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Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure

Li, Qing, Fu, Jiaju, Zhu, Wenlei, Chen, Zhengzheng, Shen, Bo, Wu, Liheng, Xi, Zheng, Wang, Tanyuan, Lu, Gang, Zhu, Jun-jie, Sun, Shouheng·2017·Journal of the American Chemical Society

Abstract

Tin (Sn) is known to be a good catalyst for electrochemical reduction of CO 2 to formate in 0.5 M KHCO 3 . But when a thin layer of SnO 2 is coated over Cu nanoparticles, the reduction becomes Sn-thickness dependent: the thicker (1.8 nm) shell shows Sn-like activity to generate formate whereas the thinner (0.8 nm) shell is selective to the formation of CO with the conversion Faradaic efficiency (FE) reaching 93% at −0.7 V (vs reversible hydrogen electrode (RHE)). Theoretical calculations suggest that the 0.8 nm SnO 2 shell likely alloys with trace of Cu, causing the SnO 2 lattice to be uniaxially compressed and favors the production of CO over formate. The report demonstrates a new strategy to tune NP catalyst selectivity for the electrochemical reduction of CO 2 via the tunable core/shell structure.

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Metadata

Authors
Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lu, G., Zhu, J.-J., & Sun, S.
Venue
Journal of the American Chemical Society
Published
2017-03-16
Volume
139
Issue
12
Pages
4290-4293
ISSN
  • 0002-7863 (ISSN-L)
  • 1520-5126
OpenAlex
W2596465153
Cited by
676
References
23
FWCI
21.63
Type
journal article
Language
en
Open access
closed

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CoChat. (2026). Citation check: Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure. https://app.cochat.ai/papers/10.1021/jacs.7b00261
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Li, Q., Fu, J., Zhu, W., Chen, Z., Shen, B., Wu, L., Xi, Z., Wang, T., Lu, G., Zhu, J.-J., & Sun, S. (2017). Tuning Sn-Catalysis for Electrochemical Reduction of CO2 to CO via the Core/Shell Cu/SnO2 Structure. Journal of the American Chemical Society. https://doi.org/10.1021/jacs.7b00261

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Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).

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