The DOI matches its Crossref record; 29 of the 29 references it cites were found in a registry or an index.
Enantioselective Decarboxylative Cyanation Employing Cooperative Photoredox Catalysis and Copper Catalysis
Abstract
The merger of photoredox catalysis with asymmetric copper catalysis have been realized to convert achiral carboxylic acids into enantiomerically enriched alkyl nitriles. Under mild reaction conditions, the reaction exhibits broad substrate scope, high yields and high enantioselectivities. Furthermore, the reaction can be scaled up to synthesize key chiral intermediates to bioactive compounds.
Overview
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Integrity signals
Registry
Cites
Statistics
Verification
Claims the paper makes
The claims and statistics of this paper haven’t been checked yet.
Run the check — free, no account needed. It reads the open-access text and checks the sources it cites.
Self-check
Percentages, sums and reported differences re-computed from the paper’s own numbers.
The self-check needs the paper’s full text.
Citations
Cites
Prier, C. K., Rankic, D. A., & MacMillan, D. W. C. (2013) · Chemical Reviews · doi:10.1021/cr300503r · Cited by 9,590
Visible light photoredox catalysis: applications in organic synthesis
Narayanam, J. M. R., & Stephenson, C. R. J. (2011) · Chem. Soc. Rev. · doi:10.1039/b913880n · Cited by 4,161
Visible light photocatalysis as a greener approach to photochemical synthesis
Yoon, T. P., Ischay, M. A., & Du, J. (2010) · Nature Chemistry · doi:10.1038/nchem.687 · Cited by 2,657
Kalyanasundaram, K. (1982) · Coordination Chemistry Reviews · doi:10.1016/0010-8545(82)85003-0 · Cited by 1,943
Merging photoredox with nickel catalysis: Coupling of α-carboxyl sp 3 -carbons with aryl halides
Zuo, Z., Ahneman, D. T., Chu, L., Terrett, J. A., Doyle, A. G., & MacMillan, D. W. C. (2014) · Science · doi:10.1126/science.1255525 · Cited by 1,611
Decarboxylative coupling reactions: a modern strategy for C–C-bond formation
Rodríguez, N., & Goossen, L. J. (2011) · Chemical Society Reviews · doi:10.1039/c1cs15093f · Cited by 1,476
Radicals: Reactive Intermediates with Translational Potential
Yan, M., Lo, J. C., Edwards, J. T., & Baran, P. S. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.6b08856 · Cited by 1,098
Photochemistry and Photophysics of Coordination Compounds: Iridium
Flamigni, L., Barbieri, A., Sabatini, C., Ventura, B., & Barigelletti, F. (2007) · Topics in Current Chemistry · doi:10.1007/128_2007_131 · Cited by 1,022
Lowry, M. S., Goldsmith, J. I., Slinker, J. D., Rohl, R., Pascal, R. A., Malliaras, G. G., & Bernhard, S. (2005) · Chemistry of Materials · doi:10.1021/cm051312+ · Cited by 902
Visible‐Light‐Induced Decarboxylative Functionalization of Carboxylic Acids and Their Derivatives
Xuan, J., Zhang, Z., & Xiao, W. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201505731 · Cited by 826
Asymmetric copper-catalyzed C-N cross-couplings induced by visible light
Kainz, Q. M., Matier, C. D., Bartoszewicz, A., Zultanski, S. L., Peters, J. C., & Fu, G. C. (2016) · Science · doi:10.1126/science.aad8313 · Cited by 761
A general alkyl-alkyl cross-coupling enabled by redox-active esters and alkylzinc reagents
Qin, T., Cornella, J., Li, C., Malins, L. R., Edwards, J. T., Kawamura, S., Maxwell, B. D., Eastgate, M. D., & Baran, P. S. (2016) · Science · doi:10.1126/science.aaf6123 · Cited by 727
Efficient Yellow Electroluminescence from a Single Layer of a Cyclometalated Iridium Complex
Slinker, J. D., Gorodetsky, A. A., Lowry, M. S., Wang, J., Parker, S., Rohl, R., Bernhard, S., & Malliaras, G. G. (2004) · Journal of the American Chemical Society · doi:10.1021/ja0345221 · Cited by 690
Ye, Y., & Sanford, M. S. (2012) · Journal of the American Chemical Society · doi:10.1021/ja301553c · Cited by 682
Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay
Zhang, W., Wang, F., McCann, S. D., Wang, D., Chen, P., Stahl, S. S., & Liu, G. (2016) · Science · doi:10.1126/science.aaf7783 · Cited by 676
Self-citationZuo, Z., Cong, H., Li, W., Choi, J., Fu, G. C., & MacMillan, D. W. C. (2016) · Journal of the American Chemical Society · doi:10.1021/jacs.5b13211 · Cited by 519
Okada, K., Okamoto, K., Morita, N., Okubo, K., & Oda, M. (1991) · Journal of the American Chemical Society · doi:10.1021/ja00024a074 · Cited by 446
Zhou, Q., Guo, W., Ding, W., Wu, X., Chen, X., Lu, L., & Xiao, W. (2015) · Angewandte Chemie International Edition · doi:10.1002/anie.201504559 · Cited by 326
Zhao, W., Wurz, R. P., Peters, J. C., & Fu, G. C. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.7b07546 · Cited by 321
Zhu, R., & Buchwald, S. L. (2013) · Angewandte Chemie International Edition · doi:10.1002/anie.201307790 · Cited by 294
Schnermann, M. J., & Overman, L. E. (2012) · Angewandte Chemie International Edition · doi:10.1002/anie.201204977 · Cited by 274
Wu, L., Wang, F., Wan, X., Wang, D., Chen, P., & Liu, G. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b13299 · Cited by 269
Self-citationBifunctional Photocatalysts for Enantioselective Aerobic Oxidation of β-Ketoesters
Ding, W., Lu, L.-Q., Zhou, Q.-Q., Wei, Y., Chen, J.-R., & Xiao, W.-J. (2017) · Journal of the American Chemical Society · doi:10.1021/jacs.6b11418 · Cited by 260
Pratsch, G., Lackner, G. L., & Overman, L. E. (2015) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.5b00795 · Cited by 245
Jin, M., Adak, L., & Nakamura, M. (2015) · Journal of the American Chemical Society · doi:10.1021/jacs.5b02277 · Cited by 229
Recent advances in catalytic decarboxylative acylation reactions via a radical process
Guo, L.-N., Wang, H., & Duan, X.-H. (2016) · Organic & Biomolecular Chemistry · doi:10.1039/c6ob01113f · Cited by 181
Le Vaillant, F., Wodrich, M. D., & Waser, J. (2017) · Chemical Science · doi:10.1039/c6sc04907a · Cited by 176
Song, H.-T., Ding, W., Zhou, Q., et al. (2016) · The Journal of Organic Chemistry · doi:10.1021/acs.joc.6b01360 · Cited by 82
One‐Pot Transformation of Carboxylic Acids into Nitriles
Miyagi, K., Moriyama, K., & Togo, H. (2013) · European Journal of Organic Chemistry · doi:10.1002/ejoc.201300629 · Cited by 16
Cited by
Metallaphotoredox: The Merger of Photoredox and Transition Metal Catalysis
Chan, A. Y., Perry, I. B., Bissonnette, N. B., Buksh, B. F., Edwards, G. A., Frye, L. I., Garry, O. L., Lavagnino, M. N., Li, B. X., Liang, Y., et al. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00383 · Cited by 1,754
Tay, N. E. S., Lehnherr, D., & Rovis, T. (2022) · Chemical Reviews · doi:10.1021/acs.chemrev.1c00384 · Cited by 518
Metadata
- Authors
- Wang, D., Zhu, N., Chen, P., Lin, Z., & Liu, G.
- Venue
- Journal of the American Chemical Society
- Publisher
- American Chemical Society (ACS)
- Published
- 2017-10-30
- Volume
- 139
- Issue
- 44
- Pages
- 15632-15635
- ISSN
- 0002-7863 (ISSN-L)
- 1520-5126
- OpenAlex
- W2765308013
- Cited by
- 304
- References
- 29
- FWCI
- 15.81
- Type
- journal article
- Language
- en
- Open access
- closed
About these checks
Registry, retraction, Cites and statistics results are computed, not judged, with one exception: a printed reference that no index lists is read once by a model before it counts as a citation error. Claims are extracted by a model and kept only when their quote appears verbatim in the text; each cited source is then checked, with a model’s help, for whether it says what the claim relies on. Those verdicts can be wrong — read the claim’s quote and the cited source before relying on one.
Statistics and arithmetic are recomputed, not judged.
Confidence bands are shown only for fields calibrated on our annotated test set. None is calibrated yet, so no band is shown.
What counts as a claim ›How we measure confidence ›How we check this ›
Are you an author, or do you see a problem with this page? Request a review
Data sources
Bibliographic data: Semantic Scholar, OpenAlex, Crossref.
Contains information from the Semantic Scholar Academic Graph Datasets, made available under the ODC Attribution License (ODC-BY 1.0).
Semantic Scholar’s data is described in: Kinney, R., et al. (2023). The Semantic Scholar Open Data Platform. arXiv:2301.10140.