The DOI matches its Crossref record; 17 of the 17 references it cites were found in a registry or an index.
Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources
Abstract
We report a Mn-catalyzed electrochemical dichlorination of alkenes with MgCl 2 as the chlorine source. This method provides operationally simple, sustainable, and efficient access to a variety of vicinally dichlorinated compounds. In particular, alkenes with oxidatively labile functional groups, such as alcohols, aldehydes, sulfides, and amines, were transformed into the desired vicinal dichlorides with high chemoselectivity. Mechanistic data are consistent with metal-mediated Cl atom transfer as the predominant pathway enabling dual C–Cl bond formation and contradict an alternative pathway involving electrochemical evolution of chlorine gas followed by Cl 2 -mediated electrophilic dichlorination.
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Cites
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Cited by
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Electrochemical Late-Stage Functionalization
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Metadata
- Authors
- Fu, N., Sauer, G. S., & Lin, S.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-23
- Volume
- 139
- Issue
- 43
- Pages
- 15548-15553
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2762076493
- Cited by
- 293
- References
- 17
- FWCI
- 11.61
- Type
- journal article
- Language
- en
- Open access
- closed
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