates, the common OMMs usually show small pore size and amorphous (or semicrystalline) frameworks. Tailor-made amphiphilic block copolymers with controllable molecular weights and compositions have recently emerged as alternative soft templates for synthesis of new OMMs with many unique features including adjustable mesostructures and framework compositions, ultralarge pores, thick pore walls, high thermal stability and crystalline frameworks. In this Perspective, recent progresses and some new insights into the coassembly process about the synthesis of OMMs based on these tailor-made copolymers as templates are summarized, and typical newly developed synthesis methods and strategies are discussed in depth, including solvent evaporation induced aggregation, ligand-assisted coassembly, solvent evaporation induced micelle fusion-aggregation assembly, homopolymer assisted pore expanding and carbon-supported crystallization strategy. Then, the applications of the obtained large-pore OMMs in catalysis, sensor, energy conversion and storage, and biomedicine by loading large-size guest molecules (e.g., protein and RNA), precious metal nanoparticles and quantum dots, are discussed. At last, the outlook on the prospects and challenges of future research about the synthesis of large-pore OMMs by using tailor-made amphiphilic block copolymers are included.
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“In the case of copolymers containing PS and PAN, the hydrophobic segments can be converted to carbon residue in high yield in the carbonization step, which provides additional mechanical support to the mesoporous framework [145].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [145]
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Metadata
- Authors
- Wei, J., Sun, Z., Luo, W., Li, Y., Elzatahry, A. A., Al-Enizi, A. M., Deng, Y., & Zhao, D.
- Affiliations
- Fudan University (CN)
- Donghua University (CN)
- Qatar University (QA)
- Department of Chemistry, College of Science, King Saud University, Riyadh 11451, Saudi Arabia
- Chinese Academy of Sciences (CN)
- Corresponding author
- Deng, Yonghui
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-01-25
- Volume
- 139
- Issue
- 5
- Pages
- 1706-1713
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2572913071
- Cited by
- 336
- References
- 61
- Citations by year
- 2026: 15 · 2025: 26 · 2024: 22 · 2023: 35 · 2022: 43 · 2021: 35 · 2020: 43 · 2019: 54 · 2018: 44 · 2017: 19
- FWCI
- 18.48
- Type
- journal article
- Language
- en
- Open access
- green
- hdl.handle.net
- Licence
- other-oa
- Locations
- Journal of the American Chemical Society (publishedVersion)
- PubMed (publishedVersion)
- Qatar University QSpace (Qatar University) (submittedVersion)
- Griffith Research Online (submittedVersion, other-oa)
- Funders
- Xi’an Jiaotong University
- Ministry of Science and Technology of the People's Republic of China (2013CB934104)
- Shanghai Municipal Education Commission (13SG02)
- Qatar University (QUUG-CAS-DMST-15\16-18)
- National Natural Science Foundation of China (21210004, 21673048, 51372041, 51402049, 51422202, 51432004, U1463206)
- Shanghai Education Development Foundation (13SG02)
- Central Committee of the Communist Party of China
- Shanghai Science and Technology Committee (14JC1400700)
- Deanship of Scientific Research, King Saud University (PRG-1437-32)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Inorganic Chemistry › Metal-Organic Frameworks: Synthesis and Applications
- Keywords
- ordered mesoporous materials, amphiphilic block copolymers, soft templating, co-assembly, crystalline frameworks, metal nanoparticles, quantum dots, catalysis, sensors, energy storage and conversion, biomedicine
- MeSH terms
- Micelles, Particle Size, Polymers, Surface Properties, Surface-Active Agents, Porosity, Hydrophobic and Hydrophilic Interactions
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