Thick wall mesoporous carbons with a large pore structure templated from a weakly hydrophobic PEO-PMMA diblock copolymer
Abstract
Thick wall mesoporous carbons (FDU-18) with ordered large pore structures were synthesized via an evaporation induced self-assembly (EISA) approach by using a novel amphiphilic diblock copolymer with a weakly hydrophobic segment as a template, soluble resol as a carbon source and THF as a solvent. The versatile atom transfer radical polymerization (ATRP) method was utilized to prepare the diblock copolymer, poly(ethylene oxide)-b-poly(methyl methacrylate) (PEO-b-PMMA). 1H NMR spectroscopy and gel permeation chromatography show that the obtained PEO-b-PMMA has a Mn of 20 070 g mol−1 and a narrow molecular weight distribution (1.09). Small angle X-ray scattering (SAXS) and transmission electron microscopy (TEM) measurements demonstrate that the obtained mesoporous carbons have a face centered cubic close-packed mesostructure (Fmm) with a large unit cell (∼38 nm). N2 sorption isotherms indicate that the mesoporous carbons have a high surface area up to 1050 m2 g−1 and a uniform large mesopore (∼10.5 nm). It is interesting that the pore walls of the mesoporous carbonaceous materials are ultra thick (ca. 11.5–12.4 nm), which are even larger that their pore diameters. The thick pore walls are related to the weakly hydrophobic block PMMA, which can associate with the phenolic resol precursors. Many useful performances such as high mechanical/chemical stability and graphitization could be expected for this kind of thick wall carbon material.
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Synthesized BCPs for templating usually contain P2VP, P4VP, or PEO as the hydrophilic block, and PS, PMMA, PI, PIB, and PAN as the hydrophobic block.
“These synthesized BCPs usually contain poly(2-vinylpyridine) (P2VP), poly(4-vinylpyridine) (P4VP), or poly(ethylene oxide) (PEO) as the hydrophilic block, and PS, PMMA, PI, polyisobutylene (PIB), and polyacrylonitrile (PAN) as the hydrophobic block [143,144].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [143]
Mesoporous carbon films were prepared via EISA from a thermosetting precursor using a variety of BCP templates such as PS-b-P4VP, PEO-b-PS, PEO-b-PMMA, and PEO-b-PMMA-b-PS.
“In addition, mesoporous carbon films were prepared via EISA from a thermosetting precursor (phenol-formaldehyde system, resol, resorcinol, etc.) using a variety of BCP templates such as PS-b-P4VP, PEO-b-PS, PEO-b-PMMA, and PEO-b-PMMA-b-PS [143].”
From Block Copolymers: Synthesis, Self-Assembly, and Applications (2017) · cites this paper as [143]
Cites
Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles
Joo, S. H., Choi, S. J., Oh, I., Kwak, J., Liu, Z., Terasaki, O., & Ryoo, R. (2001) · Nature · doi:10.1038/35084046 · Cited by 2,496 · see citing works
Synthesis of Highly Ordered Carbon Molecular Sieves via Template-Mediated Structural Transformation
Ryoo, R., Joo, S. H., & Jun, S. (1999) · The Journal of Physical Chemistry B · doi:10.1021/jp991673a · Cited by 2,453 · see citing works
Synthesis of New, Nanoporous Carbon with Hexagonally Ordered Mesostructure
Jun, S., Joo, S. H., Ryoo, R., Kruk, M., Jaroniec, M., Liu, Z. P., Ohsuna, T., & Terasaki, O. (2000) · Journal of the American Chemical Society · doi:10.1021/ja002261e · Cited by 2,417 · see citing works
Meng, Y., Gu, D., Zhang, F., Shi, Y., Yang, H., Li, Z., Yu, C., Tu, B., & Zhao, D. (2005) · Angewandte Chemie International Edition · doi:10.1002/anie.200501561 · Cited by 1,306 · see citing works
Self-citationMeng, Y., Gu, D., Zhang, F., Shi, Y., Yang, H., Li, Z., Yu, C., Tu, B., & Zhao, D. (2005) · Angewandte Chemie · doi:10.1002/ange.200501561 · Cited by 1,270 · see citing works
Self-citationMeng, Y., Gu, D., Zhang, F., Shi, Y., Cheng, L., Feng, D., Wu, Z., Chen, Z., Wan, Y., Stein, A., et al. (2006) · Chemistry of Materials · doi:10.1021/cm060921u · Cited by 1,097 · see citing works
Self-citationSynthesis of a large-scale highly ordered porous carbon film by self-assembly of block copolymers
Liang, C., Hong, K., Guiochon, G. A., Mays, J. W., & Dai, S. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200461051 · Cited by 834 · see citing works
Synthesis of a new mesoporous carbon and its application to electrochemical double-layer capacitors
Lee, J., Yoon, S., Hyeon, T., Oh, S. M., & Kim, K. B. (1999) · Chemical Communications · doi:10.1039/a906872d · Cited by 771 · see citing works
Zhang, F., Meng, Y., Gu, D., Yan, Yu, C., Tu, B., & Zhao, D. (2005) · Journal of the American Chemical Society · doi:10.1021/ja0545721 · Cited by 610 · see citing works
Self-citationNanoengineering of a Magnetically Separable Hydrogenation Catalyst
Lu, A., Schmidt, W. N., Matoussevitch, N., Bönnemann, H., Spliethoff, B., Tesche, B., Bill, E., Kiefer, W., & Schüth, F. (2004) · Angewandte Chemie International Edition · doi:10.1002/anie.200454222 · Cited by 550 · see citing works
Electric Double-Layer Capacitor Performance of a New Mesoporous Carbon
Yoon, S., Lee, J., Hyeon, T., & Oh, S. M. (2000) · Journal of The Electrochemical Society · doi:10.1149/1.1393561 · Cited by 432 · see citing works
Deng, Y., Yu, T., Wan, Y., Shi, Y., Meng, Y., Gu, D., Zhang, L., Huang, Y., Liu, C., Wu, X., et al. (2007) · Journal of the American Chemical Society · doi:10.1021/ja067379v · Cited by 402 · see citing works
Self-citationSu, F., Zeng, J., Bao, X., Yu, Y. H., Lee, J. Y., & Zhao, X. (2005) · Chemistry of Materials · doi:10.1021/cm0502222 · Cited by 372 · see citing works
Yu, C., Fan, J. Q., Tian, B., Zhao, D., & Stucky, G. D. (2002) · Advanced Materials · doi:10.1002/1521-4095(20021203)14:23 · Cited by 357 · see citing works
Self-citationKaneda, M., Tsubakiyama, T., Carlsson, A., Sakamoto, Y., Ohsuna, T., Terasaki, O., Joo, S. H., & Ryoo, R. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0131875 · Cited by 354 · see citing works
Lee, J., Joo, S. H., & Ryoo, R. (2002) · Journal of the American Chemical Society · doi:10.1021/ja012333h · Cited by 352 · see citing works
Zhang, F., Meng, Y., Gu, D., Yan, Chen, Z., Tu, B., & Zhao, D. (2006) · Chemistry of Materials · doi:10.1021/cm061400+ · Cited by 251 · see citing works
Self-citationOrganic Aerogels with Very High Impact Strength
Tan, C., Fung, B. M., Newman, J., & Vu, C. (2001) · Advanced Materials · doi:10.1002/1521-4095(200105)13:9 · Cited by 233 · see citing works
Taking Nanocasting One Step Further: Replicating CMK-3 as a Silica Material
Lu, A., Schmidt, W. N., Taguchi, A., Spliethoff, B., Tesche, B., & Schüth, F. (2002) · Angewandte Chemie International Edition · doi:10.1002/1521-3773(20020916)41:18 · Cited by 193 · see citing works
Characterization of mesoporous carbons synthesized with SBA-16 silica template
Kim, T., Ryoo, R., Gierszal, K. P., Jaroniec, M., Solovyov, L. A., Sakamoto, Y., & Terasaki, O. (2005) · Journal of Materials Chemistry · doi:10.1039/b417804a · Cited by 168 · see citing works
Graphitic Mesostructured Carbon Prepared from Aromatic Precursors
Kim, C. H., Lee, D.-K., & Pinnavaia, T. J. (2004) · Langmuir · doi:10.1021/la049602c · Cited by 163 · see citing works
Huang, Y., Cai, H., Yu, T., Zhang, F., Zhang, F., Meng, Y., Gu, D., Wan, Y., Sun, X., Tu, B., et al. (2006) · Angewandte Chemie International Edition · doi:10.1002/anie.200603665 · Cited by 125 · see citing works
Self-citationOhkubo, T., Miyawaki, J., Kaneko, K., Ryoo, R., & Seaton, N. A. (2002) · The Journal of Physical Chemistry B · doi:10.1021/jp0200369 · Cited by 111 · see citing works
Kim, T., & Solovyov, L. A. (2006) · Journal of Materials Chemistry · doi:10.1039/b516945c · Cited by 66 · see citing works
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Zhai, Y., Dou, Y., Zhao, D., Fulvio, P. F., Mayes, R. T., & Dai, S. (2011) · Advanced Materials · doi:10.1002/adma.201100984 · Cited by 2,964 · see citing works
Self-citationTang, J., Liu, J., Li, C., Li, Y., Tade, M. O., Dai, S., & Yamauchi, Y. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201407629 · Cited by 630 · see citing works
Block Copolymers: Synthesis, Self-Assembly, and Applications
Feng, H., Lu, X., Wang, W., Kang, N.-G., & Mays, J. (2017) · Polymers · doi:10.3390/polym9100494 · Cited by 467 · see citing works
“) using a variety of BCP templates such as PS-b-P4VP, PEO-b-PS, PEO-b-PMMA, and PEO-b-PMMA-b-PS [143].”
BackgroundMethodLarge-pore ordered mesoporous materials templated from non-pluronic amphiphilic block copolymers
Deng, Y., Wei, J., Sun, Z., & Zhao, D. (2013) · Chem. Soc. Rev. · doi:10.1039/c2cs35426h · Cited by 447 · see citing works
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Wei, J., Sun, Z., Luo, W., Li, Y., Elzatahry, A. A., Al-Enizi, A. M., Deng, Y., & Zhao, D. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11411 · Cited by 336 · see citing works
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Deng, Y., Cai, Y., Sun, Z., Gu, D., Wei, J., Li, W., Guo, X., Yang, J., & Zhao, D. (2010) · Advanced Functional Materials · doi:10.1002/adfm.201001202 · Cited by 139 · see citing works
Self-citationDeng, Y., Liu, J., Liu, C., Gu, D., Sun, Z., Wei, J., Zhang, J., Zhang, L., Tu, B., & Zhao, D. (2008) · Chemistry of Materials · doi:10.1021/cm802413q · Cited by 126 · see citing works
Self-citationZhang, J., Deng, Y., Wei, J., Sun, Z., Gu, D., Bongard, H., Liu, C., Wu, H., Tu, B., Schüth, F., et al. (2009) · Chemistry of Materials · doi:10.1021/cm901371r · Cited by 107 · see citing works
Self-citation
- Authors
- Deng, Y., Liu, C., Gu, D., Yu, T., Tu, B., & Zhao, D.
- Affiliations
- Fudan University (CN)
- Corresponding author
- Zhao, Dongyuan
- Venue
- J. Mater. Chem.
- Publisher
- Royal Society of Chemistry (RSC)
- Published
- 2008
- Volume
- 18
- Issue
- 1
- Pages
- 91-97
- ISSN
- 0959-9428 (ISSN-L)
- 1364-5501
- OpenAlex
- W2045452718
- Cited by
- 100
- References
- 24
- Citations by year
- 2026: 2 · 2024: 4 · 2023: 2 · 2022: 3 · 2021: 6 · 2020: 7 · 2019: 3 · 2018: 2 · 2017: 7 · 2016: 7 · 2015: 10 · 2014: 9 · 2013: 5 · 2012: 11
- FWCI
- 2.58
- Type
- journal article
- Language
- en
- Open access
- closed
- Locations
- Journal of Materials Chemistry (publishedVersion)
- Topics
- Physical Sciences › Materials Science › Materials Chemistry › Mesoporous Materials and Catalysis
- Physical Sciences › Materials Science › Materials Chemistry › Block Copolymer Self-Assembly
- Physical Sciences › Chemistry › Inorganic Chemistry › Zeolite Catalysis and Synthesis
- Keywords
- evaporation-induced self-assembly, atom transfer radical polymerization, high surface area, pore wall thickness, graphitization
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