The DOI matches its Crossref record; 22 of the 22 references it cites were found in a registry or an index.
Large-Scale Synthesis of Carbon-Shell-Coated FeP Nanoparticles for Robust Hydrogen Evolution Reaction Electrocatalyst
Abstract
A highly active and stable non-Pt electrocatalyst for hydrogen production has been pursued for a long time as an inexpensive alternative to Pt-based catalysts. Herein, we report a simple and effective approach to prepare high-performance iron phosphide (FeP) nanoparticle electrocatalysts using iron oxide nanoparticles as a precursor. A single-step heating procedure of polydopamine-coated iron oxide nanoparticles leads to both carbonization of polydopamine coating to the carbon shell and phosphidation of iron oxide to FeP, simultaneously. Carbon-shell-coated FeP nanoparticles show a low overpotential of 71 mV at 10 mA cm –2, which is comparable to that of a commercial Pt catalyst, and remarkable long-term durability under acidic conditions for up to 10 000 cycles with negligible activity loss. The effect of carbon shell protection was investigated both theoretically and experimentally. A density functional theory reveals that deterioration of catalytic activity of FeP is caused by surface oxidation. Extended X-ray absorption fine structure analysis combined with electrochemical test shows that carbon shell coating prevents FeP nanoparticles from oxidation, making them highly stable under hydrogen evolution reaction operation conditions. Furthermore, we demonstrate that our synthetic method is suitable for mass production, which is highly desirable for large-scale hydrogen production.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Mussel-inspired surface chemistry for multifunctional coatings
Lee, H., Dellatore, S. M., Miller, W. M., & Messersmith, P. B. (2007) · Science · doi:10.1126/science.1147241 · Cited by 10,965
Identification of Active Edge Sites for Electrochemical H 2 Evolution from MoS 2 Nanocatalysts
Jaramillo, T. F., Jørgensen, K. P., Bonde, J., Nielsen, J. H., Horch, S., & Chorkendorff, I. (2007) · Science · doi:10.1126/science.1141483 · Cited by 6,100
MoS 2 Nanoparticles Grown on Graphene: An Advanced Catalyst for the Hydrogen Evolution Reaction
Li, Y., Wang, H., Xie, L., Liang, Y., Hong, G., & Dai, H. (2011) · Journal of the American Chemical Society · doi:10.1021/ja201269b · Cited by 5,001
Computational high-throughput screening of electrocatalytic materials for hydrogen evolution
Greeley, J., Jaramillo, T. F., Bonde, J., Chorkendorff, I., & Nørskov, J. K. (2006) · Nature Materials · doi:10.1038/nmat1752 · Cited by 4,097
Ultra-large-scale syntheses of monodisperse nanocrystals
Park, J., An, K., Hwang, Y., Park, J.-G., Noh, H.-J., Kim, J.-Y., Park, J.-H., Hwang, N.-M., & Hyeon, T. (2004) · Nature Materials · doi:10.1038/nmat1251 · Cited by 4,076
Self-citationShinagawa, T., Garcia-Esparza, A. T., & Takanabe, K. (2015) · Scientific Reports · doi:10.1038/srep13801 · Cited by 3,287
Nanostructured Nickel Phosphide as an Electrocatalyst for the Hydrogen Evolution Reaction
Popczun, E. J., McKone, J. R., Read, C. G., Biacchi, A. J., Wiltrout, A. M., Lewis, N. S., & Schaak, R. E. (2013) · Journal of the American Chemical Society · doi:10.1021/ja403440e · Cited by 2,911
Tian, J., Liu, Q., Asiri, A. M., & Sun, X. (2014) · Journal of the American Chemical Society · doi:10.1021/ja503372r · Cited by 2,373
Synthesis of MoS 2 and MoSe 2 Films with Vertically Aligned Layers
Kong, D., Wang, H., Cha, J. J., Pasta, M., Koski, K. J., Yao, J., & Cui, Y. (2013) · Nano Letters · doi:10.1021/nl400258t · Cited by 2,250
Deng, J., Ren, P., Deng, D., & Bao, X. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201409524 · Cited by 1,314
Kibsgaard, J., Tsai, C., Chan, K., Benck, J. D., Nørskov, J. K., Abild-Pedersen, F., & Jaramillo, T. F. (2015) · Energy & Environmental Science · doi:10.1039/c5ee02179k · Cited by 979
Zou, X., Huang, X., Goswami, A., Silva, R., Sathe, B. R., Mikmeková, E., & Asefa, T. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201311111 · Cited by 979
Jiang, P., Liu, Q., Liang, Y., Tian, J., Asiri, A. M., & Sun, X. (2014) · Angewandte Chemie International Edition · doi:10.1002/anie.201406848 · Cited by 885
Cui, X., Ren, P., Deng, D., Deng, J., & Bao, X. (2016) · Energy & Environmental Science · doi:10.1039/c5ee03316k · Cited by 791
Highly Durable and Active PtFe Nanocatalyst for Electrochemical Oxygen Reduction Reaction
Chung, D. Y., Jun, S. W., Yoon, G., Kwon, S. G., Shin, D. Y., Seo, P., Yoo, J. M., Shin, H., Chung, Y.-H., Kim, H., et al. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09653 · Cited by 677
Self-citationMolecular metal–Nx centres in porous carbon for electrocatalytic hydrogen evolution
Liang, H.-W., Brüller, S., Dong, R., Zhang, J., Feng, X., & Müllen, K. (2015) · Nature Communications · doi:10.1038/ncomms8992 · Cited by 655
Zhang, H., Ma, Z., Duan, J., Liu, H., Liu, G., Wang, T., Chang, K., Li, M., Shi, L., Meng, X., et al. (2016) · ACS Nano · doi:10.1021/acsnano.5b05728 · Cited by 491
Wang, Z.-L., Hao, X.-F., Jiang, Z., Sun, X.-P., Xu, D., Wang, J., Zhong, H.-X., Meng, F.-L., & Zhang, X.-B. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b09021 · Cited by 414
Component-Controllable WS2(1– x )Se2 x Nanotubes for Efficient Hydrogen Evolution Reaction
Xu, K., Wang, F., Wang, Z., Zhan, X., Wang, Q., Cheng, Z., Safdar, M., & He, J. (2014) · ACS Nano · doi:10.1021/nn503027k · Cited by 341
Chung, D. Y., Park, S.-K., Chung, Y.-H., Yu, S.-H., Lim, D.-H., Jung, N., Ham, H. C., Park, H.-Y., Piao, Y., Yoo, S. J., et al. (2014) · Nanoscale · doi:10.1039/c3nr05228a · Cited by 287
Self-citationActivity and stability of cobalt phosphides for hydrogen evolution upon water splitting
Ha, D.-H., Han, B., Risch, M., Giordano, L., Yao, K. P. C., Karayaylali, P., & Shao-Horn, Y. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.04.034 · Cited by 199
Rationalization of electrocatalysis of nickel phosphide nanowires for efficient hydrogen production
Chung, Y.-H., Gupta, K., Jang, J.-H., Park, H. S., Jang, I., Jang, J. H., Lee, Y.-K., Lee, S.-C., & Yoo, S. J. (2016) · Nano Energy · doi:10.1016/j.nanoen.2016.06.002 · Cited by 66
Cited by
Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles
Zhu, J., Hu, L., Zhao, P., Lee, L. Y. S., & Wong, K.-Y. (2020) · Chemical Reviews · doi:10.1021/acs.chemrev.9b00248 · Cited by 3,133
Cocatalysts for Selective Photoreduction of CO2into Solar Fuels
Li, X., Yu, J., Jaroniec, M., & Chen, X. (2019) · Chemical Reviews · doi:10.1021/acs.chemrev.8b00400 · Cited by 2,304
Heterostructures for Electrochemical Hydrogen Evolution Reaction: A Review
Zhao, G., Rui, K., Dou, S. X., & Sun, W. (2018) · Advanced Functional Materials · doi:10.1002/adfm.201803291 · Cited by 1,422
Solar‐to‐Hydrogen Energy Conversion Based on Water Splitting
Qi, J., Zhang, W., & Cao, R. (2018) · Advanced Energy Materials · doi:10.1002/aenm.201701620 · Cited by 649
Lu, X. F., Yu, L., & Lou, X. W. (. (2019) · Science Advances · doi:10.1126/sciadv.aav6009 · Cited by 649
Metadata
- Authors
- Chung, D. Y., Jun, S. W., Yoon, G., Kim, H., Yoo, J. M., Lee, K.-S., Kim, T., Shin, H., Sinha, A. K., Kwon, S. G., Kang, K., Hyeon, T., & Sung, Y.-E.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-05-03
- Volume
- 139
- Issue
- 19
- Pages
- 6669-6674
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2608014736
- Cited by
- 519
- References
- 22
- FWCI
- 20.28
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.
