The DOI matches its Crossref record; 23 of the 23 references it cites were found in a registry or an index.
Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure
Abstract
Tin (Sn) is known to be a good catalyst for electrochemical reduction of CO 2 to formate in 0.5 M KHCO 3 . But when a thin layer of SnO 2 is coated over Cu nanoparticles, the reduction becomes Sn-thickness dependent: the thicker (1.8 nm) shell shows Sn-like activity to generate formate whereas the thinner (0.8 nm) shell is selective to the formation of CO with the conversion Faradaic efficiency (FE) reaching 93% at −0.7 V (vs reversible hydrogen electrode (RHE)). Theoretical calculations suggest that the 0.8 nm SnO 2 shell likely alloys with trace of Cu, causing the SnO 2 lattice to be uniaxially compressed and favors the production of CO over formate. The report demonstrates a new strategy to tune NP catalyst selectivity for the electrochemical reduction of CO 2 via the tunable core/shell structure.
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Cites
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels
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Enhanced electrocatalytic CO2 reduction via field-induced reagent concentration
Liu, M., Pang, Y., Zhang, B., De Luna, P., Voznyy, O., Xu, J., Zheng, X., Dinh, C. T., Fan, F., Cao, C., et al. (2016) · Nature · doi:10.1038/nature19060 · Cited by 2,000
Aqueous CO2 Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles
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Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces
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A selective and efficient electrocatalyst for carbon dioxide reduction
Lu, Q., Rosen, J., Zhou, Y., Hutchings, G. S., Kimmel, Y. C., Chen, J. G., & Jiao, F. (2014) · Nature Communications · doi:10.1038/ncomms4242 · Cited by 1,478
Hori, Y., Kikuchi, K., & Suzuki, S. (1985) · Chemistry Letters · doi:10.1246/cl.1985.1695 · Cited by 1,401
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO2 to CO
Zhu, W., Michalsky, R., Metin, Ö., Lv, H., Guo, S., Wright, C. J., Sun, X., Peterson, A. A., & Sun, S. (2013) · Journal of the American Chemical Society · doi:10.1021/ja409445p · Cited by 1,382
Self-citationNanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate
Zhang, S., Kang, P., & Meyer, T. J. (2014) · Journal of the American Chemical Society · doi:10.1021/ja4113885 · Cited by 1,151
Size-Dependent Electrocatalytic Reduction of CO2 over Pd Nanoparticles
Gao, D., Zhou, H., Wang, J., Miao, S., Yang, F., Wang, G., Wang, J., & Bao, X. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b00046 · Cited by 1,099
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Cited by
Progress and perspectives of electrochemical CO2 reduction on copper in aqueous electrolyte
Nitopi, S., Bertheussen, E., Scott, S. B., Liu, X., Engstfeld, A. K., Horch, S., Seger, B., Stephens, I. E. L., Chan, K., Hahn, C., et al. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00705 · Cited by 5,223
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Industrial carbon dioxide capture and utilization: state of the art and future challenges
Gao, W., Liang, S., Wang, R., Jiang, Q., Zhang, Y., Zheng, Q., Xie, B., Toe, C. Y., Zhu, X., Wang, J., et al. (2020) · Chemical Society Reviews · doi:10.1039/d0cs00025f · Cited by 1,388
Electrocatalysis for CO 2 conversion: from fundamentals to value-added products
Wang, G., Chen, J., Ding, Y., Cai, P., Yi, L., Li, Y., Tu, C., Hou, Y., Wen, Z., & Dai, L. (2021) · Chemical Society Reviews · doi:10.1039/d0cs00071j · Cited by 1,295
Pan, Y., Lin, R., Chen, Y., Liu, S., Zhu, W., Cao, X., Chen, W., Wu, K., Cheong, W.-C., Wang, Y., et al. (2018) · Journal of the American Chemical Society · doi:10.1021/jacs.8b00814 · Cited by 1,242
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Metadata
- Authors
- Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lu, G., Zhu, J.-J., & Sun, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-03-16
- Volume
- 139
- Issue
- 12
- Pages
- 4290-4293
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2596465153
- Cited by
- 676
- References
- 23
- FWCI
- 21.63
- Type
- journal article
- Language
- en
- Open access
- closed
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- Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lu, G., Zhu, J.-J., & Sun, S. (2017). Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b00261
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